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The results showed that the decomposition of 4-nitroimidazole began with the split of the C—NO2 bond in the temperature range of 185—210℃. The strongly oxidative product NO2 destroyed the instable annulus of 4-nitroimidazole instantly, all the other C=N, C=C, C—H and N—H bonds of the five membered ring were broken simultaneously, and the detected gas products of 4-nitroimidazole decomposition were NO2, CO2 and CO.

结果表明,4-硝基咪唑的催化热分解起始于其分子中C-NO2化学键的断裂,温度范围是185~210℃。C-NO2键的强氧化性的裂解产物NO2瞬间作用于4-硝基咪唑分子中不稳定的五员环,使化学键C=N、C=C、C-H和N-H同时被打破。4-硝基咪唑的气体分解产物包括NO2、CO2和CO。

Methanol molecule participates in the proton transfer process, which takes place by a intermolecular six-membered proton-transfer transition state structure instead of the intramolecular four- membered. Consequently, the activation energy of the proton-transfer process is reduced greatly,resulting in the carbon-carbon bond formation process become the rate-determining step. The results are consistent with Aggarwal's the latest dynamics experiments.

CH3OH分子参与质子转移过程,使得原本通过四元环结构过渡态的质子转移过程通过六元环结构过渡态实现,从而极大地降低了质子转移过程的活化能,碳-碳键形成过程进而成为反应的速度控制步骤,研究结果与Aggarwal等的最新动力学研究成果相吻合。

On the basis of Raman and FTIR spectra research on melt structure and water solubility mechanism in albite glasses, we can make the following conclusions:(1) Higher pressure (1bar-2. 0GPa) can lead to below frequency region (50-650cm〓) shift to higher frequency and become narrower, and result in high frequency region (850-1300cm〓) move to lower wave number and become narrower at the same time. These are consistent with the decrease of average T-O-T angle and distribution scope of bond angles (0). In addition, the intensity of 580cm〓 band decrease with increase of pressure and the changes are obvious while pressure is in the range of 0.8-1. 0GPa. And these result from the"collapse"of the planar three membered -containing rings within the glass structure.

通过对高温高压下钠长石熔体结构及水在钠长石熔体中溶解机制的Raman和FTIR光谱实验研究,可以得出以下结论:(1)随着压力升高(1bar-2.0GPa)NaAlSi〓O〓熔体玻璃Raman光谱的低频区(50-650cm〓)不断变窄并向高频方向移动,同时高频区(850-1300cm〓)不断变窄且向低频区方向移动,这表明随着压力升高T-O-T键角不断减小,并且分布范围变窄,T-O-T键角这种变化从而可使T-O键的力常数减小,导致键强减弱;另外,580cm〓谱峰强度随着压力升高不断减弱,并在0.8-1.0GPa时最为显著,这是由于在0.8-1.0GPa时包含的平面三元环结构的"垮塌"造成的。

During mercerization, ramie fiber is swelled, and consequently the distance of cellulose molecules increases, and the hydrogen-bond between molecules is weakened, and even broken.

在丝光,苎麻纤维的膨胀,因此,纤维素分子的距离增加,并的氢键分子之间被削弱,甚至打破。

It was truly a merging of cultures and a common bond formed by the power of music.

这确实是文化的融合和音乐的力量所带来的共鸣。

A lot of energy is required to break the strong metallic bond in the giant metallic lattice.

打开巨型金属晶格中的强金属键需要大量的能量。

Objective The factors affecting bond strength between metallic orthodontic bracket and tooth surface were studied.

目的 体外评价金属网底托槽与牙面间的粘结强度,研究其影响因素。

Based on the ability of neural network in classification and recognization, a feed-forward multi-layer neural network is applied in the diagnosis of adhesive bond quality between metallic and nonmetallic components of a pressure vessel through acoustic feature extraction in the frequency domain, based upon the acoustic response on knocking the pressure vessel.

本文基于神经网络对目标的识别与分类能力,用简单的敲击法获取了某压力容器的声响应信号,通过对声信号的频域特征提取,应用前馈多层神经网络对压力容器的金属与非金属部件之间的粘接质量进行了诊断。

The most studies on ultrasonic nondestructive testing detection laid particular were qualitative, so the authors put forward a quantitative detection method of adhesive bond quality between metallic and nonmetallic components based on the neural networks.

根据超声无损检测中偏重于定性研究的现状,提出一种基于神经网络的金属与非金属材料粘接质量的定量检测方法。

FTIR and SEM analyses indicated that crosslinking reaction between Zn2 and NBR might occured during the curing process,and metallic bridge bond between them was formed.

傅里叶变换红外光谱和扫描电镜分析表明,在硫化过程中,Zn2与NBR发生了接枝和共交联反应,形成离子键桥键。

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推荐网络例句

Alternatively, the con- trollers can use the synchronous rectifier itself or loss- less inductor current-sensing methods to provide overload protection with lower power dissipation.

另外,康威特罗勒斯可以使用同步整流器本身或亏损减少电感电流检测方法,以提供低功耗过载保护。

Mr. Dauber's other Schatz hangs in his home movie studio.

多伯把沙兹的另一件作品挂在家里的电影室。

Most foreign trading companies in West Africa deal in rubber, cocoa and vegetable oil.

非洲西部大多数的外贸公司都是经营橡胶、可可和菜籽油。