查询词典 benzoyl-glycine

Part I, the Friedel-Crafts acylation on DAA and methyl dehydroabietic acid was carried out with acetyl chloride, benzoyl chloride or phthalic anhydride as acylating regents, anh- ydrous aluminum chloride as catalyst and with different solvents to compare with, we have got t- hree new compounds.

第一部分，分别以脱氢松香酸和脱氢松香酸甲酯为底物，乙酰氯、苯甲酰氯、邻苯二甲酸酐为酰化试剂，无水三氯化铝作催化剂，采用不同的溶剂及反应条件进行傅克酰基化反应，得到3个新化合物。

The latter is chlorinated in the side chains under free-radical conditions to give 2,4-dichloro-5-fluoro-3-dichloromethyl-1-trichloromethylbenzene. The latter is hydrolysed via 2,4-dichloro-5-fluoro-3-dichloromethylbenzoic acid, which can be isolated if necessary, to give 2,4-dichloro-5-fluoro-3-formyl-benzoic acid, the aldehyde group of which is reacted to give 2,4-dichloro-5-fluoro-3-N-hydroxyiminomethyl-benzoic acid, from which, with simultaneous conversion of the carboxyl group into the chlorocarbonyl group, water is eliminated using an acid chloride to give the nitrile 2,4-dichloro-3-cyano-5-fluoro-benzoyl chloride.

随后，在游离基条件下进行侧链的氯化，得到2，4-二氯-5-氟-3-二氯甲基-1-三氯甲基苯、后者被水解，经过2，4-二氯-5-氟-3-二氯甲基苯甲酸(如果需要此化合物可以分离)，得到2，4-二氯-5-氟-3-甲酰苯甲酸，将其醛基反应，得到2，4-二氯-5-氟-3-N-羟基亚氨基甲基苯甲酸，用酰氯从其中除去水，同时将羧基转化为碳酰氯，得到一种腈，即2，4-二氯-3-氰基-5-氯-苯甲酰氯。

Preferred examples of thermal initiators include persulphates especially sodium and ammonium persulphate, peroxides especially benzoyl peroxide, t-butyl hydroperoxide and lauryl peroxide, and azos, especially azobisisobutyronitrile.

热发起者首选的例子包括硫酸盐，尤其是钠，过硫酸铵的，过氧化物尤其是过氧化苯甲酰的吨丁基过氧化氢和十二烷基过氧化物，和azos，尤其是二异丁腈。

The synthesis of homocubane derivatives from 4, 6-dicarboxy homocubane was studied, several new compounds were synthesized, and the behavior of homocubanoyl chloride on some reaction was found to be similar with that of benzoyl chloride.

对由4，6—二羧基高立方烷合成不同的衍生物作了一系列研究，合成了一些新化合物，并发现了高立方烷酰氯衍生物与苯甲酰氯有相似的反应性。

Under catalysis of AlCl3, trans-1-chloro-3-phenyl-1-propen-3-one was first prepared using benzoyl chloride and acetylene in CH2Cl2 at 20~25℃, which the yield is 7% higher than that in CCl4 at 40~45℃.

通过对其反应条件的研究，首次用苯甲酰氯和乙炔在三氯化铝作用下合成出反－3-苯基－1-氯－1-丙烯－3-酮；并发现用二氯甲烷作介质在20~25℃下的反应产率，比用四氯化碳作介质在40~45℃下的反应产率约高7%。

Cellulose benzoate,the degree of substitution of which was calculated from the content of C determined by element analysis,was prepared from microcrystalline celluloseand benzoyl chloride under heterogeneous condition and characterized by FT-IR and~1H-NMR.

研究了微晶纤维素和苯甲酰氯在多相条件下合成制备纤维素苯甲酸酯的反应，通过元素分析所得碳的质量百分含量计算了产物的取代度，并系统研究了吡啶与N，N-二甲基乙酰胺或与三乙胺混合反应溶剂、苯甲酰氯与纤维素羟基的摩尔比r、反应温度和反应时间对D S的影响，用FT-IR和1H-NM R对产物进行了表征。

Such as,(1) Active Zincdust catalyzed the esterification reactions between benzoyl chloride and phenol or alcohol,which needed not solvent, warming and could fulfilled in a very short period (1-2min), andthe handling of the reaction mixtures was very simple. We believe it's the simplest and mosteconomic method for the synthesis of many aryl esters.

包括：(1)活性锌粉催化的酯化反应，在室温下即可反应，毋需溶剂，毋需加热，反应迅速(通常1—2分钟即可反应完全)，处理非常简便，相信目前是合成许多芳香酯最简便的方法，是一种值得加以推广的合成芳香酯的好方法。

Model compounds were synthesized from benzoyl chloride and diamine Ⅰ or diamine Ⅱ in NMP with anhydrous lithium chloride. Structures of model compounds were measured by melting point, FT-IR, element analysis and 〓H NMR. Reaction mechanism was from model reaction.

二胺Ⅰ和二胺Ⅱ分别与苯甲酰氯在含有LiCl的NMP溶液中合成模型化合物，采用熔点，FT-IR，元素分析，〓H NMR等方法对模型化合物的结构进行了表征，根据模型反应确定反应机理。

The biogenic amines in test samples were extracted by 10% trichloroacetic acid and then derived with benzoyl chloride. The HPLC analysis for the samples were conducted as the following condition: mobile phase was a gradient elution program of methanol and water, the flow rate was 0.8 mL/min.

用10%的三氯乙酸提取样品中的生物胺，采用苯甲酰氯衍生处理后，以甲醇/水为流动相，进行梯度洗脱，流速0.8 mL/min，紫外检测器波长为254 nm。

The only reference in the published literature to such a reaction was a note by Clark who reported-without experimental details-that benzaldehyde is converted to benzoyl chloride Indeed, in some cases,t-butyl hypochlorite has been known to effect substitution of hydrogen by chlorine.

在出版文学中仅有的参考这样一反作用was a指出经过克拉克，那苯醛存在在有些情形下的确使转而信仰苯酰氯化物在外面所报告的-实验details-的，t-丁基次氯酸盐已经被知道实现氢的代用在附近氯。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。