查询词典 anions

The synthesis methods of energetic salts and energetic ionic liquids(cations including triazole, tetrazole, bridged azole, hexamethyenetetrammonia, etc;and anions including nitrate, perchlorate, azide, tetranitratealuminate, polycyan anion, N,N'-dinitrourea, etc.) are reviewed, and the effects of cations, anions and their substitution groups on melting point, enthalpy of formation, density of the materials are summarized.

本文综述了多种含能盐和含能离子液体（阳离子包括三唑、四唑、双环唑、六次甲基四胺等；阴离子包括硝酸根、高氯酸根、硝基唑、叠氮根、四硝基铝、多腈基化合物、二硝基尿素等）的合成；结合其表征结果分析了阳离子上的取代基以及阴阳离子对它们的性能如熔点、生成焓、密度等的影响。

This thesis consists of three main parts of the research work on the syntheses, structures and reactivities of the olefin-coordinated transition metal carbene and carbyne complexes. In chapter 1, on the basis of our previous research works on the reacitivites of the cationic carbyne complexes of transition metals with metalcarbonyl anions, we explored the reactions of the cationic carbyne complexes of manganese (1) and rhenium (2) with polymetalcarbonyl anions, and developed a new method for the preparations of heternuclear trimetal bridging carbyne complexes.

本论文对烯烃配位的过渡金属卡宾和卡拜络合物的合成、结构和反应性能进行了研究，主要进行了如下三方面的工作：第一章在本小组过去的研究基础上，进一步考察锰和铼的阳离子卡拜络合物1和2与羰基金属阴离子化合物的反应，用来合成异核多金属桥卡拜络合物，发展合成多金属桥卡拜络合物的新方法和新路线。

These phenomena are explained as follows thatduring the hydration of α-hemihydrate gypsum, cations have significance influence on theζpotential of α-hemihydrate gypsum, thereby the dispersed state and the dissolving ratesof α-hemihydrate gypsum are changed. But anions have slight influence because it isdifficult that anions enter the double-layer.

产生这一现象的主要原因是：在α半水石膏的水化硬化过程中，阳离子对α半水石膏的ζ电位产生较大影响，从而改变了α半水石膏颗粒的分散程度和溶解速度；而阴离子很难进入双电层，因此对水化过程的影响较小。

For systematically studying the quantitative structure-property relationships for electrolytes, the thesis chapter 6, 7 and 8 systematically studied molecular structure and quantitative structure-property relationships, including the relationship between molecular structure and conductivity, anions structure and electrochemistry stability, on anions of 1,2-Dihydroxycyclo-pentenetrione (croconic acid, H_2C_5O_5) and the whole series of dicyanomethylene derivatives, anions of 1,2-dihydroxycyclobuten- 3,4-dione (squaric acid, H_2C_4O_4) and the whole series of dicyanomethylene derivatives, and anions of 1,2-Dihydroxy-cyclobuten- 3,4-dione (squaric acid, H_2C_4O_4) and the whole series of dicyanomethylene derivatives.

为了系统地研究锂盐的分子结构与电解质的关系，论文第六、七、八三章系统地从理论上研究了方酸及其氰基亚氨基衍生物、方酸及其二氰亚甲基衍生物、克酮酸及其二氰亚甲基衍生物等各系列电解质分子结构、分子结构与电导率、阴离子结构与电化学稳定性的关系。

A chromium free conversion coating at least equivalent in corrosion protective quality to conventional chromate conversion coatings can be formed on metals, particularly cold rolled steel, by a dry-in-place aqueous acidic liquid comprising: a component of anions, each of said anions consisting of at least four fluorine atoms and at least one atom of an element selected from the group consisting of titanium, zirconium, hafnium, silicon, and boron, and, optionally, ionizable hydrogen atoms, and optionally, one or more oxygen atoms; a component of cations of elements selected from the group consisting of cobalt, magnesium, manganese, zinc, nickel, tin, zirconium, iron, and copper; the ratio of the total number of cations of this component to the total number of anions of component being at least 1:5; sufficient free acid to give the composition a pH in the range from 0.5 to 5.0; a component selected from the group consisting of phosphorus-containing inorganic oxyanions and phosphonate anions; and a component selected from the group consisting of water-soluble and water-dispersible organic polymers and polymer-forming resins and, preferably, also including a component selected from the group consisting of tungstate, molybdate, silicotungstate, and silicomolybdate anions.

通过对包含以下成分的含水酸性液体进行干燥，可以在金属上形成无铬的转换涂层，该涂层与普通铬酸盐转换涂层相比，至少在抗腐蚀质量上等效：$_一种阴离子成分，所述各个阴离子包括至少4个氟原子，至少选自钛、锆、铪、硅与硼元素中的1个原子。任选地可离解的氢原子，任选地1个或多个氧原子；$_一种选自钴、镁、锰、锌、镍、锡、锆、铁与铜元素的阳离子成分，上述成分的阳离子总数与成分内的阴离子总数之比至少为1∶5；$_足够的游离酸以使该组合物的pH值在0.5～5.0的范围内；$_一种选自含磷的无机含氧阴离子与膦酸盐阴离子的成分；$一种选自水溶性与水可分散性有机聚合物与聚合物形成的树脂的成分，优选还包括一种选自钨酸盐、钼酸盐、钨硅酸盐与钼硅酸盐阴离子的成分。

In borate or phosphate buffered NaCl solutions with a constant total concentration of borate or phosphate, E_ increases with an increase in pH. With the increase of the concentration of chloride ions, E_ decreases markedly in the test solutions. Moreover, the buffer capacity and concentration of nonaggressive anions in the test solutions also exerts some effects on the crevice corrosion of Type 304 stainless steel. Furthermore, the cooperative inhibition effect of the environmental factors on crevice corrosion was investigated. The potential of crevice corrosion E_(cc shows a strong dependence on a parameter J, which was called as general environmental factor and defined as the product of concentration of nonaggressive anions, pH, buffer capacity and concentration of chloride ions.

在含NaCl 的硼酸或磷酸盐缓冲溶液中，在相同的缓冲溶液总浓度下，E_c随pH 值增加而增加；但随着氯离子浓度的增加，E_c显著降低；另外缓冲容量及其阴离子对304 不锈钢缝隙腐蚀也有影响；最后实验研究了这些环境影响因素的协同影响规律，得出环境综合影响因素参数J，J 由pH 值、缓冲容量、氯离子浓度及其缓冲溶液中其它阴离子浓度定义，缝隙腐蚀电位与参数J 有好的线性关系。

The electric conductivity of solid polyiodides increases largely as the aggrandizement of polyiodide anions"polymerization degree. The solid polyiodides have excellent sterilizing effects and the effect of tetra-n-butyl ammonium undecaiodide is the best of them, and the sterilizing effects increase as the aggrandizement of polyiodide anions" polymerization degree. The sterilizing effects of resinic polyiodides increase as the aggrandizement of polyiodide anions polymerization degree, the heptaiodide resinic polyiodide has better sterilizing effects than the triiodide and pentaiodide.

固体高聚碘系列化合物的电导率随着高聚碘阴离子聚合度的增加而增加，并且增幅较大；固体高聚碘对常见细菌均具有很好的杀灭作用，并且随着高聚碘阴离子聚合度的增加，杀菌能力也随着增强，其中正四丁基十一碘化铵杀菌剂的效果最佳；树脂高聚碘随着高聚碘阴离子聚合度的增加，杀菌能力增强，碘七树脂高聚碘的杀菌效果要明显好于碘三树脂和碘五树脂高聚碘。

This Ph.D. thesis describes further studies on theformation of fluorinated phosphorus ylide-anions resultingfrom organometallics and their reactions, stereochemistry andapplications in organic synthesis. We found that inverse stereochemical results wereobserved in the reaction of the fluorinated ylide-anions withvarious proton donors.

本博士论文进一步研究了用有机金属试剂对含氟膦叶立德的亲核加成导致的叶立德阴离子的反应性、立体选择性及其在有机合成中的应用：首次发现含氟叶立德阴离子在与不同的质子化试剂作用时，反应呈现完全相反的立体化学结果。

It has been found that the interlayer distance increases first and then decreases with the increase of pH value,which is due to the change of orientation of tartaric anions and malic anions in the interlayer region.

结果显示，随着pH值的升高，插层LDHs层间距先增大后减小，这是由于客体阴离子在LDHs层间的排布方式不同造成的。

Structural analysis reveals that the assemblies of these complexes are mainly directed by counter anions, followed with the change of anions from simple inorganic species (SCN~-/dca/Cl~-) to organic ones (ip/nip/tp/chdc), diversiform structures are formed varying from mononuclear, tetranuclear molecules to infinite 1-D and 2-D frameworks.

第三章利用4-bpt的同分异构体4-氨基-3，5-双(2-吡啶基)-1，2，4-三唑(2-bpt)作为螯合试剂，与多种无机/有机阴离子以及金属Cd~盐反应，得到了一系列Cd~配位化合物(7-15)。

The absorption and distribution of chromium were studied in ryeusing nutrient culture technique and pot experiment.

采用不同浓度K2CrO4(0，0.4，0.8和1.2 mmol/L)的Hoagland营养液处理黑麦幼苗，测定铬在黑麦体内的亚细胞分布、铬化学形态及不同部位的积累。

By analyzing theory foundation of mathematical morphology in the digital image processing, researching morphology arithmetic of the binary Image, discussing two basic forms for the least structure element: dilation and erosion.

通过分析数学形态学在图像中的理论基础，研究二值图像的形态分析算法，探讨最小结构元素的两种基本形态：膨胀和腐蚀；分析了数学形态学复杂算法的基本原理，把数学形态学的部分并行处理理念引入到家实际应用中。