查询词典 aryl

The ligand of the chiral Schiff base and acetylacetone vanadium are subjected to complexation in situ, hydrogen peroxide is taken as an oxidant, aryl alkyl thioether asymmetric oxidation reaction is catalyzed in a toluene or dichloromethane solution under low temperature or room temperature, enantioselectivity of chiral sulphoxide is 72 percent to 95 percent ee, and yield is 42 percent to 83 percent.

将上述手性西佛碱配体与乙酰丙酮氧钒原位络合，采用双氧水为氧化剂，在甲苯或二氯甲烷溶液中低温至室温下催化芳基烷基硫醚不对称氧化反应，手性亚砜的对映选择性为72％-95％ee，产率为42％-83％。

This could be a fascinating method for the practical syntheses of chiral synthons as valuable building blocks and important medicinal intermediates.3.Series of novel optical pureγ-aryl-1H-1,2,4-triazole derivatives were designed and synthesized by using the chiral auxiliary(Oppolzer\'s sultam),and all these target compounds were structurally characterized by ~1H NMR,~(13)C NMR,MS and elemental analysis,at the same time,some representative compounds have been elucidated by X-ray diffraction analysis.

应用手性辅剂樟脑磺内酰胺的手性诱导作用，设计合成了一系列光学纯的γ-芳基-1H-1，2，4-三唑类衍生物，所有目标化合物都采用了~1H NMR、~(13)C NMR、MS和元素分析进行了结构表征，同时也获得了部分代表性化合物的晶体结构，进一步确证了化合物的结构。

Aryl tetralin of lignans in podophyllotoxin has significant anti-tumor activity, which podophyllotoxin glucoside derivatives etoposide (VP-16) and teniposide (VM-26) is widely used in clinical.

芳基四氢萘类木脂素中的鬼臼毒素具有显著的抗肿瘤活性，其中鬼臼毒素的糖苷衍生物etoposide(VP-16)和teniposide (VM-26)被广泛用于临床。

A series of 3,3,6,6 tetramethyl 1,8 dioxo 9 aryl 1,2,3,4,5,6,7,8,9,10 decahydro acridines have been synthesized by the condensation of aromatic aldehydes, 5,5 dimethyl 1,3 cyclohexanedione and ammonium acetate in the presence of triethylbenzylammonium chloride as catalyst in water.

芳醛、5 ，5 二甲基 1，3 环己二酮与醋酸铵在三乙基苄基氯化铵催化下以水作为溶剂反应，生成一系列 3 ，3 ，6，6 四甲基 1，8 二氧代 9 芳基 1，2 ，3 ，4，5 ，6，7，8，9，10 十氢吖啶，与其它溶剂相比，水作为该反应的溶剂具有价格便宜，不易燃和无毒等优点，而且产率较高，产物的结构通过单晶X射线确

Stuay on electronic structures and spectra properties of 3-phenly6-aryl-1,2,4 triazolo[3,4-b]thiadiazole with time-dependent density functional theory.

李会学，萧泰。3-苯基-6-芳基-1，2，4-三唑并[3，4-b]-1，3，4-噻二唑的电结构和光谱性质的含时密度泛函理论研究。

The shape and size of the cluster can be adjusted.πconjugate aryl alkynyl thio ethers containing thiomethyl in the end are important compounds. We can use such compounds to get some functional molecules that have good assemblied effect, especially in controlling the shape and the size of the cluster.

设计并合成一些形态多样的π共轭系多-SCH_3功能基的芳炔硫醚类分子对获得一些具有良好组装效果，尤其是能够控制团簇形态或控制团簇尺度有用的功能分子有着重要的理论和实际意义。

The target compounds I_ provide possibility to construct different aryl alkynyl thio ethers.

甲硫基甲基苯基砜是一种用途十分广泛的有机硫试剂。

Poly(aryl ether sulfone ether ketone ketone) with side carboxyl attached to the main chain was synthesized by Friedel-Crafts polycondensation of 4,4′-diphenyoxyl diphenyl sulfone with trimellitic anhydride chloride.

以4，4′-二苯氧基二苯砜，偏苯三酸酐酰氯为单体通过Friedel-Crafts亲电反应合成了主链芳环上带有羧基侧基的聚芳醚砜醚酮酮树脂。

A new tripodal aryl amide type ligand,1,1,1-tris{[(2′-benzylaminoformyl)phenoxyl]methyl}-p-toluene sulfonyl aminomethane,and its Eu(NO_3)_3,Tb(NO_3)_3 complexes have been synthesized.

合成了一个新的三足芳香酰胺型有机配体1，1，1-三[(2′-甲酰苄胺苯氧)甲基]对甲苯磺酰氨基甲烷，及其Eu(NO3)3和Tb(NO3)3的配合物，并通过元素分析、红外光谱、核磁共振氢谱和摩尔电导率进行了表征。

0Mol%. The catalytic system combining Pd 〓, imidazolium salt and pyridine has been employed in the cross-coupling of unactive aryl chlorides with malononitrile.

对大多数溴代芳烃而言，无论芳环上取代基是吸电子的，还是给电子取代基，均可高产率地制备得到相应的α—芳基丙二腈化合物（产率＞85％）。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。