查询词典 alkali reaction

To restore the ability of chromium can be dissolved in sulfuric acid, hydrochloric acid and High-FE acid and release hydrogen, but also of pure chromium with aqua regia does not work, when there is the presence of halogen ions in the acid can not be long-term stability, high temperature with alkali, hydrogen sulfide, sulfur steam, phosphorus, ammonia, such as carbon monoxide and water vapor reaction of the corresponding compounds, in the high temperature reaction of silicon into the silicide also chromium, chromium alloys with many metals generate a wide range of industrial applications, such as chromium-manganese stainless steel is used extensively for chemical plants.

铬的还原能力强，能溶于硫酸、盐酸和高FE氯酸而放出氢气，但纯铬连王水也不起作用，当有卤素离子存在时，在酸中不能长期稳定，高温时能与强碱、硫化氢、硫蒸汽、磷、氨、一氧化碳和水蒸汽等反应生成对应的化合物，在高温下还能与硅反应成硅化铬，铬能与许多金属生成合金广泛在工业上应用，如铬锰不锈钢大量用于化工设备。

In order to determine the influence of alkali metals on charge properties for new burdening,the reaction and distribution of alkali metals in Blast Furnace were presented.

为了解新配矿条件下碱金属对高炉炉料性能的影响，研究了碱金属在高炉内的反应及分配。

First, a chlorinator was self-designed in this paper, and dichloride of 2-methyl-1-propene was synthesized by 2-methyl-1-propene reacted with chlorine fast in this reactor. By means of the Orthogonal Experiments design and single factor experiments, the influence of several reaction variables on the yield were examined and the optimum reaction conditions under the intervallic operation were obtained, the yield and selectivity of dichloride of 2-methyl-1-prop-ene were more than 65% and 80% respectively. Second, the preparation of 2-methylene-1, 3-propanediol, which dichloride of 2-methyl-1-propene reacted with alkali was investigated. By means of the Orthogonal Experiments design and single factor experiments, the influence of several reaction variables on the yield were examined and the optimum reaction conditions under the intervallic operation were obtained, the conversion of dichloride of 2-methyl-1-propene was 100%. Moreover the preparation of MPO, which 2-methylene-1, 3-propanediol reacted with hydrogen, in presence of Al_2O_3-Pd catalyst, was gotten, and the product was appraised.

本文在氯化反应过程中，自行设计制作出了氯化管式反应器，在该反应器中异丁烯和氯气迅速混合反应生成二氯异丁烯，根据该氯化反应特征利用正交试验和单因素试验考察了有关因素的影响并优化得到了最佳工艺条件，二氯异丁烯的总收率达65％以上，选择性达80％；接着，对二氯异丁烯进行水解反应制得了2-甲烯-1，3-丙二醇，讨论了相关因素对水解反应的影响，并通过正交试验和单因素试验得到了较佳工艺条件，二氯异丁烯的转化率达100％；同时还对制备的2-甲烯-1，3-丙二醇在常压下采用三氧化二铝负载钯催化剂催化加氢得目的产物MPO，并对产品进行了鉴定，从而打通了整个工艺路线。

4The obtained solid alkali catalyst was applied to biodiesel preparation with colza oil and used oil as materials respectively and the technics was optimized by sigle-factor and orthogoral experiments with esterification rate as the index. The optimal technique conditions using colza oil were: the amount of solid catalyst 12%, the mol ratio of methanol to oil 9:1, reaction temperature 65℃, reaction time 3h, under which the esterification rate reached to 94.48%.

4以菜籽油和煎炸废油为原料，利用固体碱催化剂催化制备生物柴油，以转化率为考察指标，采用单因素和正交试验对工艺进行优化，得到以菜籽油为原料时制备的最佳工艺参数为固体催化剂投入量2.5％，醇油摩尔比9∶1，反应温度65℃，反应时间3h，转化率达到93.9％；以煎炸废油为原料时最佳工艺参数为反应温度65℃，反应时间3h，固体催化剂投入量4％，醇油摩尔比6∶1，转化率达到91.2％。

In addition, some modifications on several computational methods are also presented. Using LMTO method the electronic structure of several systems are studied, and some results are obtained. They are: The ideal Nb (100) surface has three surface states, the multi-layer relaxed surface has two surface states. The surface energy of the ideal surface is higher than that of the relaxed surface, that means that the multi-layer relaxed surface is more stable than the former one, which supports the LEED results. The mono-layer relaxed Ag (111) surface is the most stable one among several" stable surface models"presented by several researchers. The surface energy of Ag (111) surface is higher than that of surface Ag (001), which supports some experimental results such as different reaction rate at different surface orientations for the same material. The surafce states of Si (111) surface not only locate near the Fermi level, but also in the valence band, which agrees well with Cohen's conclusion. Si (111)-H is an effective model for analysing the surface states and H adsorbed on the back surface is a good method for improving the convincingness of the results obtained on thinner slab models. The surface stability depends on three different kinds of MoSi〓(001) surfaces, the surface with mono-layer Si is the most stable one, and the surface with Mo at the first layer is the most unstable one among them. These are consistant with the Kemoda's experimental results. The valence bands of clean or K adsorbed CdTe (111) surface agrees well with the synchrotron radiation studies. The surface of CdTe (111) consists of four kinds of surface models which show different surface electronic structures and different surface structure stabilities. The conclusion agrees well with Wu's experimental work. The different absorbed alkali metals on the CdTe (111) surface give different adsorption characteristics which have relations not only with the valence electrons, but also with the core ones of the alkali metals. The electonic structures of Si-C alloys are different from that of Si-Ge alloys, and the energy band gaps of Si-C alloys do not increase linearly with Carbon concentration, our conclusion supports Alexander's results, but conflicts with Soref's one.

现分述如下： LMTO方法及其应用方面：1）通过对Nb（100）表面电子态分析发现清洁理想表面有三个表面态，多层弛豫表面有两个表面态；表面能大小说明多层弛豫表面更稳定，支持了LEED结果。2）通过对采用不同方法获得的几种不同Ag（111）表面稳定结构的表面能计算分析，给出了单层弛豫表面为Ag（111）表面的最稳定结构；从Ag（111）单层弛豫表面和Ag（001）表面的表面能比较，发现了Ag（001）表面表面能要比Ag（111）小的，表明了同种物质不同表面取向将表现出不同物理、化学性质，这是与实验中得出的结论是吻合的，3）通过对Si（111）表面态分析，不仅发现了Si（111）表面不仅具有居于费米能级附近的悬挂键所对应的表面态，而且还有很多表面态位于价带能量范围内，与Cohen等结果一致，H饱和slab模型背表面相当于增加了slab层的厚度，是一有效的变相增加slab层厚的方法，弛豫表面较清洁理想表面价带谱们低能端的少许移动，预示着总能降低，说明弛豫表面较清洁理想表面稳定。4）MoSi〓具有三种表面，从费米能级上态密度值大小得到单层Si表面最稳定，Mo原子为表层原子的表面最不稳定，双层Si原子表面居中的结论，这与Kemoda等人实验结果是一致的。5）通过对CdTe（111）表面表面电子态、表面结构稳定性及表面H、碱金属吸附的电子结构系列研究，不仅得出了CdTe（111）清洁及碱金属K吸附价带谱与同步辐射光电子谱相吻合的结果，而且发现了CdTe（111）表面具有四类不同原子近邻特征，表现出四类不同的表面结构及电子结构特征：不同表面态分布、不同的表面结构稳定性（表层原子与次层原子成三键有一悬挂键的表面要比表层原子与次层原子成一键有三悬挂键稳定（与Wu等人实验结果一致））、不同的H吸附特性。

Meanwhile, the dosages of etherification agent and alkali influencing on degree of substitution and reaction efficiency are discussed. The optimal alkali catalyst dosage (1%) is determined in the process of preparing cationic starch.

同时讨论了醚化剂用量和碱的用量对取代度和反应效率的影响，确定了合成阳离子淀粉反应的最佳碱催化剂用量为1%。

A method for forming an aqueous chlorine dioxide solution is disclosed which includes reacting in a reaction vessel an acid reaction solution containing a hydroxy carboxylic acid and a companion acid with an alkali metal salt of a chlorite ion.

本发明公开了一种生成含水的二氧化氯溶液的方法，其中包括在反应容器中让含有羟基羧酸和配对酸的酸的反应溶液与亚氯酸根离子的碱金属盐进行反应。

The results showed high class PbSt2 could be synthesized by this new saponifying process.Compared with metathetical process,the reaction time shortened,liquid-solid ratio and moisture content of filter cake decreased.Powder product could be prepared by one-step process,and particle product by two-step process.For the optimum processing conditions,the reaction temperature and time for one-step process were 65℃ and 10min,the amount of alkali added in the first step was 50%;reaction temperture and time were 65℃ and 10min for the two-step process.

结果表明，用皂化法工艺可得到优等品PbSt2，较复分解工艺，反应时间缩短、液-固比降低、滤饼湿含量比减小，一步式工艺得到粉状产品，二步式工艺得到颗粒状产品；最佳工艺条件为：一步式工艺反应温度65℃，反应时间10min；二步式工艺第一步的加碱量比50%，反应温度65℃，反应时间10min。

Some prescribes about the test method of alkali aggregate and alkali-aggregate reaction have been shown in the regulations of geologic reconnoitering and the test method of the hydraulic concrete.

中国已建的混凝土大坝中，有些也含有一定量的碱活性骨料，但由于采用了低标号水泥和大量的活性混合材，因此至今未发生碱骨料破坏反应；但也有个别工程，虽经碱骨料反应的检测，并采用了一定的抑制措施，但运行20年后，在大坝溢流面混凝土中出现了碱骨料反应的微观和宏观裂缝破坏。

The good method to analyze the structural changes of reaction process of melamine modified UF resin by the traditional process alkali-acid-alkali is 13C-NMR. It can also extrapolate potential reaction.

通过13C-NMR可以很好地解析采用传统工艺合成三聚氰胺改性脲醛树脂反应过程中的结构变化，并可推测其发生的反应。

In the negative and interrogative forms, of course, this is identical to the non-emphatic forms.

。但是，在否定句或疑问句里，这种带有"do"的方法表达的效果却没有什么强调的意思。

Go down on one's knees;kneel down

屈膝跪下。。。下跪祈祷