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The copper atom is in a planar coordination site of [N_2O_2] and it devites from the mean plane by only 0.80 pm. Byπ-πstacking interactions, a alabastrine structure was obtained.(2)Schiff-base complex [Cu(H_2O)]·H_2O, where H3GS is the 3-carboxyl -salicylidene glycine, was synthesized and characterized by elemental analysis, IR spectra and single-crystal analysis. The crystal belongs to monoclinic system, space group P2(1)/c, a=848.46(3)pm, b=681.54(3)pm, c=1967.16(8)pm,β=95.8210(10)°, Z=4, R_1=0.0279, wR_2=0.0724. The copper atom is in a square-pyramidal field with the base

结果表明该晶系属单斜晶系，空间群P2(1)/c，晶胞参数：a=848.46(3)pm，b=681.54(3)pm，c=1967.16(8)pm，α=90°，β=95.8210(10)°，γ=90°，Z=4，R_1=0.0279，wR_2=0.0724，Cu原子位于轻微变形的四方锥场底心，底面被氮原子、酚氧原子、甘氨酸羧基的一个氧原子和一个水分子氧原子占据，而甘氨酸羧基的另一个氧原子占据相邻分子的锥顶，因而形成一维链状结构；合成了单核双聚配合物Na_2[Cu_2_2]·2H_2O ，铜三核配合物Cu_3_2·5H_2O和铜锌异三核配合物ZnCu_2_2·5H_2O，并用元素分析，IR光谱，电子光谱和磁化率测定对配合物的组

The alkoxyl group at 2-position is affected by the steric repulsion due to the two methyl groups at 1, 3-position, which causes the oxygen atom of alkoxyl group to deviate from the aromatic ring plane, hence, the conjugation effect of the oxygen atom with aromatic ring decreases

对于IV〓、IV〓，其1，3-位两个甲基对2-位烷氧基产生空间排斥作用，使2-烷氧基氧原子偏离芳环平面，烷氧基对芳环的助色作用受到削弱。

Halohydroxylation reaction of allenyl sulfides occurs predominately with the β,γcarbon-carbon double bonds with the halogen atom bonded to the middle carbon atom of the allene moiety.

在1，2-联烯基硫醚分子中由于同时存在着硫原子和具有两个相互垂直π-键的累积双烯结构，使其具有一些特殊的反应性能。

In this thesis, the resonance fluorescence spectra of a A-type three-level atom is calculated, which is driven by two bichromatic fields having the same difference of the frequency. In addition, the influence of the relative phase difference on the fluorescence spectra are considered. It is found that the fluorescence spectra of the atom are deeply depend on the relative difference and the appearance and cancellation of the fluorescence are obtained by changing the relative phase difference.

文中以具有相同频差的两个双色场驱动下的三能级Λ型原子为模型，计算了其共振荧光谱，考虑了两个双色场的相对相位差对谱线的影响，结果表明：原子的荧光谱强烈地依赖于驱动场的相对相位差，可以利用相对相位差的改变对荧光的产生和抑制加以操纵。

Aura: is the bioplasmic energy around an object and life form. It contains divine atom, proton, electron, neutron, light, atom, proton, electron, neutron, anti-proton, photon, anti-electron, antineutron, and also anti-energy and antimatter field.

它含有神性的光，原子，质子，电子，中子原子，电子，中子，原子质子，反-质子，光子，正电子，反中性子，同样也有反-能量和反物质粒子在光环里存反物质粒子反物质粒在和由光环或金场金场组成。

In the complex, the tin atom is hepta-coordinated in a distorted pentagonal bipyramid including a bridging pyridyl N atom, by which the one-dimensional infinite chain is formed.

结果表明，该化合物中锡原子配位数为7，处在畸变五角双锥配位场中，化合物通过吡啶基氮原子的桥连作用形成了一维无限链状结构。

In the 2A1 distorted trigonal bipyramid structure ,the single non equivalent Ga atom has the population of 4s 4p ,while the two equivalent Ga atoms have the population of 4s 4p .this compares with a Ga population of 4s 4p in the undistorted D3h structure ,hence the jahn-teller distortion causes depletion of the charge density on the 4s orbital of the non-equivalent Ga atom, and enhancement of charge density on the 4s orbital for the two equivalent atoms .an opposite trend is observed for the 4p orbitals of these Ga atoms .the P population for the two equivalent atoms is 3s 3p .the populations of the other 2B1 state with the edge-capped tetrahedral structure are similar with the exception that all three Ga atoms have similar but not identical populations .

在2A1被变形的三角bipyramid结构，唯一非等效Ga原子有4s 4p的人口，而二个等效Ga原子在未变形的D3h结构有4s 4p 。this的人口和4s相比4p的Ga人口，因此jahn出纳畸变在non-equivalent Ga原子的4s轨道导致电荷密度的取尽，并且电荷密度的改进在4s轨道为二个等效原子。an在趋向对面对这些Ga原子4p轨道被观察。the人口为二个等效原子是另一个2B1状态3s 3p 。the人口与边缘加盖的四面体结构是相似的P 除之外全部三个Ga原子有相似，但不相同人口。

The result is that both tin atoms are five-coordination, have a distorted trigonal bipyramidal geometry with an additional week interaction between another oxygen atom and tin atom.

分子中四个羧酸酯基有桥联双齿和单齿两种不同的配位模式；在内环锡和外环锡的配位单元中，锡均形成具有五配位的畸变三角双锥配位构型，同时另有一氧原子与中心锡原子之间有弱相互作用。

It is found that in this structure the molybdenum atom is coordinated by six sulfur atoms of three 1, 1 -dicynoethylene 2 ,2 -dithiolate(i-mnt2 -) ligands and a terminal oxygen atom, forming a distorted pentagonal bipyramidal structure.

结构分析结果说明Mo原子与三个配位基的六个硫原子和一个端基氧形成扭歪五角双锥结构。

In all those complexes, no matter which conformation IDA assumes (mer- or fac-style), the two 0 atoms of 1N2O are both from carboxylic hydroxyl. However, by comparing the bond length, we can find that O(4) and O(2) atom is from different group in this complex, 0(4) atom from carboxylic hydroxyl, whereas, 0(2) from carboxylic carboxide.

值得注意的是：在这个双核配合物中，我们首次发现一种新颖的配位方式：IDA上与金属离子配位的三齿螯合原子是亚氨N原子、一个羧基上的羟基O原子和另外一个羧基上的羰基O原子。

You can do some assertiveness training.

你可以进行一些自信训练。

We were well on the path to making a rear-wheel-drive global platform," says Mays."

我们正致力于建立一个后轮驱动的平台，"Mays这样说道。"