查询词典 butanol

Chiral 3 methy 1,4 butanediol and its derivatives are the important intermediate of synthesis of chiral smectic liquid crystal polyesters and chiral natrual products with biological activity. In the paper, a new efficient route of 3 methyl 1,4 butanediol and its two derivatives, 2 methyl 4 tetrapyranyloxy 1 butanol and 2 methyl 4 tetrapyranylbutanal, was described, and the target products were synthesized by employing asymmetric hydroboration oxidation improved.

手性2－甲基－1，4－丁二醇及其衍生物是合成各种手性近晶型液晶材料以及手性天然生物活性物质的重要中间体，以3－甲基－3－丁烯－1－醇为原料利用改进的不对称硼氢化－氧化反应，成功地合成了－2－甲基－1，4－丁二醇以及其2种手性衍生物：－2－甲基－4－四氢吡喃氧基－1－醇和－2－甲基－4－四氢吡喃氧基丁醛。

The compounds extracted by water and n-butanol are glycosides, maltose and sugarlike compounds.

氯仿萃取结果表明微波法萃取得到的药液含有较少的树脂类化合物。

But the yields decreased to 71~37％ in n-propanol, i-propanol and i-butanol, with another trimeric byproduct 1-oxo-13c-(2-naphthyloxy)-1, 13c-dihydro-dibenzo xanthenes (29) increasing up to 30％ yield.

而在正丙醇、异丙醇和异丁醇中二苯并咕吨4~6的产率下降至71~37％，另一个二聚体副产物1-氧代-13c-（2-萘氧基）-1，13c-二氢-二苯并-咕吨（29）的含量增加，产率可达30％。

Following resolution, the following steps are performed: reduce the isomer to an alcohol, react the alcohol with triphenylmethyl chloride, ozonalyze the resulting reaction product, reduce the ozonalyzed product to yield a diol and react the diol with a methane sulfonyl compound to form-3-2-{(methylsulfonyloxy}ethoxy-4--1-butanol methane sulfonate.

拆分后，进行下一步：将异构体还原为醇，使醇与三苯基甲基氯反应，臭氧化所得反应产物，还原臭氧化产物以得到一种二醇并使所述二醇与甲烷磺酰基化合物反应以形成-3-2-{(甲基磺酰基氧}乙氧基-4--1-丁醇甲烷磺酸酯。

The cause of hard agglomerate formation and its effect on sinterability were investigated. The water-washed ZrO〓-Y〓O〓 powders were found to be greatly made up of hard agglomerates. The ethanolwashed powders also contained a few of hard agglomerates because of uneffective dehydration. Beside, ethanol volatilizes in advance of water during drying because ethanol has a lower boiling point than water, so steric effects of ethanol won't act. However, nearly no hard agglomerate formed in the azeotropic distilled powders, because of effective dehydration and higher boiling point for n-butanol.

研究指出，水洗工艺所得ZrO〓-Y〓O〓粉末几乎完全由硬团聚组成；乙醇洗涤工艺的脱水效果不是很好，并且由于乙醇的沸点比水低，以致在干燥过程中残留乙醇比水先挥发，乙醇的空间位阻效应不能有效地发挥作用，因此，仍然可以导致产生一定量的硬团聚；而共沸蒸馏工艺的脱水效果最佳，且正丁醇的沸点比水高，干燥时残留正丁醇比水后挥发，从而正丁醇的空间位阻效应可有效地发挥作用，因此避免了在煅烧过程中形成Zr-O-Zr键，即共沸蒸馏粉末中不含硬团聚。

Firstly, A precise batch-distilling tower, which would be adaptable to operate in industry or middle scale experiment, has been designed and set up. The optimized operation conditions of reflux (80?1), vaporing quantity ( 9~10 mL?min-1), and raw material concentration (60% mass of 2-methyl-1-butanol) were found.

首先在小试研究成果的基础上，放大设计并建造了适合2-甲基-1-丁醇与3-甲基-1-丁醇的分离的中试或小规模工业化生产的间歇精馏装置，并以此装置作为实验装置进行了工业化试验，得到了该塔的最优操作条件：回流比80、汽化量9~10ml/min、原料中2-甲基-1-丁醇的质量百分浓度约为60%。

The methyl pheophorbide-a (5) was oxidized with osmium oxide and sodium periodate to give chlorin 8 which was converted into aldehyde purpure-18 (9) and purpure-7 trimethyl ester (10) by air-oxidation in butanol in the presence of sodium.

选用四氧化锇和高碘酸钠将5氧化成卟吩醛(8)，在丁醇中以丁醇钠作催化剂， 8的氧化和重排反应给出3-甲酰基紫红素-18酯(9)和紫红素-7三甲酯衍生物10。

The orthogonal experimental design was applied to investigate the effects of zirconia source Zr(NO34·5H2O, ZrOCl2·8H2O,precipitants and sulfating agent (sulfuric acid, ammonium sulfate) on the catalytic performance of the catalysts unde the most superior condition .The catalytic activity was tested in esterification of acetic acid with butanol .

在最优的条件下用正交设计法考察锆源（Zr(NO3)4·5H2O，ZrOCl2·8H2O）、沉淀剂和硫酸化试剂对催化剂性能的影响，并通过乙酸和正丁醇的酯化反应的酯化率检测所制备的SO4/ZrO2催化剂的催化效果。

Then in another tower, of which the height was 1.6m and the inner diameter was 20mm, the pentanol mixture was exactly rectified. The influence factors on separation effect, for example, the material concentration, evaporation velocity, circumfluence rate.etc, were studied and a set of separation system about salt-out -exactitude rectify was upbuilt. The result showed: when the material concentration was 60%, we got our product, 2-methyl-1-butanol, with the concentration over 99% and the top quality recovery over 82.7% which would increase as the material concentration did.

在高1.6m，内径为20rnm的精馏塔内，对戊醇混合物进行精密精馏，研究了原料浓度、蒸发速率、回流比等因素对分离效果的影响，建立了一套盐析-精密精馏的分离体系，结果表明：原料中2-甲基-1-丁醇浓度60％时，得到的2-甲基-1-丁醇产品浓度在99％以上，最高收率达82.7％以上，且随着原料浓度的增加而进一步增大。

The results showed that Kaidimycin was chemically neutral, macrocylic polylactones, stable and liable to dissolve into water and pyridine, slight to dissolve into methanol, ethanol and N-butanol, difficult to dissolve into ethyl acetate, acetone, benzene and chloroform. Chemical reaction of functional group of Kaidimycin showed that it had glycoside, amino acid and aldehyde, no reducing sugar, polypeptide and phenol.

凯地菌素属中等极性的、中性抗生素，极性纸层析结果与多烯类抗生素的纸层析结果相似：易溶于水、吡啶，微溶于甲醇、乙醇、正丁醇，不溶于乙酸乙酯、丙酮、苯、三氯化碳；对高温、光照和紫外处理有很好的稳定性；官能团反应试验结果发现，凯地菌素可能含有糖苷键、氨基酸伯氨基和醛基，不含有还原糖、多肽和酚基，高锰酸钾、浓硫酸反应与多烯大环内酯类抗生素的特性相似；并且依据纯品，采用生物法和分光光度法对摇床发酵液进行了效价的测定。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。