查询词典 benzyl

Ce2(SO4)3 was used as an inexpensive and effective catalyst for the Friedel-Crafts alkylation of aromatic compounds with benzyl alcohol s, allyl alcohols and benzyl chlorides.

硫酸亚铈作为一种便宜的和有效的催化剂催化芳香化合物与苄基醇、烯丙醇类化合物和苄基氯的傅-克烷基化反应。

Ce2(SO4)3 was used as an inexpensive and effective catalyst for the Friedel-Crafts alkylation of aromatic compounds with benzyl alcohols, allyl alcohol s and benzyl chlorides.

硫酸亚铈作为一种便宜的和有效的催化剂催化芳香化合物与苄基醇、烯丙醇类化合物和苄基氯的傅-克烷基化反应。

When the molar ratio of H2O2 to benzyl alcohol was 0.9, the conversion of benzyl alcohol was 86.2%, the selectiv-ity of benzaldehyde was not less than 99%.

当H2O2与苯甲醇的物质的量比为0.9时，苯甲醇的转化率为86.2%，苯甲醛的选择性≥99%。

The synthesis of benzyl benzoate from sodium benzoate and benzyl chloride by phase transfer catalysis process is studied in the article.

由苯甲酸钠和氯化苄通过相转移催化法合成了苯甲酸苄酯，考察了几种季铵盐类相转移催化剂的亲核取代反应性能。

Benzyl benzoate was synthesized using benzoic acid paste residua and benzyl chloride as raw material at the presence of TEA.

以反应代替分离，将膏状的苯甲酸釜残液碱化后和氯化苄反应，采用相转移催化技术合成苯甲酸苄酯来加以应用。

In this thesis, we did modifications of alkyl groups upon benzyl fluorophosphonate. In order to study the influence of alkyl length and steric effect on activity and selectivity of probes, we synthesized benzyl fluorophosphonate recognition heads with modifications including ethyl, butyl, octyl and cyclohexyl. By way of connecting different kinds of tag like azido group, biotin and rhodamine with recognition heads separately through a higher hydrophilic ethylene glycol derived linker, a series of benzyl fluorophosphonate probes were made up. And they will apply to various biological testing strategies.

在本论文中，我们以苯甲基氟化磷酸酯为基础，於其上进行一系列烷基之修饰，为了探讨烷基长度与空间立体性质对於探针活性及选择性的影响，我们合成了包含乙烷基、丁烷基、辛烷基以及环己烷基修饰的苯甲基氟化磷酸酯辨识端，并藉由具较高亲水性的聚乙二醇衍生连接桥结合三种不同的发报端，分别有叠氮基团、生物素及萤光基团来构成不同的化学探针组合，这一系列苯甲基氟化磷酸酯类化学探针将可被应用於不同的生物测试策略。

Under the optimal conditions, the conversion of benzyl chloride is nearly 100% during esterification, and the total yield of benzyl alcohol is higher than 98%, the percent of benzyl ether is lower than 2%.

氯化苄在酯化反应中基本反应完全，苯甲醇的两步总选择性可以达到98%以上，二苄醚的含量低于2%。

The optimal esterfication reaction conditions as following, the esterification temperature is 115℃, the initial mole ratio of benzyl chloride to sodium formate is 1:1, the volume ratio of water to benzyl chloride is 1:1, and the catalyst amount is 2% according to the quantity of benzyl chloride.

确定最佳的酯化工艺条件为：温度115℃，氯化苄与甲酸钠的摩尔比1：1，氯化苄与水的体积比1：1，催化剂量为氯化苄重量的2%。

There are three different nucleophilic reagent respectively reaction with m-dinitrobenzene ramification at distint alkaline term:With the nitrobenzene 、 m-nirtobenzenesulfone sodium salt 、 2.4-dinitro chlorobenzene 、 m-dinitrobenzene for bottom thing, benzyl cyanide、 benzyl chloride、 benzyl chloropyridine、is a nucleophilic reagent reaction for under the different term proceeds a series reaction. At the same time ,discuss about the impact factor to nucleophilicity such as the number of attract electron group、 ability of attract electron and the nucleophilic substitution reaction part.

设计了三类不同的亲核试剂分别与活化芳环在不同的碱性条件下发生反应：以苄基氰、苄基氯化吡啶为亲核试剂，以硝基苯、间二硝基苯、间硝基苯磺酸钠、2，4-二硝基苄基氯为底物进行亲核取代反应；并且对亲核试剂的体积效应、溶剂效应对亲核性影响，底物上吸电子基团的数目、吸电子能力对亲电性的影响，以及亲核取代反应的发生部位受哪些因素影响进行探讨。

On the other hand, 3(2)-fluoro-4-methoxyl methyl benzyl alcohol and 3(2)-fluoro-4-methyl benzyl alcohol are mixture and components of pyrethrum esters. Both of them have "mixture fluorine effect " and higher activity, lower drug resistance. As we know, the mixture benzyl alcohol containing fluorine is more easy to be synthesized than the single, so the cost of preparation is lower. We hope to apply it to molecule design of the new agriculture chemical. On the base of molecule design and structure-activity relationship research of pyrethric acid II and mixture of alcohol containing fluorine, we intend to get new pyrethrum ester that have higher activity and lower resistance.

另一方面，混合含氟对甲氧甲基苄醇和混合含氟对甲苄醇都是具有&混合氟效应&的高活性、低抗性的拟除虫菊酯醇组分，由于混合含氟醇的合成要比单一异构体的合成容易，成本较低，本文希望将其应用到新农药的分子设计中，用第二菊酸和一些含氟醇进行分子设计及进一步的构效关系的研究，筛选出一些高活性低抗性的拟除虫菊酯换代新品种。

Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在，所有的孩子都要在综合学校继续学习，所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地，使人们普遍认识到发展不能以牺牲农业为代价。