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The structure of the compound 〓(1) consists of a pentanuclear molecule which is center-symmetric. One W atom is coordinated by four S atoms and two Cu atom. As expected, the Fe atoms are sandwiched between two staggered pentadiene rings. The most interesting aspect of the structure is that Fe-C-P-Cu-P-Cconstitutes a distorted hexagon and Fe-Cu-W-Cu-Fe is nearly in a line.

结构是以W原子为对称中心含有五个金属原子的线型结构，W原子与四个μ〓-S和两个Cu原子配位；Fe原子在两个戊二烯环中间形成一个三明治夹心结构；Fe〓-C〓-P〓-Cu〓-P〓-C〓-构成扭曲的六边形，由于两边1，1'-双二茂铁配体的作用导致Cu-S键的拉长。

Based on the above experiments, the author studied the mixed metallic pillared and modified montmorillonites. The experimental result indicated that the microporous structure of Fe-Al-PLMs was affected by the changing of interlayer Fe-Al polymer with different Fe/Al ratio. But the presence of Al iron was helpful to incorporate Fe iron into interlayer of montmorillonites.. Introducing Zr helped Al-PLMs getting better larger spacing, thermal stability, surface area and pore volumes. Its successful to apply Zr-Al-PLMs to treat wastewater containing Cr iron. The experiment of modifying Al-PLMs by PVA showed that the order of adding starting materials (Al-pillaring solution, PVA, montmorillonite solution) was related to the property of Al-PLMs. The PVA as precursor was beneficial for Al to go into interlayer of the clay and to form larger basal spacing porous clay. The surface area and pore volumes of Al-PLMs increased mainly because of increasing the external surface area and mesoporous volumes after acid-activating. This conclusion confirmed that the microporous structure of pillaring clay depends upon the interlayer pillar.

实验结果表明：在Al-PLMs中引入Fe离子，不同Fe／Al比制得的Fe-Al-PLMs因层间的Fe-Al聚合离子结构不同而影响其微孔结构，但羟基Al离子的存在有利于Fe离子进入蒙脱石层间；在Al-PLMs中引入Zr离子，有助于其层间距、比表面积、孔体积增大，所得Zr-Al-PLMs应用于含Cr废水处理效果显著；PVA改性后的Al-PLMs其物化性质变化与铝柱化剂、PVA溶液、蒙脱石溶液三者不同添加顺序有关，说明PVA的前撑有利于Al进入蒙脱石层间得到较大层间距的Al-PLMs；经酸化处理得Al-acid-PLMs，其比表面积增大以外表面积为主，孔体积增大以中孔为主，这也证实了柱撑蒙脱石的微孔结构取决于其层间的柱化物。

Dissimilatory Fe oxide reduction under anaerobic condition is a process which is an anaerobic respiration with Fe as the terminal electron acceptor. This anaerobic respiration showed important environmental significances. Dissimilatory Fe reducers can use diverse electron acceptors including many toxic heavy metals and metalloids such as Mn、Cr、Co insides Fe. So these toxic metals were detoxified or were immobilized reductively.

这种厌氧呼吸作用具有重要的环境学和地学意义，Fe还原微生物可利用除Fe以外的许多其它电子受体包括许多有毒重金属和类金属，如Mn、Cr、Co等，从而对这些有毒重金属起到还原解毒或还原固定的作用；还原过程还可促进一些有机污染物的降解； Fe氧化物的还原偶联着Si、P等元素的变化，对提高这些营养元素的有效性发挥着重要作用。

The Fe^0 concentration and pH had optimal values during the decolorization of X-BR in Fe^0-anaerobic biological system. When Fe0 dose, initial pH value and X-BR concentration were 400 mg/L, 7 and 100 mg/L respectively, the decolorization rate of X-BR in the integrated system could reach up to 90% after 68 h reaction. Compared with pure Fe^0 and pure microorganism treatment systems, it could be improved about 40% under the same experimental conditions. In addition, the analysis result of UV-vis spectrogram indicated that Fe^0 could promote effectively biodegrading of anthraquinone dye X-BR and its intermediate products.

结果表明，在Fe^0-厌氧微生物体系中，Fe^0投加量和pH值均存在最适宜值，当两者分别控制在400mg/L和7，染料初始浓度和反应时间分别为100mg/L和68h时，该体系脱色率可达到90%以上；与相同反应条件下的纯Fe^0、纯厌氧微生物体系相比，该体系的脱色率提高近40%根据紫外可见光谱分析，Fe^0可有效促进厌氧微生物对X-BR及其中间产物的降解，实现完全脱色。

But when Fe/D113 precursor is pyrolysed in the range of 400-700℃, the crystal structure of the iron particle is different. The products are mainly iron oxides andα-Fe as Fe/D113 precursor pyrolysed at 500℃, and as the pyrolytic temperature increases to the range of 600-700℃,α-Fe and Fe_3C are observed. Meanwhile, Al_2O_3、MgO、MgAl_2O_4 were observed in Al/C, Mg/C, Al-Mg/C which were prepared from D113 resin at 1000-1300℃.

而在同样的条件下热解载铁树脂(Fe／D113)，热解产物中铁的晶体结构与热解温度有关，400℃热解产物为铁的氧化物；500℃热解产物为体心立方结构的单质铁；600-700℃的热解产物为bcc单质铁和铁的碳化物(Fe_3C)。1000-1300℃热解含Al、Mg及Al-Mg的D113树脂制得的Al／C、Mg／C、Al-Mg／C材料中Al、Mg主要以Al_2O_3、MgO、MgAl_2O_4形式存在。

The temperature range of phase transformation from γ-Fe to α-Fe is 300-550℃: the activity of carbon atoms in solid solution of α-Fe would be increased with increasing the annealed temperature, and the diffusion of carbon atoms results in analogue state of different Fe configurations.

Fe相向α-Fe相转变的温度范围为300-550℃；α-Fe固溶体中的C原子的活度随退火温度的提高而提高，C原子的扩散导致不同的Fe原子组态趋于一致。

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" I' d like to get some rough idea about music in the baroque ear, please."

请简要介绍一下巴罗克时期的音乐，好吗？

The results showed that the peak latency and pattern of SEPs elicited by electrical needling in LI-l1 and MP were similar. The amplitude of SEPs elicited by electrical needling in LI-l1 was higher than that of MP. There was no obvious SEPs generation when MM was electrical needling.

结果显示，电针刺激曲池穴和其邻近桡侧伸腕长肌运动点诱发性脑电波的波形和波峰时间是类似的，只是穴位的诱发性脑电波波幅较大，而电针刺激非穴位点并没有明显的诱发性脑电位。