查询词典 aryl

Have had the intense function fromthis the explanation preparation and DNA, matched the body the planearyl residue groups and bases to insert the DNA double spiral plane,caused the plane aryl residue groups and bases the electronic clouddensity to have the change.

由此说明配合物和DNA发生了强烈作用，配体的平面芳基基团插入了DNA的双螺旋平面，导致平面芳基基团的电子云密度发生改变。

According to the synthetic methods study of the quinolones, it is found that the synthetic method of parent ring is of wide use by the condensation from α-substituted aryl formyl-β-substituted aminoacrylic acid and the inner molecular nucleophilic substitution reaction, which is almost suitable for the quinolones preparation of different rings or different substituted groups in 〓-position.

然后，对其合成方法进行了归纳，发现：由α-取代芳甲酰基-β-取代氨基丙烯酸缩合，经分子内亲核取代反应形成喹诺酮母环的合成方法用途非常广，几乎适用于所有不同环系或〓-位是不同取代基的喹诺酮类衍生物的制备。

One-pot reactions of 4 with isocyanates, triphenyl phosphine, hexachloroethane and triethylamine produced 2-anilino-5-arylidene-1-aryl-4,5-dihydroimidazo[1,2-b]-1',2',4'-triazol-4-ones 6 (or 7) in good yields.

而后用4与芳基异氰酸酯、三苯基膦、六氯乙烷和三乙胺"一锅"反应，得到4，5-二氢咪唑并[1，2-b]-1'，2'，4'-三唑-4-酮衍生物6或7。

This is exactly opposite to the order of E465/E665 in HA and the order ofΔ~ K. It shows that the larger the extent of humification, the larger the effect for reducing the rate of Phoxim hydrolysis, because the extent of HA humification is closely related to the extent of benzene in HA and the amount of carbonyl, aryl, phenolic hydroxide.

因腐殖酸腐殖化程度与腐殖酸芳构化程度、羧基、羰基和酚羟基的含量等相关，因此用腐殖酸腐殖化程度反映腐殖酸对农药水解作用大小比仅用腐殖酸中有机碳含量等因素反映更为合理。

The reductive coupling of aryl halide s to form the corresponding biaryls was effected with high selectivity in water,using formic hydrazide as a reducing agent in the presence of a catalytic amount of Pd/C.

在Pd/C催化下，以甲酰肼为还原剂，卤代芳烃通过还原偶联反应能高选择性地合成相应的联苯化合物。

In this section, we focused on the investigation of the condensation, Michael reaction of different aromatic aldehyde with different aryl substituted ketones under solvent-free and PTC conditions, obtained polysubstitutedcyclohexanol derivatives in mordent yield when using TBAB as the catalyst.

通过实验发现，TBAB对该反应具有良好的促进作用，使在液相中需十几个小时甚至几十个小时才能完成的反应，在无溶剂条件下几分钟就可完成，并且使液相中两步完成的反应，而在无溶剂条件下一步就可完成，且产率优良。

The bulky ortho-brominated aryl groups are implanted to create nonplanarity around amino center. Thus, the effective conjugation length to the protonation site is shortened and the energy gap between neutral and protonated forms is narrowed. The protonation can only occur at the nitrogen atom of the benzothiazole and the temperature variation disturbs the equilibrium between the neutral and monocation and the reverible thermochromic effect can thus be achieved.

在邻位的位置引入立体阻碍大的溴原子，进而控制质子化过程的酸碱平衡只发生在 benzothiazole 上的氮原子上，企图达到只有中性分子，与单阳离子两种稳定的形式存在，经由外界的刺激下，例如温度或酸的量的改变，促使逆反应的发生，而达到热致变色的效果。

Experimental results show that the different substituted location and different substituted group on benzene cycle would result in the diversity of reduction properties of substituted aryl nitrobenzene. Substituted nitrobenzenes with withdrawing group will be reduced at more positive potential, while those with repelling group will be reduced at more negative potential. In addition, the reduction potential of nitro group of o-nitrobenzene shifts more negative due to the effect of space resistance.

结果表明，芳族硝基化合物在苯环上的取代基位置不同以及在相同位置上取代基的种类不同均可使各芳族硝基化合物的电还原性能发生较大差异：吸电子取代基在电还原过程中电位较正，推电子取代基的电还原电位较负：邻位取代基在反应过程中由于空间位阻效应，苯环上的硝基在电还原时电位往负方向移动。

Nitrations of both hydroxyl- and acetamino-substituted porphyrins were found to take place at the adjacent position of the substituent in the very aryl ring, whereas nitro group was guided into para positions of unsubstituted phenyl ring during the nitration of nitro-substituted porphyrin.

结果表明，羟基和乙酰氨基卟啉的硝化反应发生在与该取代基处于同一芳环的meta位，而硝基卟啉进行硝化时，硝基取代于其他未取代苯环的para位。

In the reaction of NAE18 with nitrogen mustard aryl phosphorochloridate, 4-dimethylaminopyridine played critical catalytic action.

在合成工作中发现：在NAE18与氮芥芳基磷酰氯的反应过程中， 4-二甲氨基吡啶起着关键性的催化作用。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。