查询词典 aldehydes

Progress in pinacol coupling of aldehydes and ketones using low valent titanium is reviewed in recent years.

由低价钛络合物诱发的片呐醇偶联反应，具有良好的化学选择性和立体选择性，近几年来又引起有机化学家们的极大兴趣与重视。

In aprotic solvents magnesium effects pinacol reductive coupling of aldehydes and ketones.

在非质子性溶剂，镁对频纳醇与醛和酮的还原耦合反应也有一定效果。

Now, a convenient, efficient pinacol coupling of aldehydes mediated by zinc in good yields has been carried out in ammonia water in the presence of a little crown ether. Adding a small amount of crown ether was highly effective to enhance the yields of pinacol from 63% to 84%.

本文报道一种简便、有效的水相呐偶合反应，它是在含有少量冠醚的稀氨水溶液中，使用锌粉促进醛基化合物进行水相呐偶合反应，其中加入少量的冠醚有助于提高反应的产率，呐醇产率由63%提高到84%。

5 The pinacol coupling reaction of aromatic aldehydes and ketones was performed in 8-95% yield with magnesium in 0. 1M aqueous NH4CI.

2.4 以蒙脱土K10和锌的体系中，在超声波作用下，研究了醛、酮的还原偶联反应，于22～30℃反应2～3小时，产率23～91％。

A reduction-coupling-etherification reaction between aromatic aldehydes or ketones (1) and alcohols ( 2 ) to yield corresponding diether ( 3 ) of pinacol in the presence of tin and chlorotrimethylsilane.

在三甲基氯硅烷、四氢呋喃体系中，芳香醛、酮和醇在金属锡的作用下发生还原-偶联-醚化反应生成相应的频那醇二醚类化合物。

In Chapter Ⅱ, the pinacol-coupling reactions of carbonyl compounds promoted by dysprosium were described. The reaction of ketones and aldehydes promoted by Dy/n-BuBr were proceeded in anhydrous THF which gave pinacol in high yield.

第二章研究了金属镝促进下羰基化合物的还原偶联反应，醛、酮在无水THF中与Dy/n-BuBr反应，可高产率地得到频哪醇。

The aluminium powder has been used to reduce titanium tetrachloride to generate the low valent titanium reagent which can induce the reductive coupling of aldehydes and ketones to form the corresponding pinacol s.

以价廉易得的铝粉还原四氯化钛制得低价钛，将其用于醛酮还原偶联，合成了6种片呐醇，其中对称片呐醇4种，不对称片呐醇2种。

In the presence of SnCl2- C6H5Me3NBr and microwave irradiation, the mixture of tin-indium and propargyl bromide reacted quickly with aldehydes in aqueous media to produce the homopropargyl alcohols exclusively in high yields.

在SnCl2 和C6H5Me3NBr存在及微波照射下，锡-铟和炔丙基溴的混合物在水介质中与醛快速反应，生成高产率的单一的高炔丙醇。

Promoted by metal dysprosium, aldehydes and ketones could react smoothly with propargyl bromide to afford the corresponding homopropargylic alcohol s in good to excellent yields, and no allenic alcohols were found.

在金属镝的促进下，醛、酮可与炔丙基溴反应，高选择性高产率地得到相应的高炔丙醇，没有发现连二烯醇的存在。

Promoted by metal dysprosium, aldehydes and ketones could react smoothly with propargyl bromide to afford the corresponding homopropargylic alcohols in good to excellent yields, and no allenic alcohol s were found.

当用苯基炔丙基溴代替炔丙基溴与醛、酮反应时，主要得到了相应的连二烯醇，而没有发现高快丙醇的存在，由此提出了六元环过渡态的反应机理

You can buy sweetened beverages, if that suits you.

你若喜欢的话，可以买些含有糖精的混合饮料。

As many of you are probably aware, Nick and Vanessa were recently faced with an embarrasing sex scandal after naked pictures of the two getting jiggy with it in a hot tub surfaced the net.

正如很多你可能知道，尼克和 Vanessa 最近面临一个尴尬的绯闻事件后，赤裸裸的图片两个越来越jiggy与它在浴缸中的一个热点浮现净。