查询词典 binaphthyl

Much better asymmetric induction was obtained with the catalysis of Ag /MAPs than with Ag /H〓-MAPs, and the binaphthyl backbone of R configuration was found to match to the S, S pyrrolidino group.

含有中心手性和轴手性两种手性因素的氮膦配体中，轴手性为R构型时，和中心手性S，S构型相匹配。

The introduces binaphthyl bisphenol monomer on side-chain benzene ring of sulfonic group on molecular level, prepares sulfonated poly aryl ether with sulfonic group only on naphthalene ring of side chain, so that ensures chemical stability of main chain with high molecular weight, while having no influence on mechanical property thereof.

本发明从分子水平出发，将磺酸基在侧链苯环上的联萘双酚单体引入，制备仅在侧链苯环上有磺酸基的磺化聚芳醚，从而保证了高分子主链的化学稳定性，且不会影响其优异的物理机械性能。

In this paper,- and (5)-2,2'-diethynyl-1,1'-binaphthyl with highly stable chiral configurations were employed as structural templates, and a new type of helical cyclophane compounds-3 and-3 were synthesized in enantiopure form by the introduction of benzyl sulfone through Sonogashira coupling reaction, followed by the treatment of disulfone with lithium diisopropylamide.

基於2，2'-二取代的联萘衍生物在手性构型上高度稳定的特点，分别从光学活性的-和-2，2'-二乙炔基-1，1'-联萘结构模板出发，通过Sonogashira偶连反应导入苄基碸，然后用二异丙基氨基锂处理制得的联萘二碸成功地合成了一种新的螺旋环芳分子－对映异构体-3和-3。

The asymmetric polymerization of methyl methacrylate is carried out using the chiral binaphthyl crown ether macrocyclic compounds binding n-BuLi or t-BuOK as chiral initiator at -78℃.

以手性联萘冠醚为配体，络合n-BuLi，t-BuOK等有机金属化合物形成手性引发剂体系，初步探讨了甲基丙烯酸甲酯单体的聚合反应。

Starting from 3, 5-dihydroxybenzoic acid, a total of 16 kinds of salicylicaldehyde derivatives have been synthesized by the esterification, substitution, reduction, formylation, condensation, brominate, functional group protection and deprotection reactions, of which 11 have not been reported yet. Enatiomerically pure 2-amino-2'-hydroxy-1, 1'-binaphthyl has been easily obtained from its racemic mixture by the eantioselective formation of inclusion crystals with N-benzylcinchoninium chloride.

树枝状大分子希夫碱三齿手性配体的设计与合成从3，5-二羟基苯甲酸出发，通过酯化、取代、还原、甲酰化、缩合、官能团的保护与去保护等反应合成了四个系列16种水杨醛衍生物，其中11中是未见文献报道的新化合物。

Bulky and electron-rich MOP-type phosphine ligand 2-ditertbutylphosphino-2'-isopropyloxy- 1,1'-binaphthyl (L1) shows good catalytic activity in palladium-catalyzed α-arylation of 1,3-dicarbonyl compounds.

富电子、大位阻MOP型烷基膦配体2-二叔丁基膦-2'-异丙氧基-1，1'-联萘(L1)在钯催化的1，3-二羰基化合物的α-芳基化反应中显示了较好的催化活性。

The chiral polymer P-1 shows strong blue fluorescence due to the extended π-electronic structure between the chiral repeating unit-6,6'-di(4-trifluoromethyl-phenyl)-2,2'-bisoctoxy-1,1'-binaphthyl and the conjugated linker 2,2'-bipyridyl group via vinylene bridge.

手性高分子P-1能发射强的蓝色荧光，这是由于手性重复单元-6，6′-二(4-三氟甲基苯基)-2，2′-二正辛氧基-1，1′-联萘和单元2，2′-联吡啶通过亚乙烯基桥连形成共轭高分子结构造成的。

The second-order nonlinear optical properties of the binaphthyl bridged chiral bis-porphyrins were greatly improved by introducing push/pull substituents onto the porphyrin chromophore.

卟啉环上引入推／拉电子基团可以有效地提高手性联萘桥联双卟啉的二阶非线性光学系数。

Bulky and electron-rich MOP-type phosphine ligand 2-ditertbutylphosphino-2 -isopropyloxy 1,1 -binaphthyl (L1) shows good catalytic activity in palladium-catalyzed α-arylation of 1,3-dicarbony compounds.

富电子、大位阻MOP型烷基膦配体2-二叔丁基膦－2'-异丙氧基－1，1'-联萘(L1)在钯催化的1，3-二羰基化合物的α-芳基化反应中显示了较好的催化活性。

An inclusion complex -BINOL--Omeprazole or -BINOL--Omeprazole was first obtained from racemic omeprazole with chiral host --or --2, 2'- dihydroxy-1, 1'-binaphthyl in high selectivities, and thus both optically pure enantiomers of omeprazole were prepared as syrup with more than 99% enantiomeric excess, the overall yields of both two enantiomers are more than 60%.

首次发现光学纯R--或s--联二萘酚高效识别并包结R--或S--奥美拉唑，形成包结络合物的现象，并首次将包结拆分法应用于手性苯并咪唑类抗溃疡药物的制备，用一种构型的光学纯联二萘酚直接拆分奥美拉唑，可同时得到油状或糖浆状e.e。

Finally, according to market conditions and market products this article paper analyzes the trends in the development of camera technology, and designs a color night vision camera.

最后根据市场情况和市面上产品的情况分析了摄像机技术的发展趋势，并设计了一款彩色夜视摄像机。

Only person height weeds and the fierce looks stone idles were there.

只有半人深的荒草和龇牙咧嘴的神像。