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The coordination geometry of the Eu atom is best described as a strongly distorted square-antipyrism.. The two Eu atoms are bridged by two N-oxide oxygen atoms forming a dimeric unit with crystallographic inversions centre. The Eu……Eu distance is 4.2137(9)〓. The two europium atoms and two bridging oxygen atoms is coplanar. The angles of Eu(1)-O(7)-Eu(1A) and O(7)-Eu(1)-O(7A) are 117.82(14)° and 62.18(14)°, respectively. 15 is the first dinuclear triboluminescent lanthanide complex reported.

同时还测定了其摩擦发光光谱与其光致发光光谱，并讨论了晶体结构和摩擦发光活性之间的关系。X-射线结构分析表明，15为有对称中心结构的配合物，每个Eu与三个HTTA的六个O原子和两个PyO的两个O原子形成八配位的四方反锥几何构型，2个N-Oxide O原子桥联两个Eu，形成了一个双核配合物，Eu。。。。

The ligands are tridentate and bridge across the Ag〓 triangles with bridging S atoms occupying all three edges of these trans-oriented triangles.

三齿配体通过硫原子形成了跨过Ag〓三角平面的三条边的桥键。

The results are following:(1)We investigated the influence of the positional isomeric effect on structures.Due to the less space-crowding,it is easier for 3-pytpy to behave as bridging ligand than 2-pytpy under the same reaction conditions,while,it is easier for 2-pytpy to function as tridentate chelating ligand to construct supramolecular structures.

研究结果如下：(1)研究了两个吡啶取代三联吡啶配体的位置异构效应对配合物结构的影响。3-pytpy配体比2-pytpy具有更小的空间位阻，在相同的合成条件下容易以单-三齿桥联方式配位；而2-pytpy更易以三齿螯合形式配位，通过π…π堆积作用形成超分子结构。

It is considered that the carboxylic groups coordinate to the metal ions in four modes: monodentate, the chelating bidentate, the bridging bidentate, and thebridging-chelating tridentate.

一般认为羧酸基有四种配位方式：单齿、螯合双齿、桥联双齿和螯合桥联三齿。

The combinative effect of the fluorine substitute and the bridging unit can make complex 2 as a highly active and selective catalyst for ethylene trimerization.

氟原子效应和桥碳原子上大取代基效应两者结合在一起，可以使络合物2成为一种高活性和高选择性的乙烯三聚催化剂。

In compound 1, Co is in a distorted octahedron environment with four nitro-gen atoms from the tripodal ligand and two oxygen atoms from the bridged oxalate, and the molecule is a dimmer-ic structure consisting of two LCo unites linked by bridging oxalate.

在配合物1中，Co与来自三脚架配体的4个氮和草酸根桥联配体的2个氧原子配位，处于扭曲八面体配位环境。由草酸根桥联两套LCo，构成了一个双核结构。

The carboxyl of the tripodal ligand is a goodbridging group. The building blocks are linked together by the bridging group andother weak interactions (hydrogen bond and π-π stacking interaction, etc), thusgenerating a one, two or three-dimensional metal complexes.2. Studies on the fluorescence properties of the lanthanide complexes indicated that:(1) The excitations in the ligand-based π-π〓 transitions cause the structuredemission of lanthanide complexes while the ligand luminescence is completelyquenched showing that ligand-to-metal energy transfer occurs.

三脚架配体所带的羧基是一个很好的桥联基团，配合物的结构基元通过这种基团的桥联作用及其它一些弱的作用力(如氢键、π-π堆积作用等)联系起来，构成了一维、二维或三维的超分子空间结构。2、稀土配合物的发光研究发现：(1)用配体的π-π〓跃迁波长进行激发，配合物均显示出稀土离子的特征发射峰，同时，配体的荧光峰没有出现，这说明在三脚架配体与稀土离子间进行了有效的能量传递。

In SDS-CaCl_2 system, the adsorption of Ca~(2+) ions on micellar surface can not result in the charge neutralization and there is no hydroxide group bridging effect in this system, so the surfaetant can not be flocculated in form of micelles.

在SDS-CaCl_2体系中，Ca~(2+)的吸附作用并未导致胶束表面电荷的中和，也不存在羟基架桥的作用，故该体系中的表面活性剂不能以胶束形式沉淀。

Shear-induced sand bridging flocculated settling experiment is conducted for Yellow River and the result indicates that the lifetime of optimal structure will be limited for a certain duration.

黄河泥沙架桥絮凝试验研究表明，剪切絮凝条件下泥沙絮凝体的最佳絮凝结构只能维持一段时间。

PDMDAAC—AM flocculates in water by charge neutralization and adsorption bridging mechanism.

PDMDAAC—AM的絮凝机理是电中和及吸附架桥两种作用的结合。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。