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Sn with the content of 0.004% in the lithosphere is almost in presence of cassiterite and little in presence of Sn-contained sulfide. Since 1980s, the anticancer active study on organic complex compounds has attracted considerable attentions, it becomes another hot issue after the study on Pt. When time up to the year 1989, the anticancer active measurement of more than 2000 kinds of Sn-contained complex compounds have been carried out by Cancer Academy, U.S, with the results showing half of these Sn-contained complex compounds posses antileucocythemia(P388) activity. Thereafter, Sn-contained complex compounds synthesized by hydrothermal reaction also become a hot issue people focus on.

Sn在地壳中的含量为0.004%,几乎都以锡石的形式存在,此外还有极少量的Sn的硫化物。20世纪80年代以来,人们对Sn有机配合物抗癌活性的研究产生了浓厚兴趣,成为继顺铂之后又一活跃的研究热点,到1989年,美国国家癌症研究所对2000多种Sn的配合物进行了抗癌活性测定,结果表明,50%的配合物具有抗P388白血病活性,故水热溶剂热合成锡的配合物也成为人们的研究热点。

Analogous complexes 3a" and 4a"= CpRu(PPh32, Ar = para-C6H4OMe containing methoxy group at the para-position of gem-diphenyl group were similarly obtained from protonation of the corresponding acetylide complexes via formation of vinylidene intermediate. But only complex 3a'= CpRu(PPh32, Ar2 = fluorenyl is stable in solution, and decomposed to unidentified complex when heated to reflux in THF. Deprotonation of complex 4a in the presence of base gives neutral acetylide complex 6a.

在两个相邻位置的苯基对位位置上接有一甲氧基的衍生物3a&和4a&也可利用类似的质子化反应合成,唯有错合物3a'= CpRu(PPh32, Ar2 = fluorenyl 可以稳定於溶液中,不会进行上述反应,如将其溶於四氢呋喃溶液加热至沸腾则会分解产生无法鉴定的化合物。

Distribution ratios of complex extraction for different operation conditions were forecasted. Using mass action law, the liquid-liquid equilibrium models of complex extraction of monobasic and polybasic carboxylic acid have been successfully induced, and physical extraction were also considered in the model. On the basis of orthogonal experiments, the models of equilibrium distribution ratios were established. The processes of complex extraction were tested and verified. Comparing experimental data with model values, it could be held that the regression precision of model was rather high and the model supplied fundamental data for industrial amplification and practical use of complex extraction.

采用质量作用定律分析方法,成功地推导了同时考虑物理萃取的一元及多元羧酸络合萃取通用液-液平衡数学模型,并在正交试验基础上建立了磷酸三丁酯络合萃取丁酸、三烷基胺(7301)萃取丁酸、丁二酸、柠檬酸的平衡分配系数模型,从平衡角度对络合萃取过程进行了验证与预测,通过实验数据与模型计算值比较,表明模型的拟合精度较好,从而为络合萃取技术的工业放大与实际应用提供了重要依据。

The catalytic activity of the mono- and bi-nuclear complexes, and unsymetric complex 〓〓 MeNTB =tris ( N-methylbenzimidazol-2-ylmethyl amine and tetranuclear complex 〓L = N, N, N', N'-tetrakis (N-methylbenzimidazol-2-ylmethyl-1,4-diaminobutane for oxidation of hexane was examined. Thedi-iron complexes with one exchangeable monodentate ligand and unsym-metric(μ-carboxylato) diiron complex exhibit high catalytic ac-tivity, while mononuclear Fe complex are inactive.

这些单核、双核化合物、不对称化合物〓-三氨和四核化合物〓四-1,4-丁二胺催化氧化环己烷的催化活性被测试,结果表明含有可交换配体氧桥联双核Fe化合物和不对称双核Fe化合物表现很高的催化活性,而单核的Fe化合物是非催化活性的。

Therefore,the northern Sulu UHPM zone can be divided into four petrological tectonic units from southeast to northwest:Haiyangsuo metamorphic complex (eclogitized crystalline basement of the Yangtze craton),Rongcheng UHPM complex,Weihai metamorphic complex (granulites retrograded from UHPM eclogites) and Kunyushan boundary metamorphic magmatic complex.

由此笔者将苏鲁变质带北部由南向北划分为海阳所变质地块(榴辉岩化扬子陆块基底变质单元)、荣成变质地块、威海变质地块(麻粒岩相叠加变质的超高压构造岩片)、昆嵛山边界杂岩带。

Comparing the landscape types of 1995 with that of 2005, we find out that:①the natural arbors are decreasing, with patches more fragmentation, size more odds, shapes more complex;②the area of natural shrubberies is increasing, with patches less fragmentation, shapes more simple and formulary ,the size of patches more even;③the area of natural grasses is increasing, with patches less fragmentation, shapes of patches more odds;④the area of timbers is increasing, with patches more dominance in landscape, more connectivity;⑤the area of Eucalyptus increases, with patches less fragmentation, shapes of patches more complex , more convergence, more connectivity;⑥the area of orchards is increasing, more connectivity;⑦the patches of the rubber is becoming more assemble, more connectivity, more formulary;⑧the area of plowland increases;⑨the area of reservoirs, rivers and ponds increases, with patches more assemble;⑩the area of cities decreases, with patches more dispersing, with shape more complexthe area of countries increases, with patches less connectivity, more dispersing, with shape more complex; the patches of the rest lands are more dispersing, with shape more complex;(3)In the process of economic development in the upper reaches of the Changhuajiang river watershed, a series of the ecological environment problems have appeared because a lot of landscape function broke off, and the connection of human landscape with natural landscape decreased, which aroused by the fragmentation of natural and semi-nature landscapes increased, the stability of the landscape structure decreased, as well as stress of human disturbance, resource and environment upon the landscape increased gradually.

3昌化江上游流域在经济发展进程中,自然与半自然景观破碎度增加,自然景观结构稳定性下降,人为干扰、资源和环境对景观胁迫逐渐增大,中断了许多生态过程,导致城市等人文景观与自然景观连接度很差,产生了一系列的生态环境问题。

This thesis makes use of complex numbers to study geometry. It mainly considers the following questions: using complex numbers to express collected points and curves on the level;geometric applications of complex numbers on collinear,concurrent,round,Mobius Mappings of Complex numbers problems,etc..Meanwhile,this thesis recommends some methods for thinking on mathematics.

本文利用复数来研究几何,主要考虑如下的问题:平面上的点集的复数表示;平面曲线的复数表示;复数在共线、共点、共圆、复数的麦比乌斯变换等几何问题上的应用,在说明这些应用的同时介绍一些数学上常用的思考方法。

The five prosthetic groups (FAD, [2Fe-2S], [4Fe-4S], [3Fe-4S] and heme group) required for electron transfer from succinate to ubiquinone were unambiguously assigned into the electron density map. Besides, we find there are some electron densities around the Qp pocket at the matrix side and we believe it represents the head structure of ubiquinone, which is proved by the inhibitor bound structure that 2-TTFA just locating at the Qp site. At the same time, we find there is the second 2-TTFA binding site, locating the inter-membrane side. This finding will change our knowledge about the electron transfer inside Complex II and the ubiquinone transfer between Complex II and Complex III, and endow a new role of Complex II in electron transfer chain.

除了对各个电子传递体( FAD ,[2Fe-2S],[4Fe-4S],[3Fe-4S]以及血红素分子)进行精确定位外,我们在该结构跨膜区靠近线粒体基质一端的口袋 Qp 中,发现了一些电子密度,认为是所结合的辅酶 Q 的头部结构,这一点被与抑制剂结合的复合体的结构所证明,在该结构中, 2- TTFA 恰好结合在口袋 Qp 中,同时,我们还发现了第二个2- TTFA 的结合位点,位于跨膜区靠近线粒体膜间隙一端的口袋 Qd 中,这个发现具有全新的意义,将影响人们对电子在复合物 II 中传递以及辅酶 Q 在复合物 II 与 III 之间转移的认识,促使人们重新复合物 II 在线粒体呼吸链中的角色。

It is presented to calculate the complex index,the complex E vector and the complex angle of refraction of evanescent wave in crystal.

本文研究了晶体界面上的全反射。我们如何计算迅衰波的复折射率、复折射角和复电场矢量。

The key of studying this kind of complex system, is adopting the theory and methodology of complex system, combining the basic law of rock mechanics, found the scientific model and system info of complex system. To nonlinear, anomalistic geometry et.

对于这样的复杂性系统研究的关键,是采用复杂性系统的理论方法,并结合岩石力学的本质规律,采用适当的研究方法,建立复杂性系统的科学模型和理论体系。

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