查询词典 atom

The bay area has no substituent and has electron-withdrawing groups,such as bromine atom,cyano-group and 4-formyl phenoxy group compounds have strong absorption in 525 nm,when excitated them,they have strong yellow and salmon pink luminescence bettwen 538 and 566 nm.When introduce electron-donating substituents,such as phenoxy group,morpholinyl,piperidinyl and n-butylamino group,the absorption bathochromic shift while the electron-donating ability is improved,bettwen 536 and 692 nm have strong absorption,reach to the near-infrared region. When excitated them,only the phenoxy group compound has strong salmon pink luminescence in 572 nm,the others have no fluorescence.

其中，港湾位无取代的以及含吸电基团(—Br、—CN、对甲酰基苯氧基)化合物在525 nm左右处均有很强的吸收ε＞10~4M~(-1cm~(-1)，当光激发时，港湾位无取代、溴代和氰基取代物发出538～547 nm的强烈黄色荧光，对甲酰基苯氧基取代物则发出566 nm的强烈橙红色荧光；含供电基团(苯氧基、吗啉基、哌啶基、正丁氨基)化合物随着供电子能力的增强，吸收发生红移，在536～692 nm处均有很强的吸收ε＞10~4M~(-1cm~(-1)，达到了近红外区，当光激发时，只有苯氧基取代物发出572 nm的强烈橙红色荧光，而含氮供电基取代物均发生了荧光淬灭。

Computationalresults indicate that the no-planar trans-benzanilide is the most stable structure. The spectra indicate that the Franck Condon region photodissociation dynamics have multidimensional character withnine activemodes. The intensity of υ24 mode in methanol is much stronger than that in acetonitrile. Compared with fatty amides and benzamide, phenyl substitution for H atom on-NH2 group makes C=O solvent effects disappear.

结果表明，苯甲酰苯胺的非平面反式结构为最稳定结构；在Frank-Condon区域内，苯甲酰苯胺主要由9个活性振动模组成；其中ν24（苯环上C＝C不对称伸缩振动和CCH的面内弯曲振动，NH面内弯曲振动）振动模在甲醇溶剂中的强度远远大于其在乙腈的强度；与脂肪酰胺类化合物和苯甲酰胺的研究结果比较发现，苯基取代－NH2上的H原子使得C＝O不再具有明显的溶剂效应。

Different e--donors and e--acceptors are incorporated at the phenyl ring of the benzothiazole to decipher the relationship between basicity of nitrogen atom and thermochromic phenomenon.

我们并且合成出其他不同的电子与体及电子受体的香豆素衍生物，来说明取代基的立体效应与电子效应对整个热致变色现象的影响。

Next HOMO or HOMO-1 for the radical cations calculated by the ab initio 3-21+G^* method, and the atom-pair interaction energy determined by NMDO calculation, it is shown that when n is equal to or largey than 3 in the bridge chain (CH2)n for bicyclo diamine radical cations, the bridgehead nitrogen atoms form a weak N, N'-three-electron σ-bond through space.

通过比较这些阳离子几何构型，HOMO和NHOMO(即NextHOMO和HOMO-1)，和由MNDO计算确定的原子对作用能，表明当二氮双环游离基阳离子的桥链(CH2)n的n≥3时，桥头氮原子通过空间相互用用形成了一个弱的N，N'-三电子σ键。

Reaction coordinate calculations show that for all of these phosphodiesters the alkaline hydrolysis follows a one-step bimolecular mechanism initialized by the attack of hydroxide ion at the phosphorous atom of the ester.

反应坐标计算表明所有这些磷酸酯的碱性水解均遵循一步历程双分子反应机理，磷酸酯的水解由氢氧根对酯上的磷原子的亲核进攻开始。

Reaction .coordinate calculations show that for all of these phosphodiesters the alkaline hydrolysis follows a one-step bimolecular mechanism initialized by the attack of hydroxide ion at thephosphorous atom of the ester.

反应坐标计算表明所有这些磷酸酯的碱性水解均遵循一步历程双分子反应机理，磷酸酯的水解由氢氧根对酯上的磷原子的亲核进攻开始。

The invention comprises a cyclopalladated catalyst with axial chiral binaphthyl backbone containing phosphine ligand as well as the synthesis thereof, and the application of the catalyst with cyclopalladated catalyst with axial chiral binaphthyl backbone containing phosphine ligand with a similar structure to the hetero atom norbornadiene ring cleavage reaction through an asymmetric catalytic organic boron agent.

本发明包括一类具有轴手性联萘骨架含膦配体的环钯催化剂及其合成，以及其与具有类似结构的轴手性联萘骨架含膦配体的环钯催化剂在不对称催化有机硼试剂对杂原子降冰片二烯开环的应用。

A series of novel chiral aminophosphine ligands with binaphthyl backbone and partially reduced binaphthyl backbone were synthesized from optically pure NOBIN and H〓-NOBIN respectively. The effects of binaphthyl backbone and substitutes at the phosphorous atom on Pd (0)-catalyzed allylation of racemic 1, 3-dipheylprop-2-en-1-yl acetate with dimethyl malonate were systematically investigated.

从NOBIN出发合成了一系列膦上含有不同取代基的氮膦配体MAPs以及含有被部分还原的联萘骨架的氮膦配体H〓-MAPs，将此两类配体运用于钯催化的乙酸1，3-二苯基烯丙基酯与丙二酸二甲酯的反应中，考查了膦上取代基和配体骨架对反应的影响。

According to yoga ,the pranamaya kosha forms the fine network through which prana flows.it is known as the pranic,etheric or bioplasmic bldy.this energy body is said to have the same shape as the physical body.however,through certain yogic techniques,concentration and visualization,te practioner is able to make it expand and contract ,especially through the technique of prana vidya.if our perception was finely attuned to the pranic body ,we would see a body of light in which there are thousands of delicate ,wire like structures conducting shakti or energy.these wire-like structures are the nadis or energy flows.the shiva samhita says that altogether there are 350,000 nadis in the body ,the prapanchasara tantra says 300,000 and the Goraksha sartaka says 72,000.there are thousands upon thousands of nadis within the substructure of the gross bosy and they distribute consciousness and prana to every atom.

根据瑜伽中说的，能量的混合形成网络，促成能量流的形成。能量、空的属性被称为是植物性神经属性的身体。能量和肉体的身体是同样的容积的。全，通过练习某些瑜伽技巧，特别是通过某些独特的呼吸方法，集中和内观，那么练习者就能够让扩大收缩强能量。如果我们能够更好的掌控能量的身体，我们就能够看见成千上万个微妙的、线状结构的光芒掌握着能量。那么SHIVA SAMHITA说在身体中总共有350，000个通道。THE PRAPANCHASARA TANTRA 说有300，000个，TEH GORAKSHA SARTAKA说有72，000个，总而言之，意识和能量就是通过这些成千上万的通道被分送到身体的每一个细胞的。

The structure is a distorted triangular bipyramid with five coordinated central tin atom.

配合物中锡原子呈五配位畸变三角双锥构型。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了