查询词典 bromomethane

This research used the optical frustrated total internal reflection by the coupling of prisms to excite surface plasma waves to measure the resonant angle of the chlorine and Halogen-methane (including the fluoromethane, chloromethane, bromomethane, and iodomethane).

中文摘要本论文是根据光受挫式内部全反射方法利用稜镜的耦合来激发表面电浆波，量测出氯气与卤族甲烷(氟甲烷、氯甲烷、溴化甲烷、碘甲烷)之共振角度。

Including high-purity synthetic hydrobromide, hydrogen bromide acetic acid solution, hydrogen bromide acetone \ dichloromethane solution, sodium bromide, calcium, ammonium and other inorganic bromide, Bromochloromethane second bromomethane, 1 - bromo --3 - chloropropane organic bromide.

包括高纯度合成氢溴酸、溴化氢醋酸溶液、溴化氢丙酮\二氯甲烷溶液、溴化钠、钙、铵等无机溴化物，溴氯甲烷、二溴甲烷、1-溴-3-氯丙烷等有机溴化物。

In the process of laboratory study, oxycodone was prepared by oxidating thebaine at 6,14-position under oxydol, hydrodeoxidizing 7,8-position double bond and 14-position ether under palladium catalyst. Furthermore, N-methyl of oxycodone was isolated byα-chloro-ethyl chloroformate under anhydrous condition and protection of 14-position hydroxyl to obtain noroxycodone, which was further converted into methylnaltrexone by N-alkylation in presence of cyclopropyl bromomethane, then by isolating 3-position methyl of methylnaltrexone under boron tribromide, becoming hydrochloride to prepare target compound, natrexone hydrochloride.

实验室工艺方面，本文首先用双氧水氧化蒂巴因的6-位和14-位、在钯炭催化下加氢还原7-8位双键和14-位醚合成羟考酮，然后提出并优化了在无水和14-位保护的情况下，用氯甲酸-α-氯乙酯脱去羟考酮的N-位甲基合成去甲羟考酮，再用环丙甲基溴将去甲羟考酮的N-位烷基化合成甲基纳曲酮，最后采用三溴化硼脱去甲基纳曲酮的3-位甲基和成盐酸盐合成盐酸纳曲酮。

Or FR4 PCB, bromide exsited mainly in pyrolysis gas and gas products mainly consisted of CO, CO2, propylene, 2-methacrylate, bromomethane, and a small amount of acetone, C1-C3 halogenation alkyls. The pyrolysis gas could be reclaimed as fules after debromide treatment. Pyrolysis liquid products consisted of 8.333% water and 91.667% oil component.

R4板中溴元素主要存在于气体产物中，气体产物主要为CO、CO2、丙烯、2-甲基丙烯、溴甲烷以及其他小分子烯烷烃产物，气体产物可通过除溴无害化处理作可燃气回收；液体产物中含有8.333%的水和油质成分。

SO〓〓/M〓O〓 solid superacid was applied to the photocatalytic oxidation of organic pollutants for the first time. Porous SO〓〓/TiO〓 solid superacid catalysts with high specific surface area were prepared by sol-gel method. The photocatalytic degradation of bromomethane was used as model reaction. The influence of impregnation with H〓SO〓 solution on the structure of catalysts and their photocatalytic performance was systematically studied by using X-ray diffraction, X-ray photoelectron spectroscopy, N〓 sorption analysis applying BET method, UV-Vis diffuse reflectance spectroscopy, FTIR spectroscopy, O〓-TPD and photocatalytic activity measurement. The acidity of TiO〓-based catalysts was investigated by Hammett indicator method, NH〓-TPD and IR spectra of pyridine adsorbtion. The mechanism of superacidifing effects on photocatalytic performances such as the photocatalytic degradation rate of bromomethane, apparent kinetic constant and apparent quantum efficiency was discussed.The results indicated that SO〓〓 is combined with metal ions of TiO〓 in a chelating bidentate mode.

本文首次将SO〓〓/MxOy型固体超强酸催化剂用于光催化氧化有机污染物研究，采用溶胶-凝胶法制备了具有多孔性和大比表面结构的二氧化钛基固体超强酸光催化剂SO〓〓/TiO〓，以光催化降解溴代甲烷为模型反应，系统地研究了H〓SO〓浸渍处理对催化剂表面酸性及其气相光催化性能的影响，结合XRD、BET、XPS、FTIR、Hammett指示剂法、吡啶吸附红外光谱、NH〓-TPD、O〓-TPD、紫外可见漫反射光谱等多种表征手段，深入地讨论了超强酸化对TiO〓的改性机理，阐明了引起SO〓〓/TiO〓超强酸催化剂光催化降解溴代甲烷的转化率、表观反应速率常数和表观量子效率变化的本质原因。

The structural and photocatalytic properties of TiO〓 as well as surface acidity were greatly improved by sulfation. SO〓〓/TiO〓 solid superacid with Hammett constant Ho less than -12.14 was prepared by treating the TiO〓 with 1.0mol. L〓 sulfuric acid solution and then calcining at 450℃ for 3h. When compared to unmodified TiO〓, the SO〓〓/TiO〓 superacid catalyst exhibited higher anatase content, smaller crystal size, higher specific surface area, centralized pore size distribution, and the blue-shifted band edge of uv-vis adsorption spectra. Furthermore, the SO〓〓/TiO〓 superacid also showed excellent reaction activity and stability for CH〓Br photocatalytic decomposition even under the moist reaction conditions. The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.

研究结果表明：SO〓〓与TiO〓表面的结合为螯合式双配位结构；TiO〓光催化剂表面经H〓SO〓浸渍处理后，提高了表面酸性，改善了催化剂结构和光催化性能，当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时，可制得SO〓〓/TiO〓超强酸催化剂(H〓＜-12.14)，其结构和光催化活性得到明显改善，与TiO〓相比，SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移，具有优异的光催化氧化活性、稳定性及抗湿性能，光催化降解溴代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级，是一种有实际应用前景的高效光催化剂；由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型，认为在SO〓〓/TiO〓超强酸催化剂表面，由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心，其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移，具有可逆吸附水的性能，是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。

The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.

研究结果表明：SO〓〓与TiO〓表面的结合为螯合式双配位结构；TiO〓光催化剂表面经H〓SO〓浸渍处理后，提高了表面酸性，改善了催化剂结构和光催化性能，当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时，可制得SO〓〓/TiO〓超强酸催化剂(H〓＜-12.14)，其结构和光催化活性得到明显改善，与TiO〓相比，SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移，具有优异的光催化氧化活性、稳定性及抗湿性能，光催化降解溴代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级，是一种有实际应用前景的高效光催化剂；由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型，认为在SO〓〓/TiO〓超强酸催化剂表面，由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心，其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移，具有可逆吸附水的性能，是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。

L and 72L liquefied propane cylinders of liquefied propylene; 18L, 26L, 28L, 35L, 70L, 80L, 105L, 118L Series liquefied bromomethane cylinders; 400L, 800L liquid chlorine, liquid ammonia cylinder; 720L cylinders and three sulfur 926L, 1180L large size cylinders; 40L, 60L, 82L, 118L, 400L, 800L, 926L, F21, F22, R32, R134a refrigerant and other agents and other specifications of industrial gas cylinders.

b。 12.2L、40L液化丙烷和72L液化丙烯钢瓶；18L、26L、28L、35L、70L、80L、105L、118L系列液化溴甲烷钢瓶；400L、800L液氯、液氨钢瓶；720L三氧化硫钢瓶和926L、1180L大规格钢瓶；40L、60L、82L、118L、400L、800L、926L、 F21、F22、R32、R134a等各种制冷剂及其它规格工业气瓶。

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。