查询词典 allylation

They were principally used to catalyze aldol, allylation, Diels-Alder, ene and Friedel-Crafts reactions.

它们主要被用来催化Aldol，烯丙基化，Diels-Alder，Ene和Friedel-Crafts等反应。

In this study, we carried out the allylation of anilines with allylic acetates in PEG-H2O system in the presence of palladium as catalyst. N-allylation of anilines was achieved.

在本研究中，我们完成利用钯催化剂，在水及聚乙二醇系统中，使苯胺类和乙酸烯丙酯类进行烯丙基化反应，并探讨各苯胺类反应物之结果。

E. 3-allyloxyisothiazole and N-allylisothiazolone, were synthesized with 3-mercaptopropionate as the starting material through ammonolysis, cyclization and allylation reactions.

以3-巯基丙酸甲酯为原料，经氨解、关环、烯丙基化合成了2种含有不饱和侧链的异噻唑类化合物，分别为3-烯丙氧基异噻唑和N-烯丙基异噻唑啉酮。

Moreover, the polymeric arsine palladium(0) complex is an efficient catalyst for the carbonyl allylation of aldehydes and the coupling reaction of aryl halides with terminal alkynes or Grignard reagent.

该聚合物负载的胂钯(0)配合物还是醛的羰基烯丙基化及芳基卤化物与端炔、Grignard试剂的交叉偶联反应的有效催化剂。

Various inorganic acid, such as ammonium chloride, copper sulfate, aluminum sulfate, mercury chloride, cerium sulfate and cerium chloride, have been evaluated for copper powder, zinc powder, or tin powder-mediated allylation reactions of carbonyl compounds with allyl bromide in aqueous medium.

结果表明：在同样的反应条件下，与铜粉或锌粉作用的此类反应相比，锡粉能更好的作用羰基烯丙基化反应，并且该反应的产率都比较高；在同样的金属促进剂存在下，硫酸亚铈的促进性能是所有无机酸中最好的。 2、研究了二氧化碳促进羰基化合物烯丙基化反应。

This dissertation focused on two types of reactions, oxidative allylation of 1, 3-dicarbonyl compounds and ring-opening allylation of epoxides.

我们重点考察了两类反应：1， 3－二羰基类化合物的不对称烯丙基化反应和环氧化合物的开环烯丙基化反应。

Because of the rapid development of allylation reaction in aqueous media, allylation reaction mediated by new metal systems or metal systems, and its mechanism are reported increasingly.

水相烯丙基化反应由于其发展速度较快，新的金属及金属体系参与的烯丙基化反应以及水相烯丙基化反应的机理研究不断被报道。

The terminal allylation reaction was studied which was influenced by reaction time, reaction temperature, category and dosage of allylation reagent and molecular weight of polyether.

其次对双羟基聚醚的端烯丙基化反应进行研究，讨论了反应时间、反应温度、聚醚分子量、烯丙基化试剂的种类和用量对反应的影响。

In this system, the allylation was selectively toward aldehyde in the presence of ketone; the allylation squinted toward aliphatic aldehyde in the presence of aromatic aldehyde.

该方法不仅对于醛和酮具有很高的化学选择性，而且对于芳香醛和脂肪醛也有很好的选择性，当存在芳香醛时，脂肪醛优先发生烯丙基化反应。

This work, concentrated on the asymmetric allylation of aldehydes controlled by different chiral auxiliaries prepared from rotational pure tartaric acid, can be divided into three parts.The first part aims to review the developments of chiral drugs and asymmetric synthesis, from which derived the present research topic backgrounds and works.Synthesis and applications of allylation from aldehydes are the second part of the thesis. By optimizing the reaction conditions, such as solvents, temperature, time and chiral auxiliaries like N,N\'-dibenzyl tartamide, N,N\'-p-dimethylphenyl tartamide, N,N\'-o-dimethylphenyl tartamide, N,N\'-o-dichlorophenyl tartamide, N,N\'-a-dinaphyl tartamide, N,N\'-dicyclohexyl tartamide and N,N\'-diphenyl tartamide, ideal experimenttal conditions are obtained according to HPLC monitoring, as well as the auxiliaries\' recoveries experiments. Starting from benzaldehyde and 3-bromopropaldehyde, N,N\'-dibenzyl tartamide is considered the best auxiliary in this reaction.

本文介绍了醛的不对称烯丙基化反应，以光学纯酒石酸为原料，研究了不同构型手性配体在醛的烯丙基化反应中的立体选择性，全文共分三部分十个章节：第一部分对当前手性药物和手性技术进行了概述，并由此展开了本文的研究背景和任务；第二部分为有机合成部分，对醛的不对称烯丙基化反应进行了深入探讨，以苯甲醛为原料对反应条件进行优化，在优化的反应条件下对制备的七种可回收手性酰胺配体(N-苄基酒石酸二酰胺、N-对甲苯基酒石酸二酰胺、N-邻甲苯基酒石酸二酰胺、N-邻氯苯基酒石酸二酰胺、N-a-萘基酒石酸二酰胺、N-环己基酒石酸二酰胺和N-苯基酒石酸二酰胺)进行筛选，优化配体回收实验条件，最终确定出N-苄基酒石酸二酰胺在苯甲醛的不对称烯丙基化反应中具有较大优越性，结晶回收的手性配体光学纯度保持不变。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新