查询词典 allylic

Grasp the electron delocolization theory; be capable of judging the relative stability of allylic and benzylic free radicals and carbocations, know the relative stability of dienes and other multiple unsaturated hydrocarbons; grasp the characteristics for the nucleophilic substitution reactions of allyl halides and benzyl halides, and the addition reactions of conjugate dienes.

掌握电子非定域化理论；能够分析判断烯丙基、苄基自由基和正离子的稳定性和二烯及多重不饱和碳氢化合物的稳定性；掌握烯丙基、苄基卤代物的亲核取代反应特性和共轭二烯的加成反应。

Moreover,the selective oxidation of primary and secondary alcohols to corresponding carbonyl compounds with the multinuclear copper complexes Cul-Cu4 as catalysts have been conducted using TBHP and O_2/TEMPO,respectively.Among them,the copper complex Cu3 showed the best performance.On the performances of the two classes of oxidants,benzylic and heterocyclic alcohols could be effectively oxidized to carbonyl compounds.Specifically,the secondary alcohols could be effectively oxidized to ketones with excellent selectivity up to 100%in the presence of TBHP and the allylic alcohols could be effectively oxidized to aldehydes in the presence of O_2/TEMPO system.

实验结果还表明，在TBHP或O_2/TEMPO存在下，各配合物催化剂均能使各种取代芳香伯/仲醇以及杂环醇等以不同程度的转化率和选择性转化成相应的醛或酮，其中，配合物Cu3在O_2/TEMPO存在下可使苯甲醇和烯丙醇等以较高转化率和近100%的选择性转化成相应的醛，而对其它芳香醇和脂肪伯/仲醇等的催化性能则较差；在TBHP存在下，配合物Cu3则可使1-苯乙醇和其它仲醇以较高转化率和近100%的选择性转化为相应的酮，但对各类其它伯醇选择氧化的性能相对较差。

A process for the carbonylation of allylic butenyl ether (for example, methyl crotyl ether, 3-methoxybutene-1 and mixtures thereof) or mixture of butadiene and alcohol and production of beta-gamma unsaturated carboxylic acid esters (for example, methyl-3-pentenoate) utilizing a rhodium-containing catalyst for example, dicarbonylacetylacetonate rhodium(I or the like promoted with an iodide-containing compound (for example, HI, AlI3, SnI4, TiI4, CrI3, and CoI2 or the like).

一种将烯丙型丁烯基醚(如甲基巴豆基醚、3－甲氧基丁烯－1及其混合物)或者丁二烯与醇的混合物羰基化的方法，以及由含碘化物化合物(如HI、AlI3、SnI4、TiI4、CrI3和CoI2或等效物)促进，用含铑催化剂如二羰基乙酰丙酮酸铑(I或其等效物制备β－γ不饱和羧酸酯(如甲基－3－戊烯酸酯)的方法。

In the final step of the synthetic pathway leading to cabergoline, an allylic acid intermediate of Formula is reacted with N-(3-dimethylaminopropyl)-N-ethyl carbodiimide to produce cabergoline, i.e.

在卡麦角林合成路径的最后一步，分子式中的一个烯丙酸基中间体同碳二亚胺耦联剂反应生成卡麦角林，如

In chapter four, the preperation of ytterbium diiodide was examined. The reductive cleavage of Se-Se bond and S-S bond induced by ytterbium diiodide was investigated. The reaction of diselenides and disulfides with allylic bromide promoted by ytterbium diiodide was also examined. The intermolecular Barbier-type reaction induced by ytterbium diiodide was studied. In the last section of this chapter, the intermolecular reductive coupling of nitriles with azides induced by samarium diiodide was investigated.

第四章，研究了二碘化镱的制备方法，以及二碘化镱作为一种优良的单电子转移试剂在有机合成中的应用：二硒醚的Se--Se键和二硫醚S-S键的还原断裂，及其在合成烯丙基硒醚，硒代酯和烯丙基硫醚，硫代酯中的应用，实验结果表明二碘化镱也能促进分子间的Barbier反应，而文献认为二碘化镱不能促进分子间的Barbier反应；最后研究了二碘化钐促进的叠氮化合物与腈的交叉还原偶联反应，一步高收率地制备脒的方法。

Some non-coded a , a -disubstituted amino acids could be obtained with up to 75.3% ee by using ketone imino esters as nueclophilles in the allylic alkylation reaction.

当利用亚胺的氨基酸酯衍生物时，可以得到一些非天然的季碳氨基酸衍生物， ee 值最高可以达到75.3%。

The nature of adsorbed intermediates detected by IR are:a π-allylic intermediate;an enolic type compound formed in the presence of Bronsted acid sites;a π-boned propylene species interacting with Lewis acid sites.

nsted酸位作用形成的烯丙醇物种；异丙醇中间物种。

We studied DBU-mediated Ireland-Claisen rearrangement. Using DBU as the base for enolization of allylic esters of unsaturated acids 9-16, we found a novel DBU-mediated tandem Ireland-Claisen rearrangement /isomerization reactions and established a consecutive Ireland-Claisen rearrangement /Cope rearrangement.

利用DBU作为烯醇化碱，对含有活泼质子的烯酸烯丙酯类化合物9-16的Ireland-Claisen重排进行了系统的研究，创建了一条新颖的DBU-促进的Ireland-Claisen重排/异构化串联反应及Ireland-Claisen重排/Cope重排的串联反应路线。

In this dissertation, polyethylene glycol monomethyl ether of 2000 molecular weight as soluble support, an array of soluble polymer-supported tartrate esters were designed, synthesized, and applied in asymmetric epoxidation of allylic alcohols.

本论文以平均分子量为2000的聚乙二醇单甲醚为可溶性支载体设计和合成了一系列可溶性聚合物支载的酒石酸酯配体，并将它们用于烯丙基醇的不对称环氧化反应。

Brominated butyl rubber was prepared by solution method,and its microstructures were characterized by 1H-NMR. It has three main microstructures,that is the unbrominated isoprene structure,the exomethylene allylic bromide structure (structure Ⅱ) and the bromomethyl olefinic structure (structure Ⅲ).

通过溶液法制备溴化丁基橡胶，并用核磁共振对溴化丁基橡胶的微观结构进行了分析，其中存在3种主要微观结构，即未溴化的丁基橡胶结构，溴代仲位烯丙基结构及溴代伯位烯丙基结构。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新