查询词典 bromo-cyanogen

S-Naproxen was obtained by asymmetric cross-coupling reaction of 2-bromo- 6-methoxynaphthalene with organozinc reagent of ethyl α- bromopropionate, catalyzed by chiral β-aminoalkylphosphine-nickel complexes.

用β -氨基烷基膦的NiCl2 配合物为手性催化剂，以 6 -甲氧基- 2 -溴萘和α-溴代丙酸酯的有机锌试剂为原料，通过不对称交叉偶联反应合成S --萘普生。

The famciclovir was synthesized from purine by a series of steps by Acylation, Decarboxylation, Reduction ,and so on; Derivatives of these intermediates is described from the 6-chloro- 9H- purin-2-amine as raw materials in different conditions when the iodine and bromide were synthesized with the addition of two intermediate 6-bromo-9H-purin-2-amine and 6-iodo-9H-purin-2-amine; There is elaborated from the main part of a acetophenone, urineaminohydrochloride, phenylhydrazine, ethyl acetoacetate as raw material through a series of reactions to synthetic 3-phenyl-4-formylphenyl pyrazole and 5-chloro-3-methyl-1-phenyl-1H-pyrazole-4-aldehyde two pyrazole aldehyde, and then with 2-amino-6-chlorine-9-(2-methicillin-oxo-co-methyl-4-yl) purine reaction of the two new pyrazole purine Schiff bases.

本论文主是采用以鸟嘌呤为原料，经过一系列的酰基化，脱羧，还原等反应作用下最终得到了产物2-氨基-9-(4-乙酰氧基-3-乙酰氧基甲基丁基)嘌呤；其中的中间体衍生物主要是阐述从以2-氨基-6-氯鸟嘌呤为原料通过在不同的条件下进行溴代与碘代分别合成了另外两种中间体2-氨基-6-溴鸟嘌呤及2-氨基-6-碘鸟嘌呤；还有一部分主要是阐述从以苯乙酮，盐酸氨基脲，苯肼，乙酰乙酸乙酯为原料通过一系列的反应先合成3-苯基-4-醛基吡唑及5-氯-3-甲基-1-苯基-1H-吡唑-4-甲醛这两个吡唑醛，然后再与2-氨基-6-氯-9-(2-甲氧羰基丁酸甲酯-4-基)嘌呤反应得到了两个新型的吡唑嘌呤席夫碱

Seven of them have not been reported.Their structures were confirmed by IR,~1HNMR,MS,and element analysis. 4.Meanwhile,the green methylation procedure of imides was developed by using dimethyl carbonate as methylation reagent.A series of imides,for example,phthalimide,3,4-dibromo-maleimide and succincide were used for substrates.The effects of DABCO(1,4-diazabicyclo [2.2.2]octane)and DBU(1,8-diazabicyclo[5.4.0]undec-7-ene)as a catalyst in this kind of reactions were investigated.2-Bromo-3-(1-methylindolyl-3-yl)-1-methyl-1H-pyrrole-2,5-dione was prepared by using dimethyl carbonate,which further expanded the use of dimethyl carbonate,as a green agent in organic synthesis.

在以硫酸二甲酯为甲基化试剂对3，4-二溴马来酰亚胺进行N-甲基化反应合成3，4-二溴-N-甲基马来酰亚胺的同时，以碳酸二甲酯为甲基化试剂，对3，4-二溴马来酰亚胺、邻苯二甲酰亚胺、琥珀酰亚胺等酰亚胺类化合物的N-甲基化反应进行了研究；考察了1，4-二氮杂双环[2.2.2]辛烷，1，8-二氮杂双环[5.4.0]十一碳-7-烯、碳酸钾和四丁基溴化铵等作为催化剂对碳酸二甲酯N-甲基化反应的反应时间和收率等的影响，并应用碳酸二甲酯为甲基化试剂，合成了N-甲基-3-溴-4-(1-甲基-吲哚-3)-马来酰亚胺。

A new photochromic organic compound of thiosemicarbazone, 4-( p -bromo-α-methylaminothiocarbonyl hydrazonobenzal)-2,5-dihydro-3-methyl-5-oxo-1-phenyl pyrazole, was synthesized and characterized by elemental analyses, IR, 1H NMR spectra, and X-ray single-crystal diffraction analysis.

文章合成了一个新的有机化合物1-苯基-3-甲基-4-对溴苯亚甲基-吡唑啉酮-5 缩甲基氨基硫脲(1)，并分别用元素分析、红外光谱、氢核磁共振及X-射线单晶衍射对化合物的结构进行了确证和表征。

In the first part, five new 4-acyl pyrazolone 4-ethyl-thiosemicarbazones compounds: 1-Phenyl-3-methyl-4-(4-bromo)benzal-pyrazol-5-one N(4)-ethyl-thiosemicarbazone (PM4Br BP-ETSC), 1-Phenyl-3-methyl-4-(4-methyl)benzal-pyrazol-5-one N(4)-ethyl-thiosemicarbaz -one (PM4MBP-ETSC), 1-Phenyl-3-methyl-4-benzal-pyrazol-5-one N(4)-ethyl-thiosemicarba -zone, 1,3-diphenyl-4-benzal-pyrazol-5-one N(4)-ethyl-thiosemicarbazone and 1-Phenyl-3-methyl-4-phenylacetyl-pyrazol-5-one N(4)-ethyl-thiosemi -carbazone have been synthesized and characterized by elemental analyses, IR, 1H NMR spectra and single-crystal XRD.

第一部分合成了五个4-酰基吡唑啉酮缩4-乙基-氨基硫脲化合物：1-苯基-3-甲基-4-（4-溴）苯甲酰基-5-吡唑啉酮缩4-乙基-氨基硫脲(PM4BrBP-ETSC)，1-苯基-3-甲基-4-(4-甲基)苯甲酰基-5-吡唑啉酮缩4-乙基-氨基硫脲(PM4MBP-ETSC)，1-苯基-3-甲基-4-苯甲酰基-5-吡唑啉酮缩4-乙基-氨基硫脲，1，3-二苯基-4-苯甲酰基-5-吡唑啉酮缩4-乙基-氨基硫脲和1-苯基-3-甲基-4-苯乙酰基-5-吡唑啉酮缩4-乙基-氨基硫脲，其中前四个具有光致变色性质。

During the annual Yadnya Kasada festival the Tenggerese climb Mount Bromo, an active volcano, and seek the blessing from the main deity Hyang Widi Wasa by presenting offerings of rice, fruit, livestock and other local produce.

在每年Yadnya嵩田节Tenggerese攀登溴，一座活火山，并寻求通过提出大米，水果，牲畜和其他地方生产的产品从主神香Widi瓦萨祝福。

A novel macromonomer,polystyrene capped with thienyl group,which can undergos oxidation coupling polymerization,has been synthesized by anionic polymerization of styrene with butyl lithium as the initiator and 3-bromo-thiophene as the terminator.

以丁基锂为引发剂、四氢呋喃为溶剂，在氮气气氛和-78℃下进行苯乙烯阴离子聚合，并加入 3-溴噻吩作为终止剂，从而合成出末端含噻吩基的聚苯乙烯，它可以进行氧化偶联聚合，是一类新的大分子单体。

The bromo-polyethylenegylcol-monomethacrylate was synthesized by two steps. Firstly, methylacrylic acid was esterified with polyethylene glycol (PEG, M=200, 400) to give polyethyleneglycol-monomethacrylate Secondly, treatment of PEG-MA with phosphorus tribromide gave the aim product.

以聚乙二醉（M分别为200，400）和甲基丙烯酸进行单酯化反应，所得单酯再与三溴化磷进行溴化反应合成了一种新的两端具有功能团的不饱和溴化物，即溴代甲基丙烯酸单聚乙二醇酯。

Using 1,4-dibromobenzene,1,3,5-tribromobenzene and 2-methyl-3-butyn-2-ol as starting materials and PdCl2,triphenylphosphine,CuI and KOH as catalysts,1-bromo-4-ethynylbenzene,1,4-diethynylbenzene and 1,3,5-triethynylbenzene were synthesized by Sonogashina coupling reaction and elimination reaction.

以对二溴苯、1，3，5-三溴苯和2-甲基-3-丁炔-2-醇为原料，在PdC l2、PPh3和CuI的催化作用下进行Sonogash ina偶联反应，偶联产物在KOH作用下发生消去反应，分别得到对溴苯乙炔、对二乙炔基苯、1，3，5-三乙炔基苯。

R-4-Methyl-δ-valerolactone was transformed into-methyl 5-bromo-4-methylpentanoate (5) which is a stable and easily reserved reagent.

首次利用甾体皂甙元氧化降解废弃物-4-甲基－δ-戊内酯合成了松叶蜂性信息素(25，3S，7S)-3，7-二甲基－2-十五醇乙酸酯(2)和丙酸酯(3)。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新