查询词典 aromatic compound

Birch Reduction, one of the most powerful synthetic methodologies available to organic chemists, provides a bridge between aromatic and aliphatic compounds and makes a huge arsenal of aromatic derivatives readily available for construction of alicyclic molecules, which are possibly converted into various natural products.

Birch还原是联接芳香族和脂肪族化合物的桥梁，它使许多芳香族衍生物成为合成脂肪族化合物，尤其六元脂环天然产物的起始原料，因此Birch还原是有机合成中很有用的方法。

by summarizing and analysing the progress on studies of pharmacodynamic material basis of resuscitation-inducing aromatic herbs such as moschus,borneolum syntheticum,styrax,benzoinum, and exploring the generality of those herbs,to provide scientific reference for further studies on the relevance of common substance ,nature and the efficiency of restoring consciousness and inducing resuscitation of those herbs.the result indicates that those four resuscitation-inducing aromatic herbs mainly contain volatile oil ,and all contain alicyclic compounds; the volatile oil of borneolum syntheticum and styrax both contain sesquiterpenes of caryophyllene; as resin herbs , styrax and benzoinum both contain vanillin, resin ester and balsamic acid .

通过对芳香开窍药麝香、冰片、苏合香、安息香的药效物质基础研究进展的整理、分析，探索其共性，拟为深入研究该类药的共性物质—药性—开窍醒神效应之间的关联性提供科学参考。结果表明，四味芳香开窍药主含挥发油，均含有脂环化合物，并存在一些共有成分，如龙脑冰片与苏合香挥发油中均含有倍半萜类成分石竹烯；苏合香和安息香皆为树脂类中药，两者均含有香荚兰醛成分，尚含树脂酯，香脂酸等。

Suitable water-immiscible organic solvents include aromatic hydrocarbons, eg toluene, xylene, naphthalene, tetrahydronaphthalene and methyl naphthalene; chlorinated aromatic hydrocarbons, eg chlorobenzene, fluorobenzene, chloronaphthalene and bromonaphthalene; esters, eg butyl acetate, ethyl acetate, methyl benzoate, ethyl benzoate, benzyl benzoate, butyl benzoate, phenylethyl acetate, butyl lactate, benzyl lactate, diethyleneglycol dipropionate, dimethyl phthalate, diethyl phthalate, dibutyl phthalate, di(2-ethylhexyl) phthalate; alcohols having six or more carbon atoms, eg hexanol, octanol, benzyl alcohol, phenyl ethanol, phenoxy ethanol, phenoxy propanol and phenoxy butanol; ethers having at least 5 carbon atoms, preferably C 5-14 ethers, eg anisole and phenetol; nitrocellulose, cellulose ether, cellulose acetate; low odour petroleum distillates; turpentine; white spirits; naphtha; isopropylbiphenyl; terpene; vegetable oil; mineral oil; essential oil; and natural oil; and mixtures of any two or more thereof.

适用于水互溶的有机溶剂包括芳香族碳氢化合物，如甲苯，二甲苯，萘，四氢萘和甲基萘；氯代芳香族碳氢化合物，如氯苯，氟，氯萘和萘；酯类，如醋酸丁酯，醋酸乙酯，苯甲酸甲酯，苯甲酸乙酯，苄酯，苯甲酸正丁酯，苯，醋酸丁酯乳酸，乳酸苄，二甘醇二丙酸酯，邻苯二甲酸二甲酯，邻苯二甲酸二乙酯，邻苯二甲酸二丁酯，二（2乙基己基）酯；醇有6个或更多碳原子，如己醇，辛醇，苯甲醇，苯乙醇，苯氧基乙醇，丙醇和苯氧基苯氧丁醇；醚至少有5个碳原子，最好荤5-14醚，如苯甲醚和phenetol；硝化棉，纤维素醚，醋酸纤维素，低气味石油蒸馏；松节油；白酒，石脑油isopropylbiphenyl；萜类，植物油，矿物油，挥发油；和天然油，以及任何两个或两个以上其混合物。

The Mannich reaction of butanone, aromatic aldehydes and aromatic amines.

对-甲苯乙酮与芳香醛和芳香胺的Mannich反应。

The gasification efficiency increased and the molar fraction of H2 decreased with an increase in the reaction temperature. The decomposition of PVA was more complete at higher temperatures. At 24 MPa, 500℃ and 120 s, the TOC remove rate, the carbon gasification rate and the hydrogen gasification rate were up to 71.46%, 67.97% and 157.24% respectively. A change in the residence time had no significant effect on the molar fraction of gas production but an increase in the residence time could enhance the gasification efficiency of PVA. It was found that the intermediates were mainly alkane, cycloparaffin, aromatic hydrocarbons, and low-molecular weight acids. It was supposed that PVA was degraded into small molecules through breaking of C-C bonds. Parts of the molecules were converted into H2, CO, CH4 and CO2 while some was converted into aromatic hydrocarbons.

过程探索发现：反应温度的升高能提高PVA气化效率，但气体产物中H2的含量随反应温度的升高有所下降；随着反应温度的升高，PVA分解趋于彻底，在压力24MPa、温度500℃、停留时间120s的条件下，TOC去除率、有机碳气化率和氢气化率分别达到71.46%，67.97%和157.24%；停留时间的变化对气体产物含量没有明显的影响，但延长停留时间能提高PVA的气化效率；PVA气化反应中间产物主要为链状烷烃、环烷烃、芳香烃及小分子酸，根据中间产物出现的顺序推测PVA的降解为由C-C键断裂形成小分子物质，这些小分子物质一部分转化为H2，CO，CH4和CO2，一部分形成难降解的芳香族化合物。

A series of diazonium salts of 4-(N-methyl-N-phenylamino)-3-amino-1,8-naphthalic anhydride 5a, its naphthalimide derivative 5b, and 5e were designed and synthesized,and it was the first time to discover that aromatic radical-induced intramolecular aromatic 1, 5-hydrogen transfer was also involved in the nitrogen-contianed system during Pschorr cyclization.

实验设计合成了4--3-氨基-1，8-萘酐的重氮盐5a、其衍生物N-丁基-4--3-氨基-1，8-萘酰亚胺的重氮盐5b和N--4--3-氨基-1，8-萘酰亚胺的重氮盐5c，并首次发现了通过普朔尔环化反应以氮甲基化的氮为桥原子的体系存在着芳香自由基诱导的芳香1，5-氢转移。

Brandy quality could be evaluated through the measurement of pH value, total phenol, colority, catechin, aromatic aldehyde and aromatic acids, Cu content, flavoring compositions, Einstein shift in ultraviolet spectrum, and non-alcohol volatile substances content in Brandy.

可通过测定白兰地的pH、总酚、色调以及儿茶素；芳香醛及芳香酸类物质；紫外光谱的"红移"现象；白兰地中的铜；白兰地中的香气成分；非酒精挥发物总量来评价酒质量。

Reaction Chemistry of Aromatic Compounds - Electrophilic Aromatic Substitution: Halogenation, Nitration, Sulfonylation and Friedel-Crafts Alkylation and Acylation.

芳香化合物的化学反应--亲电芳香取代反应：卤化，硝基化，磺基化和Friedel-Crafts 烷基化和醯基化。

With the single-crystal X-ray studies, the nanoscale rigid cavity of the aromatic macrocycle was approved, and nature of the heteromorphism of aromatic macrocyclic oligomer was also explained with the study of two kinds of single crystal with different steric structures.

并利用单晶X光衍射技术研究了三种不同结构的环状齐聚物的单晶结构，第一次通过大环分子与其对应线性齐聚物键长、键角和二面角的变化解释了聚芳醚酮类刚性大环分子环张力产生的原因。

The molecular charge distribution of the reactivator is affect the reactivating efficacy directly. Moreover its association with hydroximic acid dissociation constant pAa closely, and it will have a great impact on reactivating ability indirectly.(3) There is likely to exist front molecular interaction between Cholinesterase Reactivators and OPC-inhibited AChE, the action sites mainly lie on the aromatic ring, the substitute R and the hydroixic acid group. They act on the aromatic residues of AChE by Π-Π conjugation .(4) The reached results by Comparative Molecular Field Analysis is useful to design new higher efficacy derivatives for 1, 2, 4-oxadiazole class nonquaternary Cholinesterase Reactivators.

2复能剂分子的电荷分布直接影响复活活性，同时对肟酸解离常数pKa具有重要影响，间接影响复活能力；(3)复能剂与磷酰化酶可能存在前线轨道作用，作用部位可能主要在芳香环及其取代基R和肟基上，与AchE的芳香族残基发生л-л电子作用；(4)通过比较分子力场法研究可以指导1，2，4-oxadiazole类非季铵肟胆碱酯酶重活化剂新化合物的合成，可能得到活性更高的复能剂。

But this is impossible, as long as it is engaging in a market economy, there are risks in any operation.

但是，这是不可能的，只要是搞市场经济，是有风险的任何行动。

We're on the same wavelength.

我们是同道中人。