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The structural and photocatalytic properties of TiO〓 as well as surface acidity were greatly improved by sulfation. SO〓〓/TiO〓 solid superacid with Hammett constant Ho less than -12.14 was prepared by treating the TiO〓 with 1.0mol. L〓 sulfuric acid solution and then calcining at 450℃ for 3h. When compared to unmodified TiO〓, the SO〓〓/TiO〓 superacid catalyst exhibited higher anatase content, smaller crystal size, higher specific surface area, centralized pore size distribution, and the blue-shifted band edge of uv-vis adsorption spectra. Furthermore, the SO〓〓/TiO〓 superacid also showed excellent reaction activity and stability for CH〓Br photocatalytic decomposition even under the moist reaction conditions. The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.
研究结果表明:SO〓〓与TiO〓表面的结合为螯合式双配位结构;TiO〓光催化剂表面经H〓SO〓浸渍处理后,提高了表面酸性,改善了催化剂结构和光催化性能,当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时,可制得SO〓〓/TiO〓超强酸催化剂(H〓<-12.14),其结构和光催化活性得到明显改善,与TiO〓相比,SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移,具有优异的光催化氧化活性、稳定性及抗湿性能,光催化降解溴代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级,是一种有实际应用前景的高效光催化剂;由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型,认为在SO〓〓/TiO〓超强酸催化剂表面,由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心,其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移,具有可逆吸附水的性能,是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。
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A pivotal problem to recognize of the precise position of laser facula has been solved in the process of design work: Firstly the method of background-subtraction is used to eliminate or weaken the affect of background light. Secondly the image threshold segmentation operation and morphologic operation are used to locate the sketchy position of laser facula ; Then the new method of Extracting Edge are designed based on character of laser facula , by using this method in the search area the edges of laser facula can be extracted effectively; At last the optimum picture of laser facular is selected by using the triggering function of hardware and function of software. The exact result can be obtained only by image processing to optimum picture.
在设计过程中解决了精确确定激光斑中心位置这一关键问题:首先利用减背景法,消除或减弱背景光的变化对确定激光光斑中心的影响;再对减完背景后的图片进行阈值分割和二值化处理以确定激光光斑的粗略位置;根据本文激光光斑的特征,设计了一个有效的边界提取算法,对指定区域进行提取激光光斑边界操作,精确的确定激光斑中心位置;最后利用硬件的触发功能和软件编程实现了激光光斑最佳图片的判读,只有对最佳图片进行图像处理得到结果才是准确的。
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Rodent incisors are known to be continuously growing teeth that are maintained by both the cell-proliferation at the apical end and the attrition of the incisal edge.
啮齿动物的切牙终生不断生长,其高度通过切端磨损及根尖末端的细胞增殖来维持。
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IWA is at the forefront in connecting the broad community of water professionals around the globe - integrating the leading edge of professional thought on research and practice, regulators and the regulated, across national boundaries and across the drinking water, wastewater and stormwater disciplines.
国际水协会是连接全球水专业领域团体的中心,对于整合研究与实践、调整与控制、超越国界与横跨饮水、废水和雨水等学科的专业理论具有领导优势。
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IWA is at the forefront in connecting the broad community of water professionals around the globe - integrating the leading edge of professional thought on research and practice, regulators and the regulated, across national boundaries and across the drinking water, wastewater and stormwater disciplines.
每年IWA在世界各地组织和举办水管理和水技术的各类大会和研讨交流会,如两年一届的世界水大会,每年定期举办的技术前沿会议(分别是水资源可持续利用前沿技术、给排水处理技术前沿、水务资产管理前沿,作为对世界水大会内容的补充)。
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Then it made denoising and edge detection for the CT image of the brain aiming at the properties and keystoned of CT image. In the process of denosing for CT images of the brain,because it has some characteristics,such as the biomedical signal is a typical non-stationary signal with a strong noise in background,it is more difficult to resolution.
在对脑部CT图像的去噪处理过程中,本文针对生物医学信号是典型的非平稳信号,具有很强的背景噪声,处理起来较困难的特点,引入了一种基于EMD方法的脑部CT图像去噪方法,它可以有效地去除噪声的干扰,充分保留信号的局部特征。
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Need laminating of gilded with gold foil often worry about is easy to clean the first hot stamping and then covered with plastic film, which produce: cyclophos phamide sub-gloss film will destroy the anodized finish, not water soluble glue film covering, or it will cause anodized surface nigrescent, at the same time easy to cause we recreate the stuck to the pictures and texts issued on virtual phenomenon caused by the edge.
需要覆膜加工的烫金,人们常担心金箔容易擦落而先烫印再覆膜,这易造成:①薄膜会破坏电化铝表面光泽性,不宜采用水溶性胶水覆膜,否则会造成电化铝表面发黑,同时极易造成金粉粘在图文边缘造成发虚现象。
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The Fresnel lens in the optical receptor spotlights the headlamp beams to form their image at the 1-meter distance between the optical receptor and headlamps. CMOS camera as an image sensor, takes the photos of their images, which are captured by VG-M201, The application of some digital image processing techniques to these images, such as edge-picking up、 least-square fitting-curve algorithm, is to calculate the offset position/angle of optical axis of the high beams and the nodical offset of the unsymmetrical facular light and shade cut-off line of the low beams.
系统的图像采集工作是利用受光箱中的菲涅耳透镜在1米的测量距离上聚合前照灯灯光,由CMOS摄像头作为图像传感器件,照入灯光远光光斑和非对称近光图像,由嵌入式处理器对捕获的图像运用边缘提取、最小二乘法拟合曲线等数字图像处理技术计算出远光主光轴偏移角度以及非对称近光光斑明暗截止线拐点的偏移,实现了前照灯近光非对称光斑的自动测量。
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Results The main CT finds were as follow:①Bilaterial margins of the lesion were perpendicular to pleura with a straight cut edge presenting a square sign;②The density at the central area,some-times presenting a halo-like apperance;③Irre-gular or spiculate margins with illdefined outline could be seen;④There was extensive pleural thickening involving interlobar fissure as a response to inflamation;⑤There were small patches of slightly high density and intensified vascular markings surrounding the lesions;⑥After short-term anti-inflam-matory therrapy,most lesions were obviously reduced in size.
结果 26例球形肺炎的主要CT表现为:①邻近胸膜病变两侧缘垂直于胸膜呈刀切样平直边缘,病变呈方形;②病变中央密度高,边缘密度低,显示晕圈状改变;③病变边缘可不规则,有锯齿状改变且较模糊;④周围胸膜反应显著,有较广泛增厚;⑤病变周围血管纹理增多、增粗、扭曲,但无僵直和受牵拉;⑥抗炎治疗后病变明显吸收缩小。
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One of the main causes of the noises of the modern jet plane is the strong fluctuation generated by the flows passing by the trading edge of the airfoil and the outlet of jet engine, and the mechanism of generation of noises canoed by the fluctuation has not been clear at present.
现代喷气式飞机的主要噪声源之一是在机翼的尾缘及喷流发动机的出口处,即流体流过尾缘时产生的强烈脉动,目前这类脉动产生噪声的机理尚不清楚。
- 推荐网络例句
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By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.
到它被攻陷的时候,里面多数的犯人是写了反对政府贪污文章的作家。
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The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.
在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色,卵在发育96h后卵基本全部孵化。
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There was a conflict between plebs and patricians in ancient Rome in 494BC.
在公元前494年,罗马发生了一次平民反对贵族的斗争。