查询词典 aryl

Wherein X is an oxygen atom or a sulfur atom; C*, C** and C*** are asymmetric carbons; R 1 , R 2 , R 4 , R 5 , R 8 , R 9 and R 10 are each a lower alkyl group optionally having substituent and the like, or R 4 and R 5 and the like in combination optionally form a homocyclic ring optionally having substituent and the like; R 3 is an aryl group optionally having substituent and the like; R 6 and R 7 are each a hydrogen atom and the like; Nu is -CR 16 (COR 17 )(COR 18 ) wherein R 16 , R 17 and R 18 are each a lower alkyl group optionally having substituent and the like, and the like; and EWG is an electron withdrawing group.

通式中，X代表氧或硫；C *、C **和C ***分别表示不对称碳；R 1 、R 2 、R 4 、R 5 、R 8 、R 9 和R 10 分别代表任选取代的低级烷基等，条件是例如R 4 和R 5 可以相互结合形成任选取代的同素环等；R 3 代表任选取代的芳基等；R 6 和R 7 分别代表氢原子等；Nu表示-CR 16 (COR 17 )(COR 18 )(其中R 16 、R 17 和R 18 分别代表任选取代的低级烷基等)等；并且EWG表示吸电子基团。

Project Introduction: Trichlorosilane, also named Silicochloroform ,is mainly used in the synthesis of organic silicone, alkyl, aryl and organic functional group chlorosilane. It's the most basic monomer of the organic silane coupling agent,and the production material for semiconductor silicon and silicon; Manufacturing process of the tetrachlorosilane includes the reciprocal effect by the trichlorosilane steam and the hydric steam which has been heated up to 1700-2500SiCK by the plasma accelerator; the steam compound in the reactor goes into the condensing system that separates trichlorosilane. After that, polycrystalline silicon can be made.

三、项目概况：三氯氢硅：又名三氯硅烷、硅氯仿，主要用于有机硅烷和烷基、芳基以及有机官能团氯硅烷的合成，是有机硅烷偶联剂中最基本的单体，也是生产半导体硅、单晶硅的原料；四氯氢硅工艺包括在等离子加速器内加热到1700-2500SiCK的氢气流和四氯氢硅的蒸汽相互作用，在反应器内形成的蒸汽气体混合物进入分离三氯氢硅的冷凝系统，下步可制取多晶硅。

The results showed polymeric diaryliodonium salts were effective aryl ion transfer reagents. Thirdly, a new type polymer supported hypervalent iodine reagents poly { [4-Hydroxy iodo] styrene} has been developed. It was an effective oxidative reagent, and could be applied to the one pot synthesis of 4-arylthiazoles.

然后，我们以聚苯乙烯羟基对甲苯磺酰氧基碘苯为原料，成功制备了一类新型聚合物高碘试剂—聚苯乙烯负载的炔基碘盐，并研究了其作为炔基转移试剂的有效性：(1)该试剂可对硫、氮、硒等负离子进行亲电炔基化反应，合成炔基亚砜、0，0-二烃基二硫代磷酸炔基酯、1-苯乙炔基苯并噻唑以及炔基硒醚。

We have developed a simple and easy-handling procedure for copper-catalyzed cyanation of aryl halides using K4[Fe_6] as the cyanide source. The present procedure has ligand- and base-free advantages, and was accomplished under the conditions of exposure to the air without degassing of the solvent.4. We carried out the selective control of preparation for phenyl ether and phenol from iodobenzene with 10 mol% of Cu_2·H_2O as the catalyst under the condition of exposure to air.

这个程序有无配体无碱的好处，并能够在暴露于空气的条件下进行，溶剂也不用脱气。4、空气气氛下，用10 mol%的Cu_2·H_2O催化碘苯偶联，实现了制备二苯醚和苯酚的选择性控制：即在有(来源：Aa955BC55论文网www.abclunwen.com)机溶剂NMP中实现了碘苯直接制备二苯醚的Ullmann反应，在H2O中实现了碘苯直接制备苯酚。

Completion of the synthesis involved displacement of the remaining alcohol through a three-step, telescoped sequence featuring an efficient cleavage of an aryl mesylate, and a practical method for introduction of the isobutyric acid fragment.

完成剩余的位移所涉及合成酒精通过三个步骤不胜顺序展出了高效率的卵裂甲磺酸芳、而实际的方法引入异丁酸片段。

A series of 3 - aryl - 3 -( 5,5 - dimethyl - 3 - hydroxy - 2 - cyclohexene - 1 - one - 2 - yl) propanoic ester s were synthesized by reaction between aromatic aldehydes ,5,5- dimethyl -1,3-cyclohexanedione and isopropylidene malonate catalyzed by KF - Al2O3 in alcohols.

在KF-Al_2O_3催化下，将芳香醛3，5-二甲基-1，3-环己二酮及丙二酸亚异丙酯在醇中反应，一锅式合成了一系列的3-芳基-3-(5，5-二甲基-3-羟基-2-环己烯-1-酮-2-基)丙酸酯。

Based on the different reaction results with-menthyl,-8-(2-naphthyl)menthyl or-8-phenylmenthyl as the chiral auxiliary, it is was proposed that the possible p -stacking effect between the aryl of chiral auxiliary and dienyl group of α,β-unsaturated esters is involved in the diastereoselectivity of these reactions.

该反应手性辅基易于回收、选择性好，产率高，这一工作为合成多取代的光学活性乙烯基环丙烷衍生物的提供了一种较为简便的方法。

Four different ionic liquids, BF4, BF and PF6 were investigated, arid PF6 showed the best effect when used as the reaction media, giving the highest yield in the shortest reaction time. Promoted by KF in PF6, N-aryl or N-alkyl monosubstituted sulfonamides could react with various activated halides and unactivated primary halides smoothly. Reactions were performed at 85℃ for 2~10 hours, and thirteen N-alkylation products were obtained with 70%~97% yields. Moreover, the ionic liquid recovered could be reused for three times with no appreciable decrease in yield and reaction rate.

结果表明，以PF6为反应介质时显示出了最好的效果，反应的时间最短，收率最高。N-芳基或N-烷基单取代的磺酰胺和各类不同结构的活化的卤代烃和未活化的一级卤代烃在PF6中KF作用下，85℃反应2~10h，以70%~97%的优良收率得到了13个N-烷基化产物，而且离子液体回收使用3次后效果未降低。

ATRP initiation systems consist of organic chloride initiators (RCl, RBr or aryl sulfonyl chloride, etc.), transition-metal catalysts in lower oxidation state Cu(I, Fe, Ru, Ni, etc. and organic electronic-donating ligands (2,2'-bipyridine―bipy or bpy, PPh3, multidentate ligand compound 1,1,4,7,7-pentamethyldiethylenetriamine, etc.).

普通ATRP引发体系包括引发剂主要为氯或溴化物，芳基磺酰氯；低价过渡金属卤化物如Cu， Fe，Ru，Ni等；有机配体如2，2'-联吡啶，PPh3，脂肪族多元胺等。

The microwave-assisted reactions could be finished within several minutes to give high conversion and selectivity.Substrates whose aryl groups were substituted phenyl or naphthyl groups were more suitable in this reaction.

以TfOH为催化剂，在优化的反应条件下，大部分反应都可在数分钟内完成，该反应对于芳基是取代苯环或萘环的的底物效果较好，能得到较高的原料转化率和产物选择性。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。