查询词典 benzyl chloride

The synthesis of benzyl benzoate from sodium benzoate and benzyl chloride by phase transfer catalysis process is studied in the article.

由苯甲酸钠和氯化苄通过相转移催化法合成了苯甲酸苄酯，考察了几种季铵盐类相转移催化剂的亲核取代反应性能。

Benzyl benzoate was synthesized using benzoic acid paste residua and benzyl chloride as raw material at the presence of TEA.

以反应代替分离，将膏状的苯甲酸釜残液碱化后和氯化苄反应，采用相转移催化技术合成苯甲酸苄酯来加以应用。

In the batch process of chlorination, the byproduct -benzyl bichloride comes out when the benzyl chloride content reaches 20%, which causes low single-pass chlorination depth, high consumption of raw materials, much operation cost, and serious contamination to the environment.

釜式反应生产过程中，氯化苄浓度达到20％时即有副产物二氯化苄产生，使单程氯化深度较低，原料单耗和操作费用高，环境污染较重。

A new chiral quaternary ammonium salt 1a was synthesized by the reaction of cinchonine and(2,4,6-)trimethyl benzyl chloride.Etherification between 1a and benzyl bromide,allyl chloride,or methyl give corresponding etherified quaternary ammonium salts 1b,1c,and 1d.

由辛可宁和2，4，6-三甲基苄氯，合成了一种新的手性季铵盐(1a)，并进一步用苄基溴、碘甲烷和烯丙基氯对分子中的羟基进行醚化，得到相转移催化剂1b、1c和1d。

Aim To study the synthesis of phase transfer catalyst-triethyl benzyl ammonium chloride and its catalytic activity in phase transfer catalytic reactions.

目的 研究相转移催化剂TEBAC（Triethyl Benzyl Ammonium Chloride，三乙基苄基氯化铵）的合成以及在相转移过程中的催化性能。

Under the optimal conditions, the conversion of benzyl chloride is nearly 100% during esterification, and the total yield of benzyl alcohol is higher than 98%, the percent of benzyl ether is lower than 2%.

氯化苄在酯化反应中基本反应完全，苯甲醇的两步总选择性可以达到98%以上，二苄醚的含量低于2%。

Benzyl ether is easy to condensed from benzyl chloride in the presence of alkali. In order to prevent production of benzyl ether, benzyl chloride must not contact with alkali.

由于氯化苄在碱作用下容易生成二苄醚，为了减少二苄醚的生成，必须避免氯化苄与碱的直接接触。

The optimal esterfication reaction conditions as following, the esterification temperature is 115℃, the initial mole ratio of benzyl chloride to sodium formate is 1:1, the volume ratio of water to benzyl chloride is 1:1, and the catalyst amount is 2% according to the quantity of benzyl chloride.

确定最佳的酯化工艺条件为：温度115℃，氯化苄与甲酸钠的摩尔比1：1，氯化苄与水的体积比1：1，催化剂量为氯化苄重量的2%。

During esterification of benzyl chloride and sodium formate, benzyl formate is esterilysis which is a reversible reaction, and the mole ratio of benzyl formate to benzyl alcohol is 3:7 because of the chemical equilibrium.

在氯化苄与甲酸钠的酯化反应同时存在甲酸苄酯的水解反应，并且甲酸苄酯的水解反应是可逆反应，受化学平衡的限制，在实验条件下的甲酸苄酯与苯甲醇平衡的摩尔比大致为3：7。

There are three different nucleophilic reagent respectively reaction with m-dinitrobenzene ramification at distint alkaline term:With the nitrobenzene 、 m-nirtobenzenesulfone sodium salt 、 2.4-dinitro chlorobenzene 、 m-dinitrobenzene for bottom thing, benzyl cyanide、 benzyl chloride、 benzyl chloropyridine、is a nucleophilic reagent reaction for under the different term proceeds a series reaction. At the same time ,discuss about the impact factor to nucleophilicity such as the number of attract electron group、 ability of attract electron and the nucleophilic substitution reaction part.

设计了三类不同的亲核试剂分别与活化芳环在不同的碱性条件下发生反应：以苄基氰、苄基氯化吡啶为亲核试剂，以硝基苯、间二硝基苯、间硝基苯磺酸钠、2，4-二硝基苄基氯为底物进行亲核取代反应；并且对亲核试剂的体积效应、溶剂效应对亲核性影响，底物上吸电子基团的数目、吸电子能力对亲电性的影响，以及亲核取代反应的发生部位受哪些因素影响进行探讨。

Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在，所有的孩子都要在综合学校继续学习，所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地，使人们普遍认识到发展不能以牺牲农业为代价。