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The results show that BDT can be assembled on the surface of copper electrode to form monomolecular self-assembled membrane,and the membrane can efficiently inhibit the copper base corrosion in the 3% NaCl corrosion medium and acidic solution.

实验表明:BDT能够有效地组装到铜的表面形成单分子自组装膜,BDT自组装膜能有效地抑制铜基底在3%NaCl腐蚀介质以及酸性NaCl溶液中的腐蚀行为;缓蚀效率随组装时间的延长逐渐升高并趋于稳定,在pH值较低的溶液中仍具有较好的缓蚀效果;当BDT浓度为1.0×102 mol/L、组装时间为40 h时,铜电极的腐蚀电流最小,缓蚀效率最好。

The influence of different assembled condition such as assembly method, concentration of zirconium source and pH value on the effectiveness of assembly were evaluated via DSC-TG, FT-IR, Uv-vis and SAXRD et al. It showed that the assembly effectivness of uncalcined 3 Si/Zr_10# sample was best.c The optical characteristic, which including light-conduction in infrared band and polarity in visible band, of dip-coating film and membrane assembled zirconia after processing parameters of assembly optimized were observed via FT-IR and Uv-vis. The polarity was characterized by polarizing angle through calculation from light-transmittance, light-reflectance and fresnel coefficient. qualitative analysis showed that the polarity of Si/Zr_10 # dip-coating film assembled was best.d Adopting zirconium oxychloride as zirconium source, CTAB as template, employing different CTAB adding sequence, two mesoporous zirconia samples were prepared. The template effect of two samples was discussed. It showed that the effect of the sample which CTAB adding sequence was same as mesoporous silica film was better. The light-conduction in infrared band of these samples was also studied, which offered comparison to the polarity of zirconium dioxide assembled within mesopore.

结果显示:组装条件优化后的uncalcined 3 Si/Zr_10#厚膜样组装效果最好,其组装液对应的pH值最利于该锆源离子模板交换组装; c选用FT-IR、Uv-vis对组装条件优化后纳米氧化锆/介孔氧化硅厚膜、纳米氧化锆/介孔氧化硅薄膜包括红外导光性、可见光区内的偏光性在内的光学特性进行了分析,其中偏光性以膜层透光性、反光性及菲涅耳系数计算出的偏振角即布儒斯特角表征,定性分析显示,Si/Zr_10#ZrO_2/介孔氧化硅厚膜偏光性最好; d以氧氯化锆ZrOCl_2·8H_2O为锆源,CTAB为模板剂,采用不同的模板剂加入顺序,探索性地制备两介孔氧化锆样,分析了两介孔氧化锆样的模板效果,得出模板剂加入顺序同介孔氧化硅薄膜时介孔氧化锆样的模板效果较好,并分析了所得样品的导光性,为锆氧粒子引起的附加光学特性分析提供了参考和对比。

For this instrument, in hardware, it bases on PAX255 ARM chip. LPC2104 ARM and AD7865, the main chip in the A/D module, LCD module, and Flash and SDRAM centering on the data and program memory module are all assembled in it. The signal pre-conditioning is also assembled.

本文所设计的设备巡检系统在硬件上,以PAX255为主控制CPU芯片,搭配了以LPC2104芯片和AD7865组成的A/D采样模块、触摸屏LCD显示模块和以FLISH和SDRAM为中心的数据、程序存储模块,以及相关的信号预处理模块和网络芯片CS8900A等硬件电路。

Self-assembled nanomicelles of N -cholesterol succinyl O -carboxymethyl chitosan were prepared by probe sonication method. The amphiphilic property and the critical micelle concentration of CCMC were determined by fluorescence probe technique; the morphology and the size of CCMC self-assembled nanomicelles were analyzed by transmission electron microscopy and the dynamic laser light scattering.

以 N -胆甾醇琥珀酰基- O -羧甲基壳聚糖(CCMC,胆甾醇基取代度6.9%)为原料,在水溶液中通过探头超声处理制备其自组装凝胶纳米胶束,采用稳态荧光探针法考察临界胶束浓度,并通过透射电镜和动态激光散射仪检测胶束的形态大小。

Using "neighbor-joining" of Mega 2.1 software reconstructed the molecular Phylogenetic Tree, the results indicated Labeoninae fishes might not be monophyletic population, C.molitorella and E.bicolor of Labeoninae assembled together with Cyprinus carpio and Carassius auratus firstly, and formed sister group, then assembled together with C.mrigala and L.rohita , which suggested that C.molitorella was genetically more relative to Cyprinidae than Labeoninae.

用Mega 2.1软件的NJ法构建分子系统树,结果表明:野鲮亚科鱼类没有形成单系类群,野鲮亚科的鲮、角鱼与鲤亚科的鲤、鲫形成姐妹群,然后再与野鲮亚科的麦鲮和露斯塔野鲮聚在一起,说明鲮与鲤亚科鱼类具有较近的亲缘关系。

The UV and IR spectroscopic studies of the monomer films showed that the photoreaction ratio of monomer (about 50%) was higher than the corresponding photosensitive polymer (about 10%, PVCi). The polarized IR spectra proved that obvious anisotropic absorption was displayed in the irradiated photosensitive film. With polarizing microscopy method, we found that these kinds of photoalignment films exhibited good alignment ability, and the stability of the photoalignment film could reach about 100℃. 2 A photosensitive self-assembled monolayer was fabricated that contained photo-cycloadditable groups, such as, coumarin and cinnamate. The reaction process were detected by contact angle method because the IR absorption of monolayer was very weak. The photosensitive self-assembled monolayer promote uniform alignment of nematic liquid crystals by LPUV, and it thermal stability could reach about 130℃. 3 A cationic bolaform amphiphiles was synthesized that had two photosensitive double bonds, and can be polymerized by ultraviolet. A layer-by-layer self-assembled deposition film was prepared in aqueous solution by using this material and poly (sodium 4-styrenesulfonate). The UV-Vis. spectra proved that the multilayers film was uniform and layer-by-layer. When LPUV irradiated the film, the photopolymerizable double bond underwent [2+2] cycloaddition, and the production of the reaction distributed along the polarized direction of incident LPUV. Polarized UV-Vis. spectra indicated that the irradiated self-assembled multiplayer film was anisotropic, and the dichromic ration is about 0.09, it is higher than the spin-coating method of photosensitive polymer or monomer. We used this anisotropic film as alignment layer of nematic liquid crystals, and obtained a uniform and stability alignment result, the static contrast ratio is about 100, which is very close to application of liquid crystal device. This thesis is an instance that the photochemical material was used in the physics region of liquid crystals, the route that was from photosensitive monomer, self-assembled monolayer film to self-assembled multiplayer film was undergone, by this logical research method photoailgnment of liquid crystal was extended and consummated.

围绕上述思路开展了如下工作:1合成了三种可进行光二聚反应的光敏小分子单体,LPUV 辐照制作了光控取向膜;用紫外-可见光谱法和红外光谱法分析了薄膜中的光化学反应,发现小分子的光反应程度可达到50%以上,至少比光敏高分子高出5倍;薄膜的偏振红外光谱证实,经过LPUV 辐照后薄膜出现了明显的各向异性;将小分子光控取向膜制成液晶器件,在偏光显微镜下观察看到均匀一致的液晶取向;并且热稳定性达到100℃左右,接近实用化要求。2制备了含肉桂酸、香豆素基团的自组装单层膜;采用接触角的方法监测自组装反应的动力学过程;紫外-可见光谱证实了自组装单层膜在石英基板表面形成;自组装单层膜经LPUV 辐照后能诱导液晶均匀取向,而且热稳定性可达130℃,热稳定性进一步提高。3合成了含有光敏双键的双季铵盐,在水溶液状态下将它和聚乙烯基苯磺酸钠沉积生成layer-by-layer 自组装多层膜,紫外-可见光谱证实这是一个逐层均匀的沉积;在LPUV 照射下,自组装膜中的光敏双键按照偏振方向发生[2+2]环加成反应,形成取向膜,用二向色性值评价的分子取向度高于高分子及小分子光控取向膜的水平;实验证明用自组装多层膜制成的液晶器件亮暗态均匀,静态对比度约为100,达到实用化器件的水平。

Results showed that planktonic Prorocentrum were assembled to onegroup while benthic Prorocentrum were assembled to another group. The percentagesof the bootstrap values were higher than 95%. The results demonstrated that theplanktonic and benthic Prorocentrum should belong to different genus. Furthermore, the resulting phlogenetic structure showed the percentages of thebootstrap values (98%-100%) of Alexandrium in NJ and ML trees were significantlevers and belong to one group, divergently with genus Gonyaulax.

通过分析 17 种甲藻 18S rDNA 序列构建的系统发育树,营浮游生活的原甲藻在显著水平上聚为一类,而底栖种聚为一类,统计置信度均高于 95%,底栖原甲藻和营浮游生活原甲藻在 NJ 树和 ML 树上均为两个分支,且底栖型的分异速度较浮游型迅速,该结果说明原甲藻属中浮游种和底栖种应分属于不同类群。

As an experiment, Mercapto to modify Neisseria gonorrhoeae probe is used to prove the system. A Self-Assembled Monolayer is affixed to the probe in which 6-Mercaptohexanol is blocked.

以巯基修饰淋病奈瑟氏菌探针为例验证该系统,利用自组装单分子层技术(Self-Assembled Monolayer,SAM)固定探针。

Sensing ability of PSS/PANI self-assembled film with different doping/dedoping structure to DMMP and CEES was investigated. Results demonstrate that the gas sensitivity of PSS/PANI self-assembled film is affected by the size of dopant counterions. Gas sensitivity of self-assembled film increases with increasing size of dopant counterions. It is found that sensing ability of PSS/PANI self-assembled film to DMMP increases significantly by redoping/dedoping EB-PSS/PANI film with sarin acid that has similar structure with DMMP.

首次考察了不同掺杂/脱掺杂结构的PSS/PANI自组装膜对化学战剂模拟剂DMMP和CEES的敏感性能,研究表明,掺杂酸对离子的尺寸大小对PSS/PANI自组装膜的气敏性有很大影响,较大的对离子尺寸有利于提高自组装膜的气敏性;并且发现采用与DMMP结构类似的沙林酸对EB-PSS/PANI自组装膜进行再掺杂-脱掺杂,能显著提高PSS/PANI自组装膜对DMMP的敏感性能。

Copper ion was assembled onto DL-cysteine membrane that was directly assembled on the gold surface via Au-S bond, and then NAA was assembled onto the Cu/Cys/Au via coordinate function between NAA and Cu~(2+).

2利用过渡金属铜离子的桥联作用将萘胺乙酸作为桥联配体间接组装于单层膜Cys/Au上,构建另一类自组装多层膜体系NAA/Cu/Cys/Au。

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