查询词典 allylic

Thus. Treatment of CR1R2=C=CH2 (R1 = R2 = Me; R1 = H, R2 = n-Bu; R2 = Ph; R2 = cyclohexyl; R2 = cyclopentyl, R2 = C6H5O, R2 = 2-IC6H4O, R2 = 4-IC6H4O) with bisdiborn in the presence of Pd2 (5 mol %) and 3-iodo-2-methyl-2-cyclohexen-1-one (5 mol %) in toluene at 80 oC gave products bearing both vinylic and allylic boron moieties in good to excellent yields.

但我们发现可以使用Pd金属错合物与有机碘化物共同催化下的系统，来进行此种加成反应。溶剂的选择以甲苯为最佳，Pd错合物以没有强配位基存在为最好的选择。

Bromo-2-sulfolene (2) reacted with substituted benzoic acid salt s 3a～3c or alizarin yellow (3d) to give four novel allylic substitution products 4a～4d by esterification reaction, respectively.

以3，4-二溴环戊砜(1)为原料，在无水吡啶作用下发生消除反应，得到反应中间体4-溴-2-环戊烯砜(2)，再分别与一系列取代苯甲酸盐3a～3c以及茜素黄GG(3d)发生酯化反应，合成出4种新环戊烯砜衍生物4a～4d，并用IR，1HNMR，MS，元素分析等表征了它们的结构。

In the course of our study the chemistry of arenes contaning allylic acetates moiety under the catalysis of palladium, we found an efficient synthesis of benzocycles via intramolecular Friedel-Crafts reaction of halogen free 6-acetoxy-4alkenyl arens.

我们在设计钯催化的碳—氢键活化时，发现了含有烯丙基醋酸酯侧链的芳烃的三氟醋酸促进的分子内的Friedel-Crafts反应，从而为有效合成苯并六元环结构提供了一个方便的方法。

This novel reagent was treated with LDA to produce polystyrene-supported a-seleno carbanions, which reacted with alkyl halides and epoxides, followed by stereospecific selenoxide syn-elimination to give olefins and allylic alcohols respectively.

它与LDA反应形成α—硒基稳定的碳负离子，再与卤代烃或环氧化合物发生α—烷基化反应，烷基化后的树脂可以在30%的双氧水中进行氧化-消除，以良好产率和较高纯度合成了取代烯烃或烯丙基醇。

E. . The epoxidation of cis-allylic alcohols is difficult, and with 20％mol Ti 〓 and 30％mol tartrates, up to 80％e.

的对映选择性被得到；对难于环氧化的顺式烯丙基醇，使用20％mol四异丙氧基钛和30％mol酒石酸酯得到最高80％e.e。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新