查询词典 binuclear

It is noted to that this binuclear nickel complex is able to catalyze ethylene polymerization as single-component catalyst.

值得注意的是，该化合物可以作为单组份催化剂催化乙烯聚合。

This dissertation divides into seven chapters and the main contents and conclusions are listed as following:1. Three series binuclear lanthanide carboxylate coordination polymers 1～7 have been synthesized under hydrothermal conditions by altering the length of carbon chains between carboxyl group and phenyl ring on ligands, which are isophthalic acid, 1,3-phenylenediacetic acid and 1,3-phenoxydiacetic acid, and lanthanide ions such as Pr~(3+), Eu~(3+)and Ho~(3+).

论文共分七章，主要研究内容和结论如下：1、通过改变间苯二甲酸配体的羧基和苯环之间的碳链长度，从间苯二甲酸、间苯二乙酸到间苯二氧乙酸，以及改变稀土离子半径Pr~(3+、Eu~(3+)和Ho~(3+)出发，在水热条件下制备了三个系列双核金属单元的稀土羧酸二维配位聚合物1～7。

Furthermore, the structures of the complexes are strange. The tripodal ligand H〓L〓 form a 2: 2 ring-like binuclear complexes [Eu〓·L〓·6DMF] ·CH〓OH·DMF with Eu〓 in DMF. Two DMF molecules are accommodated in the ring and coordinate with Eu〓.

此外配合物的结构还比较特殊，三足配体H〓L〓与铕的配合物在配位能力较强的溶剂DMF中形成环状的2：2型双核配合物[Eu〓。L〓·6DMF]·CH〓OH·DMF，环状空腔刚好能够把两个配位的DMF溶剂分子包在里面。

Secondly, we found knockdown cortactin can inhibit cytokinesis process with the ratio of binuclear cells was increased.

其次，我们通过RNAi技术沉默细胞内cortactin的表达，会使得双核细胞的比例升高。

All the compounds are characterized by IR and elemental analysis.we design and prepare a bipyridinium supramolecular compound and six coordination compounds, which are also characterized by IR, elemental analysis and X-ray structure analysis. According to X-ray structure analysis, hydrogen bonds and n-n stocking interactions participate in the architecture of three-dimensional framework [H2L1 (NO3)2 (H2O)2]n; one-dimensional zigzag coordination polymer [Hgl21.5CH3OH]n; binuclear metallamacrocycle (HgI2L2)2 3H2O; helical double-stranded one-dimensional coordination polymer [Co2(L2)2-2CH3OH]n; double-stranded one-dimensional coordination polymer [Co2(L3)2-CH3OH-CH3CN]n; and three-dimensional compound [Cu(C5H4NCOO)2(H2O)2]-H2O with hydrogen bonds, three-dimensional coordination polymer {[Cd(C5H6NCOO)2H2O]-DMF}n, which are indirectly obtained from the precursor ligand L3 through metal ion induced the hydrolysis of diamide and self-assembled with the hydrolyzate.

我们首次合成了一个双吡啶鎓超分子化合物和六个过渡金属配合物，并通过IR谱，元素分析和X-ray晶体衍射分析对它们进行了表征。X-ray晶体结构分析表明：超分子化合物[H_2L1·(NO_3)_2·(H_2O)_2]_n是由多种氢键和芳香环间的π-π堆积作用构建的三维无限结构；[HgI_2(L1)·1.5CH_3OH]_n是一维锯齿状配位聚合物；(HgI_2L2)_2·3H_2O是双核金属大环化合物；[Co_2(L2)_2·2CH_3OH]_n是具有一维双螺旋结构的配位聚合物；[Co_2(L3)_2·CH_3OH·CH_3CN]_n为一维双链结构的配位聚合物；以及由非直线形配体L3在金属离子Cu和Cd的诱导作用下发生水解，并且金属离子与水解产物——异烟酸根离子自组装，形成了三维氢键超分子化合物[Cu(C_5H_4NCOO)_2(H_2O)_2]·H_2O和三维配位聚合物{[Cd(C_5H_6NCOO)_2H_2O]·DMF}_n。

A theoretical study on magneto-structural correlation for binuclear Cu complexes bridged by single N-N group from diazine has been investigated by using broken-symmetry approach within the framework of density functional theory.

在密度泛函数理论的框架下，应用对称性破损方法，研究了以N-N基团为单桥的二嗪类双核Cu体系的磁耦合强度及磁-结构关联。

Accordingly, as catalyst of light oil sweetening,the binuclear cobalt sulfonate phthalocyanine was selected in this paper. Due to the double active centers in a plane, bi-CoSPc not only increases the solubility in alkaline, but also avoids its dimerisation, which expects to increase the catalyst activity in sweetening process.

为此，本文选用双核酞菁钴磺酸盐作为轻质油品脱臭催化剂，该催化剂具有平面双核的分子结构，这不仅增加了其在碱液中的溶解度，同时也减弱了二氧加合物的形成趋势，有望在轻质油品催化氧化脱臭工艺中具有更高的催化活性和使用寿命。

This review deals with the active site structure, reactivities and chemical mimics of the binuclear copper enzymes, particularly hemocyanin and tyrosinase .

本文综述了双核铜酶，特别是酪氨酸酶、血蓝蛋白的结构，键合氧、活化氧的性能及有关仿酶模型的研究进展。

The method of self-consistent field of the intermediate neglect of differential overlaphas been used in the calculations of the binuclear cluster, trinuclear unit of hexanuclear clusterand octanuclear clusters. The results are described as follows: The high-lying MO's of thetrinunclear and binuclear cluster are mostly composed of d-orbitals of the metal cores, and areconsidered as M-M bonding orbitals.

应用INDO／S方法对二核簇合物、六核簇合物中的三核片断和八核簇合物进行了计算，结果表明，二核簇合物与三核簇合物的前线占有轨道主要是由金属簇芯的d轨道组成，是M-M成键轨道。

Mn-complexes in which Mn atom ligand with the N atom within ligand can stimulate the recovery of electron transfer and oxygen evolution. The trinuclear Mn-complex is extremely sensitive to the addition of CaCl2. It is suggested that there is an interaction between Ca2 and carboxyl within the trinuclear Mn-complex during photoactivation and this interaction benefits the ligation of Mn atom to the apo-WOC and form an active WOC. Binuclear MnMn complex shows slightly higher efficiency than binuclear MnMn complex in restoration of O2 evolution activity. It is suggested from our results that recovery of electron transport and O2 evolution with synthetic Mn-complexes is affected by different factors. Cl- can stimulate the reconstitution of WOC at the concentration of over 100mM;the maximal recovery of O2 evolution activity requires the presence of CaCl2 and 33 kDa protein polypeptide together. Bicarbonate can stimulate the reconstitution of WOC.

锰配合物中锰原子与配体中的氮原子配位连接时，能显著恢复电子传递活性和放氧活性；三核锰化合物在重组时对CaCl2的存在非常敏感，我们认为Ca2 与三核锰化合物中的羧基之间存在一定的相互作用，而这种作用有助于锰原子的光配位进而使三核锰化合物易于组装成有活性的水氧化复合物：双核锰化合物MnMn比双核锰化合物MnMn在恢复放氧活性方面更有效；影响锰化合物电子传递能力恢复的因素与影响锰化合物放氧活性恢复的因素不同；在锰蔟重组过程中，氯离子的浓度必须在100mM以上，才能有效进行光重组；最大光重组效率的获得必须有钙离子和33kDa多肽同时存在；碳酸氢根离子促进锰化合物与去锰光系统II的光组装。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。