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These dendritic NOBIN derived Schiff base ligands have been applied to titanium catalyzed hetero-Diels-Alder reaction of Danishefshy's diene and aldehydes, affording the corresponding 2-substituted 2, 3-dihydro-4H-pyran-4-one in quantitative yields and excellent enantioselectivities (up to 97. 2%ee). Comparing the reactivities and enantioselectivities of reaction catalyzed by the titanium complexes of these Schiff base ligands, it was found that a series of ligands L〓 were superior to the other three series of ligands L〓, L〓 and L〓, a significant positive NLE and a dendrimer effect existed in the L〓 dendritic catalyst system. The disposition of the dendritic wedges and the dendron size in the ligands were observed to have a significant impact on the enantioselectivity of the reaction.

NOBIN衍生的树枝状大分子希夫碱手性配体与钛形成的配合物在催化不对称杂Diels-Alder反应中的应用将得到的四个系列NOBIN衍生的树枝状希夫碱三齿手性配体与四异丙氧基钛形成的配合物用于催化Danishefsky's diene与醛的不对称杂Diels-Alder反应，通过反应条件的优化，获得了定量的收率和最高达97.2％ee值的对映选择性；考察了这四个系列NOBIN衍生的树枝状希夫碱钛配合物的催化活性和对映选择性，结果发现它们的活性次序依次为L〓≈L〓＞L〓＞L〓，对映选择性次序依次为L〓＞L〓＞L〓＞L〓。

The Diels-Alder cycloadditions of [60] fullerene for preparation of optical limitingmaterials are discussed in chapter 3 and 6. Soluble cycloaddition derivatives of 〓aresynthesized by the reaction of 〓 with indene,1,1'-biindene andcyclopentadiene derivatives.〓Particular, the Diels-Alder cycloaddition of 〓 with1,1'-biindene under controlled conditions affords the stable monoadduct 〓〓of novel structure, which was confirmed by HPLC, FTIR, FD-MS,〓NMR,〓 NMR, HMQC and HMBC spectra, Its two bridgehead cage carbons resonate at70.91ppm, The 〓 NMR spectra showed 38 lines consistent with the 〓 symmetryassociated with [6,6] addition. The 〓 shows similar optical limitingproperties to that of 〓 in toluene for 8ns laser at wave length 532nm. Moreover, thehigh solubility of this adduct in polar solvents such as THF, acetone enables itsincorporation into sol-gel glass matrix. The thin films prepared via the sol-gel methodshow improved OL behaviour compared to those of 〓. The langmuir-Blodgett filmformation and uv-visible absorption of 〓 are also investigated. LBmonolayer of this compound is prepared on the air-water interface at 〓 mol/l. In chapter 4, three water-soluble derivatives of [60] fullerene: fullerol(1), theaddition product (2)of fullerol (1)with polyvinylpyrrolidone and fumaric acidderivative of 〓(3) are synthesized and characterized.

通过Diels-Alder环加成反应，用茚〓和1，1'-联茚〓及取代茂合成了一系列可溶性的〓环加成衍生物，发现可控制反应条件，使1，1'-联茚与〓反应，并高产率地得到具有新颖结构的单加成物，用HPLC、FTIR、FD-MS 及〓、HMQC、HMBC等多种波谱技术对其结构进行表征，测得它的两个〓杂化的桥头碳的化学位移为〓ppm，证明生成的衍生物为6∶6闭式环加成，〓NMR谱中共给出38个信号，表明〓联茚衍生物分子具有〓对称性；在波长532nm，脉冲宽度8ns的激光下，〓联茚衍生物的甲苯溶液的光限幅性能与〓的甲苯溶液相近，由于〓联茚单加成衍生物熱稳定性好，在四氢呋喃，丙酮等极性溶剂中溶解性好，能分别均匀地掺入溶胶-凝胶中，已发现它的溶胶(so1)光限幅性能优于纯〓的光限幅性能；使用Langmuir-Blodgett技术将〓联茚衍生物在空气和水的界面进行了LB单层膜和多层膜实验以及UV-Vis吸收谱研究，通过等温压缩曲线测试，证明浓度为〓〓时，〓联茚衍生物能够形成单层膜。

One synthetic strategy started fromγ-butyrolactone 38, from which a cyclohexadiene intermediate 30 was prepared in an overall yield of 44% in a 7-step procedure after y-butyrolactone underwent a-bromination, dehydrobromination, Diels-Alder reaction, aminolysis, benzylation, bromination and dehydrobromination, with the key step being the Diels-Alder reaction under harsh condition.

其中一个路线从γ-丁内酯38开始，连续经过α-溴化、脱溴化氢、Diels-Alder反应、胺解、苄基化、溴化和脱溴化氢共7步反应，制备了一个环己二烯衍生物30，总产率44％，关键步骤是高温高压下Diels-Alder反应。

Solvent effect on the Diels-Alder reaction was analyzed with four different kinds of solvents: benzyl alcohol, cyclohexanone, toluent and decalin. The results show that the rate of the Diels-Alder reaction increased in more polar solvents and stereoselectivity of TCPD decreased.

在模拟计算基础之上，选择苯甲醇、环己酮、甲苯及十氢萘四种溶剂进行Diels-Alder反应的溶剂效应研究，考察温度、压力变化对反应速度、产物立体选择性的影响。

Also studied was aza Diels-Alder reaction catalyzed by polyclonal antibody. The bicyclic [2, 2, 2] heptene and the aimed immunogen were synthesized via the key intermolecular asymmetric aza Diels-Alder reaction. Then four polyclonal antibodies were obtained by immunizing rabbit.

在研究多克隆抗体催化氮杂Diels-Alder反应中，通过分子间不对称氮杂Diels—Alder反应为关键反应合成了双环[2，2，2]庚烯类半抗原和目标抗原；用目标抗原免疫动物兔后得到了4株多克隆抗体，经动力学测试表明：多抗Aza-Bsa-3#能催化氮杂Diels—Alder反应的进行。

In this article, weh ave utilized the ABEEM-σπ model to research this kind of reactions. Through regional softness values of both the atoms and π bonds, which are calculated by this model, we have interpreted properly the typical and particular stereoselectivity of Diels-Alder reaction. Furthermore, we also have initiatorily probed into the rationality and feasibility in terms of synthesizing heteroatomic -ring compounds using Diels-Alder reaction.

本文利用ABEEM-σπ模型对此类反应进行了研究，通过计算原子和π键区域的电荷分布和局域软度，结合局域硬软酸碱原理对Diels-Alder 反应的立体选择性给出了合理解释，而且还初步探讨了利用Diels-Alder 反应合成杂环化合物方法的合理性和可行性。

The Diels-Alder reactions forming one C—B bond and one C—C bond are always more favorable than the corresponding Diels-Alder reactions forming two C—C bonds, both thermodynamically and kinetically, which is in agreement with experimental observation.

形成一个C—B键的杂Diels-Alder反应都比相应的Diels-Alder反应在热力学和动力学上容易进行，这与实验结果一致。

The study underscores the need for common sense to be exercised by psychiatrists and patients alike, said Lenard Adler, MD, in a telephone interview seeking outside commentary. Dr. Alder is the director of the Adult ADHD Program at New York University Medical Center in New York, where he is also an associate professor of psychiatry and neurology.

Lenard Alder医师在电话访谈中表示，精神科医师及患者都必须具备必要的共识，但是这项需求在本试验中被低估了；Alder是纽约大学医学中心成人ADHD计画的主持人，也是该校的精神科与神经科副教授。

First, when operating the DABCO-catalyzed Ireland-Claisen rearrangement of propargylic acrylates 18b-d, we added dienophiles 40a-f in the reaction system to capture the rearranged allenes products respectively. The Diels-Alder adducts 41a-i were obtained with complete regioselectivity. Thus a novel tandem Ireland-Claisen rearrangement /Diels-Alder reaction process with propargylic acrylates has been developed.

首先在进行DABCO-催化的丙烯酸炔丙酯类化合物18b-d的Ireland-Claisen重排反应的同时，于反应体系中分别加入亲二烯体40a-f捕获重排得到的连二烯中间体，一步反应获得了单一区域选择性的Diels-Alder环加成产物41a-i，从而创建了一条新颖的丙烯酸炔丙酯类化合物的Ireland-Claisen重排与Diels-Alder环加成的串联反应路线。

According to the result of asymmetric Diels-Alder reaction of phenyl-sulfonyl a , P-unsaturated ketones and cyclopentadiene catalyzed by chiral Titanium catalysts and the structure of crystal, we discussed the mechanism of asymmetric Diels-Alder reaction.

根据苯磺酞基取代的a，p一不饱和酮与环戊二烯在钦手性金属催化剂存在下的不对称Diels一Alder反应的结果以及我们测得的单晶结构，初步探讨了不对称催化Die1S一Alder反应的机理。

By using competitive adsorption of activated carbom to remove unfavorable influence of carbon in carbonaceous gold concentrate on leaching process, the leaching rate of gold concentrate can be improved to 88% as compared with 10%by direct cyanidation.

本文论述了利用活性炭竞争吸附作用，消除含炭金精矿中炭在浸出过程中的影响，使金精矿的浸出率可由直接氰化的10％提高到88％。

The only thing you're ever gonna be king of is King of the Stupids!

你只配做傻瓜的国王！