查询词典 benzylic

In addition, preliminary results demonstrating that the halogenation of alkene and benzylic sp3 C-H bonds can also be achieved using this method.

此外，初步结果表明，苄卤化烯烃类sp3C-H键也可以用这种方法取得。

A mild and highly efficient ZnCl2-catalyzed direct alkylation of active methylene compounds with benzylic and allylic alcohols has been reported.

报道了ZnCl2催化的活泼亚甲基化合物和苄醇或烯丙醇的直接烷基化反应。

In general, the products obtained from these Pd-catalyzed reactions are complementary to those obtained via traditional methods, such as electrophilic aromatic substitution and benzylic halogenation.

一般来说，这些产品来自钯催化反应是相辅相成的所得，经传统方法苄、电等替代卤代芳香。

During the reaction,the bromide component has been converted to catalytically inactive benzylic bromide.In pure acetic acid medium,the "catalyst failure" occurs owing to the formation of benzylic bromide while in acetic acid-water medium,the solvolysis of benzylic bromide by water maintains the catalytic activity to some extent.

反应过程中溴组分会转变为无活性的苄溴，在纯醋酸溶剂中，催化剂会因苄溴的形成而发生催化剂失活现象；在醋酸-水混合溶剂中，由于水对苄溴的溶剂化作用会使苄溴还原为溴离子，一定程度上保持了催化剂活性；并且在一定范围内，含水量的提高有益于生成醛选择性的提高，研究表明，将混合溶剂的初始含水量控制在5-10wt。

During the course of our recent investigation on a new generation of dihydroxylation catalysts,we had had the pleasure of preparing DMAP-derived benzylic alcohol 1 and desired to use its sodium alkoxide ion for an intended nucleophilic substitution event.

在我们对催化剂的羟化新一代最近的调查过程中，我们不得不编写DMAP的乐趣衍生苄醇1和期望使用的预定活动的亲核取代醇钠离子。

Trifluoromethanesulfonic acid was found to be able to efficiently activate the benzylic sp3 C—F bond.

三氟甲磺酸被发现能够高效地活化(SP3)碳－氟键。

In addition, the ground state and radical state effects on BDE were analyzed. All the results in the present study are in good agreement with our recent results about the benzylic BDE.

并且还讨论了BDE的基态效应和自由基效应，其结果与最近报道的有关苄位BDE的结果基本一致。

Benzylic ether phenolic resin is one of the main components of foundry polyurethane binder; its structure and preparation condition determine the performances of polyurethane binder.

苯醚型酚醛树脂是铸造用聚氨酯粘合剂的主要成份之一，它的结构及合成工艺条件决定了该类粘合剂性能。

To our surprise we achieved the ligand 9, 11 and 29 with coordinating atoms fixing at benzylic and benzene ring positions, whose structure is unique in the planar chiral cyclophane chemistry.

以钯催化的烯丙基取代反应对配体进行了考察，硫醚或硒醚取代基在苄位取代的配体表现出更高的反应活性和更高的对映选择性，配体9和11均给出最高为94％的ee值。

Direct competitions of intramolecular C - H insertions into benzylic C - H and 4-nitroor 4-methoxy substituted benzylic C - H of methyl 2-diazo-3-oxo-6-(4-substituted phenyl)-4-(2-phenylethyl)hexanoate 44a and 44b catalyzed by Rh-mediated carbenoid were alsoinvestigated, and the relative reactivities obtained by compound 44a or 44b were comparableto those obtained by indirect method.

此外，还研究了Rh催化分解下，对位硝基取代或甲氧基取代的4-(2-苯基乙基)-6-(4-取代苯基)-2-重氮基-3-氧代己酸甲酯44a、44b苯甲位C-H插入反应的相对速率，与化合物47a和47f得到的结果比较，数据平行。

Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在，所有的孩子都要在综合学校继续学习，所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地，使人们普遍认识到发展不能以牺牲农业为代价。