查询词典 alder

TREES ALDER The Alder is the tree of fire.

赤杨： 赤杨是火的树木。

The Diels-Alder cycloadditions of [60] fullerene for preparation of optical limitingmaterials are discussed in chapter 3 and 6. Soluble cycloaddition derivatives of 〓aresynthesized by the reaction of 〓 with indene,1,1'-biindene andcyclopentadiene derivatives.〓Particular, the Diels-Alder cycloaddition of 〓 with1,1'-biindene under controlled conditions affords the stable monoadduct 〓〓of novel structure, which was confirmed by HPLC, FTIR, FD-MS,〓NMR,〓 NMR, HMQC and HMBC spectra, Its two bridgehead cage carbons resonate at70.91ppm, The 〓 NMR spectra showed 38 lines consistent with the 〓 symmetryassociated with [6,6] addition. The 〓 shows similar optical limitingproperties to that of 〓 in toluene for 8ns laser at wave length 532nm. Moreover, thehigh solubility of this adduct in polar solvents such as THF, acetone enables itsincorporation into sol-gel glass matrix. The thin films prepared via the sol-gel methodshow improved OL behaviour compared to those of 〓. The langmuir-Blodgett filmformation and uv-visible absorption of 〓 are also investigated. LBmonolayer of this compound is prepared on the air-water interface at 〓 mol/l. In chapter 4, three water-soluble derivatives of [60] fullerene: fullerol(1), theaddition product (2)of fullerol (1)with polyvinylpyrrolidone and fumaric acidderivative of 〓(3) are synthesized and characterized.

通过Diels-Alder环加成反应，用茚〓和1，1'-联茚〓及取代茂合成了一系列可溶性的〓环加成衍生物，发现可控制反应条件，使1，1'-联茚与〓反应，并高产率地得到具有新颖结构的单加成物，用HPLC、FTIR、FD-MS 及〓、HMQC、HMBC等多种波谱技术对其结构进行表征，测得它的两个〓杂化的桥头碳的化学位移为〓ppm，证明生成的衍生物为6∶6闭式环加成，〓NMR谱中共给出38个信号，表明〓联茚衍生物分子具有〓对称性；在波长532nm，脉冲宽度8ns的激光下，〓联茚衍生物的甲苯溶液的光限幅性能与〓的甲苯溶液相近，由于〓联茚单加成衍生物熱稳定性好，在四氢呋喃，丙酮等极性溶剂中溶解性好，能分别均匀地掺入溶胶-凝胶中，已发现它的溶胶(so1)光限幅性能优于纯〓的光限幅性能；使用Langmuir-Blodgett技术将〓联茚衍生物在空气和水的界面进行了LB单层膜和多层膜实验以及UV-Vis吸收谱研究，通过等温压缩曲线测试，证明浓度为〓〓时，〓联茚衍生物能够形成单层膜。

One synthetic strategy started fromγ-butyrolactone 38, from which a cyclohexadiene intermediate 30 was prepared in an overall yield of 44% in a 7-step procedure after y-butyrolactone underwent a-bromination, dehydrobromination, Diels-Alder reaction, aminolysis, benzylation, bromination and dehydrobromination, with the key step being the Diels-Alder reaction under harsh condition.

其中一个路线从γ-丁内酯38开始，连续经过α-溴化、脱溴化氢、Diels-Alder反应、胺解、苄基化、溴化和脱溴化氢共7步反应，制备了一个环己二烯衍生物30，总产率44％，关键步骤是高温高压下Diels-Alder反应。

Solvent effect on the Diels-Alder reaction was analyzed with four different kinds of solvents: benzyl alcohol, cyclohexanone, toluent and decalin. The results show that the rate of the Diels-Alder reaction increased in more polar solvents and stereoselectivity of TCPD decreased.

在模拟计算基础之上，选择苯甲醇、环己酮、甲苯及十氢萘四种溶剂进行Diels-Alder反应的溶剂效应研究，考察温度、压力变化对反应速度、产物立体选择性的影响。

Also studied was aza Diels-Alder reaction catalyzed by polyclonal antibody. The bicyclic [2, 2, 2] heptene and the aimed immunogen were synthesized via the key intermolecular asymmetric aza Diels-Alder reaction. Then four polyclonal antibodies were obtained by immunizing rabbit.

在研究多克隆抗体催化氮杂Diels-Alder反应中，通过分子间不对称氮杂Diels—Alder反应为关键反应合成了双环[2，2，2]庚烯类半抗原和目标抗原；用目标抗原免疫动物兔后得到了4株多克隆抗体，经动力学测试表明：多抗Aza-Bsa-3#能催化氮杂Diels—Alder反应的进行。

In this article, weh ave utilized the ABEEM-σπ model to research this kind of reactions. Through regional softness values of both the atoms and π bonds, which are calculated by this model, we have interpreted properly the typical and particular stereoselectivity of Diels-Alder reaction. Furthermore, we also have initiatorily probed into the rationality and feasibility in terms of synthesizing heteroatomic -ring compounds using Diels-Alder reaction.

本文利用ABEEM-σπ模型对此类反应进行了研究，通过计算原子和π键区域的电荷分布和局域软度，结合局域硬软酸碱原理对Diels-Alder 反应的立体选择性给出了合理解释，而且还初步探讨了利用Diels-Alder 反应合成杂环化合物方法的合理性和可行性。

The Diels-Alder reactions forming one C—B bond and one C—C bond are always more favorable than the corresponding Diels-Alder reactions forming two C—C bonds, both thermodynamically and kinetically, which is in agreement with experimental observation.

形成一个C—B键的杂Diels-Alder反应都比相应的Diels-Alder反应在热力学和动力学上容易进行，这与实验结果一致。

First, when operating the DABCO-catalyzed Ireland-Claisen rearrangement of propargylic acrylates 18b-d, we added dienophiles 40a-f in the reaction system to capture the rearranged allenes products respectively. The Diels-Alder adducts 41a-i were obtained with complete regioselectivity. Thus a novel tandem Ireland-Claisen rearrangement /Diels-Alder reaction process with propargylic acrylates has been developed.

首先在进行DABCO-催化的丙烯酸炔丙酯类化合物18b-d的Ireland-Claisen重排反应的同时，于反应体系中分别加入亲二烯体40a-f捕获重排得到的连二烯中间体，一步反应获得了单一区域选择性的Diels-Alder环加成产物41a-i，从而创建了一条新颖的丙烯酸炔丙酯类化合物的Ireland-Claisen重排与Diels-Alder环加成的串联反应路线。

The wood properties of alder is similar to that of poplar and birch which could be used to produce different kinds of pulp.The paper is a review about pulp production potential and status of pulping/paper-making and research on wood property of alder in the world.

桤木是一种商用种植较有发展前景的阔叶树种，生长迅速、固氮能力强，木材性质类似于杨木和桦木，可用来开发研制不同的浆种，与针叶木浆或其它阔叶木浆配抄可以生产高质量的印刷纸和书写纸等。

According to the result of asymmetric Diels-Alder reaction of phenyl-sulfonyl a , P-unsaturated ketones and cyclopentadiene catalyzed by chiral Titanium catalysts and the structure of crystal, we discussed the mechanism of asymmetric Diels-Alder reaction.

根据苯磺酞基取代的a，p一不饱和酮与环戊二烯在钦手性金属催化剂存在下的不对称Diels一Alder反应的结果以及我们测得的单晶结构，初步探讨了不对称催化Die1S一Alder反应的机理。

As of Tuesday, Google's results were still censored in China.

截至周二，谷歌的搜索结果仍受中国审查。

In order to make the positive action increase and negative one decrease, the sub-forces of the social factors must be adjusted to form a centripetal force.

在这一过程中，人的主体性发挥是社会有机体健康发展的灵魂。