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The genera formulas of these compounds are as follows:The strobilurin derivatives were synthesized from substitutedβ-keto esters (2) as starting material which were prepared from substituted ketones (1) and dimethyl carbonate. The ester (2) and methyl hydrazine or substituted amidine were dissolved in methanol and the mixture was heated to reflux to obtain the substituted 5-hydroxy-1H-pyrazole (3) or 4-hydroxy-pyrimidine (4). The title compounds were prepared by reacting the intermediates (3 and 4) with substituted halomethylphenyls which contain four active group under basic conditions.
本论文所合成的strobilurin化合物均是以β-酮酸酯类化合物(2)为起始原料合成的,该中间体(2)是由酮类化合物(1)与碳酸二甲酯在碱性条件下反应生成的,中间体(2)与甲基肼或取代脒类化合物在甲醇中回流制得取代的1H-5-羟基吡唑(3)或4-羟基嘧啶(4),中间体(3和4)再与包含四种活性基的苄卤中间体在碱性条件下制得目标化合物。
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Through researching the mechanism of biological nitrification and denitrification and actual project application of the technology and related literature materials, the obtained results are as follows:(1) Anoxybiosis is effective to the removal of COD; after the anoxic process, BOD/COD of the outflow increases, it shows that the degradation ability of wastewater is improved; anoxybiosis is insensitive when shock loading of inflow wastewater varies greatly;(2) It is demonstrated by the operation of inoculation and cultivating that biofilm takes two weeks to succeed in cultivating on packings and the removal ratios of NH3-N and COD get 50% and 70% respectively, when gas-water ratio is 6:1, HRT is 7.3 hour, water temperature is above 15°C;(3) It is demonstrated that gas-water ratio, hydraulic loading, HRT, temperature, pH etc are important factors which influence the removal effect of pollutants, when the gas-water ratio is 6:1, hydraulic loading is about 0.38kgNH3-N/m~3.d, water temperature ranges from 15°C to 27°C, pH ranges from 7.5 to 8.0, the BIOFOR removal effect of pollutants is the best;(4) The operation indicated that, this technology has strong ability of nitrification and denitrification; it has extremely vital significance for reducing the water body eutrophication;(5) It is confirmed the feasibility and the usability of preanoxic-BIOFOR process to treat L-lactic acid production wastewater. The experiment indicated that the treatment effect of this technology is very good and also shows that the technology has many advantages, such as small volume, high treatment efficiency, good effluent quality and strong endurance to load variation, this technology is a new and economical wastewater treatment process.
通过对生物脱氮机理的研究和该组合技术的实际工程应用,并结合有关文献资料,取得如下结论:(1)预缺氧池对L-乳酸生产废水中的COD去除具有一定的效果;废水中难降解的高分子物质经过缺氧工段分解为易于氧化降解的物质,浮状有机物在水解菌的作用下,将不溶性有机物水解为溶解性物质;预缺氧池具有较强的抗冲击负荷能力;(2)BIOFOR接种挂膜过程表明:HRT为7.3h、气水比为6:1、水温保持在15℃以上,经过半个月生物膜即以形成,NH_3-N和COD的去除率分别达到50%和70%左右;(3)研究表明:气水比、水力负荷、HRT、温度、pH等是影响污染物去除效率的重要因素,在气水比为6:1,NH_3-N容积负荷为0.38kgNH_3-N/m~3·d,温度在15℃-27℃,pH在7.5-8.0之间的条件下,BIOFOR对污染物的去除效率达到最佳;(4)运行表明,该组合技术具有较强的脱氮能力,对于减少水体富营养化具有十分重要的意义;(5)经过半年多实际工程的现场调试与运行,验证了利用预缺氧—BIOFOR组合工艺处理L—乳酸生产废水的可行性和实用性,得出该组合技术具有占地面积小,处理效果好,运行费用省,耐冲击负荷能力强等优点,是一项新型、经济的污水处理技术。
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The earlier wording given by Strasser may be rendered as follows: An apodictic evidence, however, has the signal peculiarity that the certainty of the being of what is beheld in it discloses itself, to a critical reflection, as an absolute unimaginableness of the seen object's non-being and therefore of that object's being dubitable.
被Strasser给出的早期表述,附注如下:一个绝然的明证,含有一个确定性的标志性特征,这个确定性(在其中所持有的being的确定性)揭示自己为绝对不可设想所见对象的non-being(于是不可设想这个对象是可疑的)。
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The results showed that sweet pepper from Guangdong province is the best candidate for extraction and the best extracting conditions are as follows: alcohol solution (95%) as menstruum, the ratio of powder and menstruum at 1:16g/ml and at the temperature of 50 ℃ for 3 h. The condensed umber oily product has high ASTA value (≥1000) and Hg element lower than 0.01 mg/kg.
辣椒红素是有一定辣味的粘性油状液体,在浓绸时为深红色,在浓度较低时为橙黄色到黄色,构成辣椒颜色的是类胡萝卜素,其中包括一部分胡萝卜素,但主要是叶黄素类的辣椒红素(Capsanthin,分子式C40H56O3)和辣椒玉红素(Cap sorubin,分子式C40 H56 O4)。
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The paper is organized as follows. In chapter 2, we introduce some concepts about SEA, the abstract SEA model and the convergence definition of algorithm. In chapter 3, we describe firstly the evolution of PMA as an abstract stochastic process, and by characterizing axiomatically the properties of the fundamental selection and evolution operators, we conclude that PMA is essentially a kind of SEA.
本文结构安排如下:第二章介绍了模拟进化算法的一些基本概念、形式化随机过程描述以及收敛性定义;第三章对改进后的 PMA 各操作作了抽象定义,得到了 PMA 的形式化随机过程描述,并公理化地证明了各操作算子为选择或繁殖算子,从而得出 PMA本质上也是一种模拟进化算法;第四章先对选择算子特征数定义作了适当改进,并通过各进化算子的具体特征数指出,如果 PMA 不采取任何执行策略时,算法本身并不收敛。
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In this thesis,the AM1,MNDO,MINDO/3(mainly AM1)and INDO/S-CI semiempirical MO methods were used toinvestigate the excited-state intramolecular protontransfer reactions of salicylic acid derivatives—salicylic acid,methyl salicylate,salicylaldehyde,o-hydroxyaceto-phenone,salicylamide and 3-hydroxy-picolinamide (6 conformers and 2-3 anion species);2-(2'-hydroxy-5' methylphenyl) benzotriazole(4 conformers),2-(2' hydroxyphenyl) benzimidazole (3 conformers and 3anion species),Bis-2,5-(2-benzoxazolyl)hydroquinone(3 conformers),2-(2'-hydroxyphenyl)benzothiazole(2conformers) and 7-azaindole dimer (2 conformers).Theinvestigations were described as follows.Geometry optimization,relative stability andhydrogen bonding energy First,for sylicylic acid derivative molecules,the AM1,MNDO and MINDO/3 methods were used toinvestigate ground-state geometry optimization,energies,relative stabilities and hydrogen-bondingenergies on the five kinds of the molecules(designing 6 conformers and 2-3 anion species).Comparing with experimental data,the optimizedgeometry,the order of stability,the hydrogen-bonding energies and the distances between O-O in O-H..O hydrogen bonds by AM1 method were in agreementwith the experimental data,however,the C-C bondlengths optimized by MNDO and MINDO/3 were longer,C-O and O-H bond lengths were shorter;for C-N bondlengths,the results opitimized by MNDO method werethe same as those by AM1 method,nevertheless the C-Nbond lengths given by MINDO/3 method were muchshorter.For some sylicylic acid derivatives(e.g.methyl salicylate,salicylamide),the order ofstabilities on the conformers given by MNDO andMINDO/3 methods were not in agreement with theexisting conformers deduced by experimental methods,and the hydrogen bonding energies calculated by MNDO.and MINDO/3 methods were smaller.Second,the studyon the other systems found that the optimizedgeometry of the proton-transfered product with INDOmethod could not be obtained,only could theoptimized geometry of reactant be obtained,and thecalculated hydrogen bonding energies were greater.Many results of calculation indicated that the studyon the excited-state intramolecular proton transferreaction system using AM1 method was suitable andreliable.
本论文用AM1、MNDO、MINDO/3(主要是AM1)和INDO/S-CI半经验分子轨道方法对水杨酸衍生物系列——水杨酸、水杨酸甲酯、水杨醛、O-羟基乙酰苯酮、水杨酰胺和3-羟基吡啶酰胺(6种异构体和2-3种阴离子);2-(2'-羟基-5'-甲基苯基)苯并三〓唑(4种异构体);2-(2'-羟基苯基)苯并咪唑(3种异构体和3种阴离子);2,5-二间氮杂氧茚氢醌(3种异构体);2-(2'-羟基苯基)间〓杂硫茚(2种异构体)和7-〓吲哚二体(2种异构体)的激发态分子内质子转移反应在以下几个方面进行了较系统的理论研究:几何构型优化和相对稳定性及氢键能首先以水杨酸衍生物系列分子为例,用AM1、MNDO和MINDO/3方法考察了5种分子(每种分子设计6种异构体和2-3种阴离子)的基态几何构型优化,能量、相对稳定性和氢键能计算,通过和实验数据进行比较,AM1方法给出的优化几何构型、稳定性次序、氢键能和O—H。。。O氢键的0—0距离与实验数据吻合最好,MNDO和MINDO/3方法优化的C-C键长偏长,C-O键和O-H键长偏短;对于C-N键长,MNDO和AM1优化结果差别不大,而MINDO/3给出了过短的C-N键长,MNDO和MINDO/3方法给出的有些水杨酸衍生物分子(如水杨酸甲酯和水杨酰胺)异构体的稳定性次序和实验上推测的可存在异构体结果不一致,MNDO和MINDO/3方法给出的氢键能偏低,对其他体系的研究发现INDO方法常常不能得到质子转移产物的优化几何构型,只能得到反应物的优化构型,并且估算的氢键能偏高,大量的计算结果表明AM1方法对本论文研究的激发态分子内质子转移反应体系是适宜和可靠的。
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ABSTRACT The aim of the project is to prepare the high temperature superconducting thin films which can satisfy the need of future applications in the field of power transmission. By using biaxially textured Ni (001) and Ag (110) as substrates, the YBCO films with high critical current were obtained under the optimized deposition conditions. Some results were obtained as follows: We developed a simple approach to prepare YBCO films doped with Ag nanograins.
本工作的研究目的是在金属基带上制备出能够满足未来超导强电应用的超导薄膜小样品,其具体的做法是在双轴织构的Ni(001)和Ag(110)基带上外延YBCO高温超导薄膜,经过不断地优化工艺条件,我们得到如下结果:发展了一种在YBCO薄膜中掺入Ag颗粒的方法,这种方法具有可以随时改变掺杂量的特点。
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The tryptophan residues play important roles in DNA photoreactivation catalyzed by CPD photolyases. We have investigated the action mechanism concerning Trp in DNA photoreactivation, and obtained the results as follows: 1 We proposed a mechanism of photosensitized splitting of CPDs by Trp and Trp-containing peptides. 2 Quantum yields of splitting of the model compounds that a Trp linked covalently a CPD were obtained under 290 nm light in various solvents, these values changing with solvent, range from 0.01 to 0.5. 3 Utilizing pulse radiolysis technique, splitting processes were observed in aqueous solution of the CPDs with hydrated electron and some oxidative species (such as hydroxyl radical, bromic radical and azide radical), and obtained their rate constants. In the case of interaction between CPD and hydrated electron, splitting of the CPD anion, and pyrimidine anion transfer an electron to FAD or Rf, were observed. The process rate was slower one order more than that in photolyase. Minor, but highly mutagenic UV-light-induced lesions are (6-4) photoproducts, which are repaired by (6-4) photolyases. These enzymes, discovered in 1993, are not well characterized and their mechanism is still under investigation.
我们研究它的作用机理,获得以下结果:1)建立了色氨酸及其肽对嘧啶二聚体光敏化裂解的直接修复作用机理模型;2)获得了色氨酸共价键连接于嘧啶二聚体的化合物在多种溶剂中290nm光辐照裂解的量子效率,其值随溶剂而变化,范围在0.01-0.5;3)运用脉冲辐解观察到嘧啶二聚体与水合电子和一些氧化性的自由基作用裂解过程,得到相应速率常数;对二聚体与水合电子作用发生裂解以及向FAD返还电子的过程进行了体外模拟;4)(6-4)光解酶的作用机理中一个关键假定是氧杂环丁烷中间体在接受电子后能自发裂解,恢复二嘧啶的结构。
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The main results are as follows:① The contents of the seven elements in both the mosses and the substrates are much higher than those normal condition;② Didymodon fallax has stronger capacity to accumulate the element Cd. It can be as the indicator of Cd;③ Comparing with the other 4 mosses, Bryum dichotomum possesses stronger enriching function for Cu, Zn, and Pb.
结果表明,铜山口铜矿这5种藓类植物体内及其生长基质中,Cu、Zn、Ca、Mg等4种元素含量较高;北地对齿藓对Cd有较强的富集能力,可以作为寻找Cd矿的特征植物;相对于其它4种藓类植物,双色真藓对Cu、Zn、Pb有较强的富集能力,可以作为寻找Cu矿、Zn矿、Pb矿的参考植物;舌叶毛口藓对Hg有一定的富集能力,可以作为寻找Hg矿的参考植物。
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After all, the conclusion are as follows: the concept of one unified society is accepted by all nationalities in China as political concept; the concept of being loyal to the sovereign while honoring one\'s parents in confucianist culture is the political and social ethics of all nationalities in China; the nationalities in the area of Gansu, Ningxia and Qinghai are all up to the concept of being loyal to the sovereign while honoring one\'s parents though they are in religion belief for all, Tibet Buddhism or Islam; the nationalities in the area of Gansu, Ningxia and Qinghai are caesaropapism by degree but they all subordinate to the unified political system in China.
甘宁青地区诸民族在全民信仰藏传佛教或伊斯兰教的同时,也都接受儒家学说的&忠君孝亲&之义;该地区诸民族在形成各种政教合一制度的同时,也都从属于中国大一统的政治体系。中国各宗教文化的认同性和别异性,具体表现为各宗教文化的多元性和它们之间的统一性。
- 推荐网络例句
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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.
曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。
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The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.
稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。
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When I was in school, the rabbi explained everythingin the Bible two different ways.
当我上学的时候,老师解释《圣经》用两种不同的方法。