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The invention comprises a cyclopalladated catalyst with axial chiral binaphthyl backbone containing phosphine ligand as well as the synthesis thereof, and the application of the catalyst with cyclopalladated catalyst with axial chiral binaphthyl backbone containing phosphine ligand with a similar structure to the hetero atom norbornadiene ring cleavage reaction through an asymmetric catalytic organic boron agent.

本发明包括一类具有轴手性联萘骨架含膦配体的环钯催化剂及其合成，以及其与具有类似结构的轴手性联萘骨架含膦配体的环钯催化剂在不对称催化有机硼试剂对杂原子降冰片二烯开环的应用。

The structure is a distorted triangular bipyramid with five coordinated central tin atom.

配合物中锡原子呈五配位畸变三角双锥构型。

Crystal structural analysis reveals that, because water molecules bond to Cu atoms, the dhbd ligand can only adopt a hydroxyl oxygen atom to bridge two reversed U-shaped subunits into a novel centrosymmetric dual-U-shaped tetranuclear Cu structure. Each U-shaped frame consists of two crystallographically distinct Cu atoms, two dpphen ligands and one coordinated water molecule.

晶体结构分析表明，由于水的配位阻断， 2，3-二羟基丁二酸根仅通过单羟基氧桥联两个U形双核亚单元形成具有一个对称中心的双U形四核结构，其中U型亚单元包含晶体学上不对称的2个Cu原子、1个2，3-二羟基丁二酸根、2个4，7-二苯基-1，10-邻菲咯啉和1个配位H2O分子。

If monomer passes atom to transfer freedom radical group above all reacts, attainable extreme contains haloid atomic polymer, and haloid and atomic itself can serve as the raw material that folds nitride, click reaction to come true to be transformed further to polymer structure to use thereby offerred a possibility, golas [10] did special overview for this.

假如单体首先经过原子转移自由基聚合反应后，则可得到末端含有卤素原子的聚合物，而卤素原子本身可以作为叠氮化物的原料，从而为采用点击反应对聚合物结构实现进一步改造提供了可能，Golas等[10]为此做了专门的综述。

An atom other than carbon in the structure of a heterocyclic compound.

碳环的有一个仅由碳原子组成的环的，如苯

The rest positions of 〓 unit are occupied by water and an oxygen atom of carboxylates from another type of ligand. With two carboxylates of this type of ligand, two ladderlike long chains are connected to form one-dimensional ladderlike chain structure.

第二类配体中每个羧酸根的一个氧原子与水分子饱和四面体结构单元余下的位置，并连接两个梯形长链形成一维梯形链状聚合物。

The main idea is tolift the band degeneracy at high symmetry points in the Brillouin zone of crystals bylowering the structure symmetry of crystal.One way is introducing nonspherical atomconfigurations,another is introducing anisotropy in atom dielectricity.

设计的核心思想是通过降低光子晶体结构的对称性，消除光子能带在晶体的布里渊区高对称点上的本征简并，以获得完全的带稀我们采用两种方法，一种是将晶体的原子做成非球对称，另一种用各向异性的颗粒球做晶体原子。

The study of crystal structure indicates that the complexes belongs to tetragonal,14(1)/a, a=b=27.047(5) A, c=14.103(3) A, a=b=y =90,V=10317(4)A3, Z=16, Dc=1.071g/cm3, F(000)=3408, R,=0.1395, R2=0.1766 and every unit of the tetranuclear complexes is four-coordinated to tridentate ligand and nitrogen atom in pyrazolone from other ligand. The complexes is slightly deformed square-planar geometry.

晶体结构研究表明，该配合物为四方晶系，空间群I4(1)/a，a=b=27.047(5)，c=14.103(3)，α=β=γ=90°，V=10317(4)，Z=16，Dc=1.071g/cm~3，F(000)=3408，R_1=0.1395，ωR_2=0.1766，其结构单元是由一个三齿配体中的ONO和另一个配体吡唑啉酮环二位上的N配位后形成略微畸变的平面四边形构型，其中Cu的配位数为4。

the title compound was synthesized and its structure was studied in theory.the schiff base compound was synthesized by condensation of paeonol with furylfurylamine,then it was deoxidized by sodium borohydried.the energies,bound lengths,bound angles,the net charges of main atom and contributive percents of frontier orbital in the title compound have been calculated by software hyperchem 7.0 in half experience method.the yield rate of title compound was 65.6%.the result of calculation showed that the most of the bond lengths and angles in the system were in the the normal range,negative charge mainly concentrate on o1,o2,o3 and n1.the title compound behaves as quadridentate ligand.

目的合成标题化合物并对其结构进行了理论研究。方法以丹皮酚和糠胺为原料合成席夫碱，经硼氢化钠还原得标题化合物；使用hyperchem7.0程序，用半经验方法计算了化合物分子中能量分布、主要键长、键角以及主要原子的净电荷分布和前言轨道分布。结果标题化合物，收率65.6%；计算结果分析表明，分子中主要原子之间的键长、键角基本在正常的范围内；负电荷主要集中于o1，o2，o3和n1上。

Moreover, the thermal conductivity of La-filled compound is decreased significantly because of phonons scattering induced by the "rattling" of La atom in the voids of skutterudite structure.

由于稀土La原子在结构空隙中的&振颤&运动强烈散射了声子，使得填充稀土La的化合物热导率获得了更大程度的降低。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。