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New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene PolymerizationFacile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that:1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下:(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2,3-双(2,6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2,6-二[1-(2,4,6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上,研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响,研究表明:1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理,可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体;2、BET,XRD,IR,SEM,GPC和DSC研究表明,脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene Polymerization Facile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that: 1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下:(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2,3-双(2,6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2,6-二[1-(2,4,6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上,研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响,研究表明: 1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理,可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体; 2、BET,XRD,IR,SEM,GPC和DSC研究表明,脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

The tectonic evolution of southern Junggar basin can be classified into seven stages: stage of intracontinental rift from middle Periman to late Late Carboniferous; stage of weak extension and peneplane from late Permian to early Triassic; stable depression stage in middle-late Triassic; maximal basin formation phase in the setting of weak extension in early-middle Jurassic; inactive depressed basin formation phase in thrust setting in middle-late Jurassic; stable depression stage in Cretaceous and Eogene; foreland depressed basin formation phase in thrust setting in Neocene and Quaternary.

准噶尔盆地南缘晚石炭世以来盆地构造演化可划分为七个演化阶段:晚石炭世—中二叠世陆内裂谷作用阶段;晚二叠世到早三叠世处于弱伸展-稳定坳陷作用阶段;中、晚三叠世准平原化作用阶段;早、中侏罗世为弱伸展背景下广盆形成阶段;中、晚侏罗世冲断背景下的坳陷盆地形成阶段;白垩纪到古近纪弱伸展背景下的稳定坳陷盆地形成阶段;新近纪—第四纪为冲断背景下的前陆坳陷盆地形成阶段。

Of the five stages deformation, the exact ages of the (2) and (3) were determined by 40Ar/39Ar method as 290 and 259 Ma respectively.2. New results on the metamorphic belts and associated metamorphism of the Xiaopu metamorphic rocksBased on detailed microtextural observations and occurrence of typical metamorphic minerals, five metamorphic belts in the Xiaopu metamorphic rocks are identified. From the north to the south, they are biotite belt, garnet belt, staurolite belt, andalusite belt, and sillimanite belt. I suggested that the metamorphic belts occurred in the Xiaopu area belongs to the high temperature/low pressure series, may have resulted from the later Permian crust extension at ca. 290 Ma.3. I suggest that there may have been a Carboniferous backarc basin along the southern slope of the Harlik Mountain.Detrital Zircon SHRIMP U-Pb dating indicated that the sedimentary age of the Julideneng formation lithic sandstone must be later than late Devonian, most likely is Carboniferous rather than previously thought Precambrian. Analyses on its geologic setting, location of provenance, and sedimentary environment suggest the Carboniferous strata may form in a lagged backarc basin bounded by backarc uplifts.5. Reconstruction of the post-Paleozoic tectonic evolution history of the Harlik MountainThe tectonic evolution of Harlik mountains since the Paleozoic were reconstructed as followings:(1) arc-affinity magmative activities occurred during the middle-Ordovician to early-Silurian;(2) the middle-Silurian to late-Devonian was a back-arc uplift stage;(3) back-arc extension featured the Carboniferous period;(4) post-collisional extension and/then compression during Permian;(5) at the Mesozoic, differential uplift developed; and (6) the late Cenozoic is the intra-continental re-orogen stage.6. Primary estimation of the crust shortening is madeThe folded pre-Mesozoic strata were used to estimate crust shortening along the Harliknanshankou-Koumenzi, Shichengzi-Baishitou, and Qincheng-Xiaopu sections. Their shortening ratios are 16.2%, 19.8%, and 20.1% respectively corresponding crust shortening are 4.3, 9, and 11.3 km.

根据Ar-Ar热年代学研究,精确测定了早二叠世伸展变形和晚二叠世挤压变形的峰期时代分别为290Ma和259Ma.2、提出了关于哈尔里克山南麓小铺一带变质带和变质作用的新认识根据显微观察资料和特征变质矿物的出现,把小铺一带的变质岩由SW向NE方向依次划分为黑云母带、石榴石带、十字石带、红柱石带和矽线石带等变质带;初步确定该区的变质作用属于中温-低压型,变质作用发生的时代为290Ma左右,是该区早二叠世地壳伸展的产物。3、首次提出哈尔里克山南麓在石炭纪可能发育弧后盆地的新观点根据哈尔里克山南麓原"居里得能组"岩屑砂岩的碎屑锆石SHRIMP U-Pb定年,确认这套地层的沉积不早于晚泥盆世,很可能是石炭纪,而不是前人所说的前寒武纪;结合对其区域地质背景、源区位置和沉积环境分析,推测该区石炭纪可能为滞后弧后盆地和弧后隆起区构造背景。4、进一步证明哈尔里克山不发育与岛弧演化相关的泥盆纪岩浆活动根据对代表性闪长岩和花岗岩的锆石SHRIMP年代学研究获得的新资料,结合该区已有相关资料的综合研究,确定哈尔里克山岩浆岩分别形成于奥陶纪-志留纪和石炭纪晚期-二叠纪,不存在泥盆纪的岩浆岩,进而认为该区泥盆纪不属于岛弧环境。5、重建了哈尔里克山古生代以来的地质演化过程根据区域资料以及本次研究所获得的资料,把哈尔里克山古生代以来的构造演化划分中奥陶世-早志留世为岛弧、中志留世-晚泥盆世为弧后区、石炭纪弧后伸展、二叠纪为后碰撞伸展与挤压、中生代差异隆升和晚新生代陆内再造山过程等构造阶段。6、初步估算了哈尔里克山地壳缩短率和缩短量根据前中生代地层褶皱估算的哈尔里克山南山口-口门子、石城子-白石头和沁城-小铺三条剖面的地壳缩短率分别为16.2%、19.8%和20.1%,相应的地壳缩短量分别为4.3km、9km和11.3km。

Occurrence of tectonic heat event on late-Mesozoic in Ordos basin result from intensive thermal mobility of deep lithosphere on the late-Mesozoic,Thermal mobility of deep lithosphere in sourth region is stronger than in north region. Mantle occur underplating and thickness of lithosphere reduce, magma invasion and eruption occur on late-Mesozoic. Ordos basin be in weak extension environment on late-Mesozoic.

鄂尔多斯盆地中生代晚期构造热事件发生的根本原因在于中生代晚期岩石圈深部的热活动增强,盆地南部岩石圈深部热活动性更强,早白垩世鄂尔多斯盆地处于一种弱拉张的构造环境,地幔发生底侵作用,岩石圈减薄,发生岩浆侵入和喷发。

During early middle Jurassic period, Quemocuo formation in NQB was offshore lake deposition with marine feature, in SQB was shelf deposition, which indicted that an intense rifting and sea level rising with more large range, and consequently, eroding area was shrunk and deposition area was expanded.4. According to the result of stratigraphic surface features, division and correlation, and the paleographic characteristic, Qiangtang Basin during late Triassic -early middle Jurassic period could be divided into two basin developing stages with difficult tectonic nature, remnent epicontinental basin stage in Carian -early Norian of late Triassic and rifting basin stage in middle Norian of late Triassic - early middle Jurassic period respectively.

雀莫错组在羌北盆地为近海湖泊沉积,更具海相色彩:南羌塘主要为外陆棚沉积,反映羌塘盆地再次发生较强烈的裂陷作用和较大幅度的海平面上升,形成陆源剥蚀区缩小,沉积覆盖面增大的古地理面貌。4、根据地层界面特征、地层划分与对比结果和岩相古地理演化特征可将晚三叠世—中侏罗世早期羌塘盆地划分为两个不同构造性质的盆地发展时期,分别为晚三叠世卡尼期—若利早期的残留内陆表海沉积盆地发展与消亡时期和晚三叠世若利期中晚期—中侏罗世早期的裂陷盆地的形成与发展时期。

Results and Conclusions (1)MRI is better than CT to show the lesion of cerebellar fossa and brain stem.(2)Late radiation encephalopathy may be the result of immunal response to the damage of brain tissue and blood vessel after radiotherapy(3) 18 F-FDG-PET is a effective screenage examimation to diagnosis late radiation encephalopathy.(4)To some degree,the symptoms of the patients were alleviated after therapy with dexamethasome,mannital and vitamine B,etc.Late radiation encephalopathy ought to be given priority to prevention and treated vigorously as soon as possible.

结果和结论(1)CT对鼻咽癌迟发性放射性脑病的诊断有一定价值,但MRI对后颅窝和脑干病变的显示优于CT;(2)迟发性放射性脑病可能是放疗致脑组织血管损伤后引起免疫改变的结果;(3)18-氟代脱氧葡萄糖( 18F-FDG)-PET是诊断迟发性放射性脑病的有效的影像学检查方法;(4)本组患者经应用激素、甘露醇、多种维生素等治疗,均取得不同程度的改善。

Relax's time,I would hope use favorite way to spent it,The end of the morning's course,When my partner Jane said to me,It so happened have two movie tickets,At 19:00,Whether with me together go to watch movie,After my heart feel delight,Though we have been reached before the consensus,Prepare to look at 19:10 the movie,《Red Cliff》,Actually,I hope to watch a local movie in china,I franked told she i have not seen the movie of the first half,But she said that will not affect,The pm 7:00,I already in the cinema At the door of wait for a long time,Has yet to see my companions,Maybe i in the kill of time,I watch of the film table,Screening of the it seem chinese movie,《Red Cliff》and《Madagascar》2 Some less the introduction of the movies,Despite I would not be surprise,But I would watch the 《Red Cliff》 should the good choice,I saw Jane,She let me wait a full 15 minutes,I think he will find for themselves better reason,To avoid being late forpsychological,Her own apology for being late because of traffic congestion on the road,Although I am a taxi to the,I feel Chengdu Crowded is Traffic,The sky already dark,The streets are constantly whistle sound,Finally,I can not on forgive her,We enter the cinemas,Cinema is no Imagine as spacious,But is a very delicate environment,The film should have been broadcast,I think we are 10 minutes late,So we quietly went to the location,To watch the movie,I feel to have chinese classical music,To surround the movie,Aslo let me fusion of the atmosphere in China,Maybe the movie has some humorous language,But sometimes have small number of comments Voice,At least that let me feel sick discomfort,We are seriously watch to the movie,Cinema is about to go out,Maybe this is for me is breath of fresh air,The best,But is the helpless's choose,Very fond three kingdoms of my friend,In U.S,They are very fond the Japanese game 《Dynasty Warriors》,They say he is cool,No have complex plot,Can let you full of crazy and direct,These maybe can to me as a reference,Because I do not know three kingdoms of lot,Jane asked in how I feel when,I told her I like Zhou Yu,,WHich have a scene,When he performed the sword dance when,In front of Xiao Qiao,I feel the ancients are the comfort and fine and smooth, And has a strong China atmosphere,Although in my thoughts,Zhuge Liang is the wisdom,And Cao Cao more are poetry and brutality,Maybe They are contrary,But i not longing the latter,In the movie has a Cao Cao poetry recitation,I ever for that memory,Is clearlr,It makes me feel he to near for me,My favorite watch movie,Maybe in U.S,Many people will because leisure watch movie,In U.S,Movie ticket prices low,That let me feel the can more depth and perfect sound quality,In U.S,I only know the Chinese movie is 《Crouching Tiger, Hidden Dragon》,This is my ever for China's thought,Martial arts and essence's experience,I like the director Ang Lee,He's movie has the ease,And sometimes,In heart was very heavy,Without violence,I feel that the oriental atmosphere,And bamboo's quiet,Maybe and 《Red Cliff》It is different,《Red Cliff》's scenes let me feel endless grand,Although i have not seen the upper part,Many Hollywood great's works,Filled more is behind the emotional and caring,They are usually war deep to aware of human nature,China's ancient war, Full of alertness,Also is the wisdom of the struggle,Even if I am fell,It still is a beautiful works,But I believe,It will become my forever memory,I like the memory,Chinese movie memory,Although it will never be able to replace the first

轻松的时间,我会选择用喜欢的方式度过它,结束了上午的课程,当我的工作伙伴珍对我说,刚好有两张电影票,下午7点,是否一起去看电影,我内心已经为此感到愉快,尽管我们之前已经达成了想法,准备看19点10分的电影《赤壁》,实际上我希望能够在中国看一部中国电影,我坦诚地告诉她并没有看过它的上部,但她说着并没有影响,下午7点,我已经在电影院门口等候多时,很迟没有看见我的同伴,也许在利用时间,我看着电影表,放映着似乎中国的电影《赤壁》,和《马达加斯加》2一些为数不多的引进电影,尽管我并不会感到惊奇,但是我想看《赤壁》,应该是不错的选择,我等到了珍,她让我等了足足有15分钟,我想她会为自己的找到更好的理由,来逃避迟到的心理,她道歉自己因为路上塞车而迟到,尽管我是计程车来的,我感到了成都交通很拥挤,天空已经黑了,街道不断是鸣笛声音,终于我无法不原谅了她,我们进入了电影院内,电影院不是想象那样宽敞,却是一个精致的环境,电影应该已经开始了播放,我想我们已经迟到了10分钟,所以我们安静走到位置,观看影片,我感到浓厚的中国古典音乐,包围着这部电影,也让我在中国气氛中间融合,也许是影片中有着幽默的语言,但有时会出现少量的评论声音,至少这让我感到不适,我们认真观赏完了这部电影,即将走出电影院,也许这是对我是呼吸新鲜空气,最佳的,可是无奈选择,我的朋友很喜欢三国,在美国,他们很喜欢日本的游戏《三国无双》,他们说他很酷,并没有复杂的剧情,可以让你充满疯狂和直接,这也许可以给我作为参考,因为我并知道三国的很多,在珍问我觉得怎么样的时候,我告诉她我很喜欢周瑜,其中有一个场景,他舞剑的时候,在小乔面前,我感到中国古人的舒适和细致,并有着浓厚的中国气氛,尽管在我的想法中,诸葛亮是智慧的,而曹操更多是诗歌和残忍,我不渴望后者,影片有一首曹操诗歌的朗诵,我曾经对那一首的记忆很清晰,它让我感到了他的靠近,我很喜欢看电影,也许在美国,很多人会因为闲暇看电影,美国的电影票价很低,这却让我感到了更加深入和完美的音质,在美国,我只知道的中国电影是《卧虎藏龙》,这是我对中国曾经的想法,武打和精华的观点,我很喜欢李安这位导演,他的电影有着缓和,和有时心里很沉重,没有暴力,《卧虎藏龙》让我感到了那段东方的气息,和竹子的舒适,也许它和《赤壁》的不同,《赤壁》的场面让我无尽感到宏伟,尽管我没有看到它的上部,很多好莱坞伟大的作品,充满更多的是背后的情感和关怀,他们往往是在战争深处而察觉人性,而中国古代的战争,充满着机警,也是智慧的斗争,即使我感到,它仍然是一部美丽的作品,但是我相信,它将成为我永远的记忆,我很喜欢这种记忆,中国电影的记忆,尽管它永远无法取代第部

Whether if you vs. of she totally it agree, she then will 258 ten thousand picture if disagree you, Show you understand if you make what atmosphere control very much romantic at all then, You will certainly love veteran if, you at all enough ripe if you go and let she often too then, She will feel irritated and oily but if you go and look for she, she will blame if any of generals wearing it you cheat emotional you of she, She will say that you are that what the play-boy wore is a bit more tattered , then you are a stolid fellow if you are jealous, She will it says to be incorrect like this but if totally jealous you, she again can think you like she you if you attempt and flirt to her at all, She will think you respect she but if well-behaved you, she again can think you like if she you come late one minute, She will complain if oneself late she how tired and more bitterly does it wait for, she will say girl it dates late to be natural if you go and look for friend of you, She will say if your picture copycat is her, she will talk about \" oh, this is very natural, Girl \" if you kiss she quickly, she will very much cold and detached if you kiss too much to say you everywhere like this, She will yell that you ate her bean curd if you have not looked after her while crossing the road, You lack morals if you look after she cross the road, she again can say this whether if trick you of man stare at a certain woman carefully then, She will criticize you to flirt and stare at to girl student she think other man everywhere, She will say that they will just appreciate if you speak with her, she hopes that it is all right that so long as you listen to if you only listen attentively to, She you speak with her again Man has seen that may say : Fly to the sky, you create take these name to have simple and complicated and weaker so living beingses woman, But so intrepid to let people angry and Cupid, please tell me should how make.

是否如果你对她全部它同意, 268,000 将然后想象如果不同意你的她,让看如果那时你确实做非常浪漫的空气控制的,你理解,你当然将爱老战士,如果,你确实足够成熟你去被让她也那时经常,她感到将激怒和油性但是如果你去寻找她,她责备将如果将军中任何人穿它你骗取易激动你她,她将说你是花花公子穿的是有点多变得破烂,然后如果你妒忌,你是一个不易激动的人,她将错误象这样但是如果全部妒忌你说,再次的她认为能你喜欢她你你试图并且确实给她调情,她认为将,你尊重她但是如果行为端正你,她再次认为能你喜欢如果她你为一分钟晚来,她抱怨将如果自己后她多疲倦和更极其做它等,她将说女孩日期是自然的后期你去寻找你的朋友,她将说是否你的照片盲目模仿者是她,她将谈论\&噢,这非常自然,女孩\&如果你吻她迅速,她将很多冷和分开你吻那么多不会象这样到处说你,她将号叫如果你在穿过道路时没照看她,你吃她的豆腐,你缺乏品行你照看如果她穿过道路,再次的她说能这是否如果计谋你人那时仔细注视一定妇女,她将批评你调情并且对她到处认为其他男人的女生注视,她将说他们将感激是否你与她谈话,她希望它好那,只要你听是否你只注意听,她你再次与她讲男人已经看见那可以说:飞往天空,你创造花费这些个名字喝简单和错综复杂和更弱的如此活着的生物妇女,但是如此无畏忿怒和丘比特,请我怎样挣。

The south-north united tectonic environment and tectonic pattern does not exist. The east-west trend thrusting Nappe structure of Majiatan and Hengshanpu can not represent the whole western margin of Ordos. The attempt to solve the regional tectonic problem with simple tectonic pattern is against the geological theory, especially in the Helan Mountain region.(2) After the geochemical data analysis of Ruqigou basalt in Helan Mountain, the article illustrates that it belongs to continental rift basalt which appeared in the late-Triassic and early middle Jurassic. Meanwhile the article states that the region is located in the rift environment of an extension background and Rudigou is located in the central part of the rift.(3) The article illustrates that the western ridge of Helan Mountain used to be on a slope and topography slowly declines from west to east after analysis and demonstrations of the distribution under XiaoSongshan bedding fault. Through comprehensive analysis of the no-strong deformation and bedding fault features, the article states that the Xiaosongshan bedding fault used to be gravity slip detachment structure and it represents the extension from the east to the west. Based on the above and analysis and demonstrations of isotope age and track datting, the article illustrates that the ? characteristic of the east of the western ridge of Helan mountain being higher than the west is the result of its late tectonic reverse.(4) Through comparison between Rujigou region Mesozoic Era late Triassic period-early and middle Jurassic period deposit and that of Ordos Basin and the analysis of the late Triassic period extension and early -middle Jurassic Period deposit povenevance it sets forth that during the period, Rujigou region was part of a large deposit basin which was closer to the northern povenevance and farther from the western povenevance.

以马家滩和横山堡为代表的东西向逆冲推覆构造模式,在整个鄂尔多斯盆地西缘不具有全区统一性,那种试图用单一的构造模式解决本区构造问题的尝试,无疑是与地质实际相悖的,尤其是对贺兰山地区;(2)通过对贺兰山汝箕沟玄武岩地质地球化学测试分析,提出其为大陆裂谷玄武岩,其形成时代为晚三叠—早中侏罗世,并通过该玄武岩的稀土和微量元素的测试分析资料进行了多种判别分析,最终确定该区处于拉张背景下的裂谷环境,汝箕沟地区大致处于当时裂谷的中心部位;(3)通过对小松山断层面之下地层分布规律,结合其变形特征的分析论证,认为当时贺兰山西麓处于一个由东向西平缓抬高的斜坡环境,并通过小松山断层面之下地层的非强烈变形及顺层断层特征等的综合分析,认为贺兰山西麓的小松山断层原本是一重力滑覆断层,它代表了近东西向的拉张,在此基础上通过裂变径迹测试资料的分析论证对其做了进一步认定,目前贺兰山西麓东高西低的剖面特征是该区后期构造反转的结果;(4)通过对汝箕沟地区中生代晚三叠世—早中侏罗世沉积与鄂尔多斯盆地内部的对比、晚三叠世延长组及早中侏罗世沉积物源和水流向分析,认为该时期汝箕沟地区为一更靠近北部物源,而距西部物源明显较远的沉积环境,是一更大型沉积盆地的一部分。

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This one mode pays close attention to network credence foundation of the businessman very much.

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Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

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