查询词典 adsorption

When pH is 10, adsorption time is 30 min, dosage of bone char is 0.6 g/L, the original concentration of As in drinking water is 0.5 mg/L, As removal can reach 95.2%. The adsorption behavior is fitted both with Langmuir and Freundlich isotherm. The adsorption mechanism is supposed to be Ca—OH functional groups combined with anion. And there may occur the co-precipitation between calcium hydrogen arsenate and hydroxylapatite in the aqueous solution, and ions also exchange. The saturation adsorption capacity of As reaches 4.688 mg/g. Indexes of effluent are in good agreement with the WHO stringent drinking water standards (0.01 mg/L).

研究结果表明：在pH=10，吸附时间为30 min和骨炭加入量为0.6 g/L，饮用水砷初始质量浓度为0.5 mg/L时其砷去除率可达95.2%；骨炭吸附砷的行为同时符合Langmuir和Freundlich等温吸附模型；其吸附机理可能是Ca—OH官能团结合HASO4阴离子，并产生砷酸氢钙和羟基磷灰石的共沉淀，另外还存在离子交换作用；吸附柱的饱和吸附容量为4.688 mg/g；出水砷浓度符合世界卫生组织规定饮水砷标准(0.01 mg/L)。

The adsorption isotherm of neptunium on silica gel correspond to the form of Langmuir isotherm. According to Clausius-Claperon equation,from the slope in InKd vs 1/T plot,adsorption heat could be estimated. From the data of adsorption heat it is concluded that the adsorption of neptunium on silica gel in nitric acid solutions belongs to chemical adsorption and the adsorption process is an endothermic reaction.

三种价态的镎在硅胶上吸附的等温线符合兰格缪尔吸附等温线的形式，是单分子层吸附；根据克劳修斯-克拉柏龙方程，以1nKd对1／T作图，通过直线斜率计算出吸附热，从吸附热的数据可判断三种价态的镎在硅胶上的吸附属于化学吸附，是吸热的过程；对NpOV）、Np和Np（VD在硅胶上的吸附进行了比较，提出了三种价态的锋在硅胶上吸附的机理。

At the heavy metal concentration of 3-4ppm, our study on adsorption capacity, adsorption selectivity of montmorillonite, illite and kaolinite to Cu〓、 Pb〓、 Zn〓、 Cd〓、 Cr〓 shows that the adsorption capacity is mainly determined by the capacity of exchangeable cations and the adsorption capacity of the three clay minerals decreases in this sequence: montmorillonite ＞＞ illite＞kaolinite. It is found that clay minerals have obvious adsorption selectivity to various heavy metals. Montmorillonite exhibits a stronger affinity to Cr〓 and Cu〓 while kaolinite and illite sorb Cr〓 and Pb〓 more effectively. At the same heavy metal concentration, adsorption amount of clay minerals to heavy metals increase with increasing pH value of the solution.

在痕量浓度下，研究了蒙脱石、伊利石、高岭石三种粘土矿物对Cu〓、Pb〓、Zn〓、Cd〓、Cr〓五种重金属离子的吸附容量、吸附选择性及其介质条件对吸附量的影响，结果表明，粘土矿物的阳离子交换容量越大，对重金属离子的吸附容量也越大，其大小顺序为蒙脱石＞＞伊利石＞高岭石；同时，不同粘土矿物对重金属离子具有明显的吸附选择性，蒙脱石对Cr〓和Cu〓有较好的选择性，伊利石和高岭石则对Cr〓和Pb〓有较好的选择性；随着吸附溶液pH值的增大，其吸附量有增加的趋势。

In this paper, adsorption is firstly described as a function of CSGC, and the effects of component and their ratio of grouts, leachate environment such as temperature, pH and salinity on adsorption are studied with equilibrium experiment. The evidence shows that the adsorption mechanism of CSGC to contaminant conforming to Freundlich Adsorption Model. It provides the theory for establishing CSGC and utilizing adsorption mechanism.

本文首次将吸附性能引入防渗帷幕的功能作用，通过大量的吸附平衡试验分析了浆液配比、地下水环境和用量对帷幕吸附污染物性能的影响，研究了帷幕对污染物的吸附规律和去除特征，结果表明粘土固化注浆帷幕对污染物的吸附符合Freundlich吸附模式，为建立粘土固化注浆帷幕、充分发挥其吸附性能提供了理论基础。

The results indicated that the effect of pH on adsorption of theanine was not obvious within range of 6~11. The adsorption date fit well into the Freundlich and Langmuir isotherm equation within temperature range of 303~323 K and investigative concentration range. The isosteric enthalpy of adsorption, free energy and entropy of adsorption showed that adsorption of theanine was endothermic and spontaneous.

结果表明：在pH6~11时，pH值对717阴离子交换树脂对茶氨酸吸附量影响不大；在温度303～323K和茶氨酸质量浓度范围内，717阴离子交换树脂对茶氨酸吸附行为符合Freundlich和Langmuir吸附等温方程；热力学参数（吸附焓、自由能、吸附熵）表明此吸附过程是吸热和自发的。

Adsorption isotherms were obtained with static adsorption method. Isosteric adsorption enthalpy, adsorption free energy and adsorption entropy were calculated according to the relationship of thermodynamic function. Isosteric adsorption enthalpy was between 29 kJ-mol"1 ~ 34 kJ'mol"1, which reveals that the main molecularly recognition interaction is hydrogen bonding.

通过静态吸附试验，测定了球状分子印迹聚合物对水溶液中茶碱的吸附等温线，利用热力学函数关系计算了球状分子印迹聚合物的等量吸附焓，吸附自由能和吸附熵，等量吸附焓在29.17 kJ·mol~(-1)～34.54 kJ·mol~(-1)之间，推测其分子识别的作用力主要为氢键作用。

The results show that the optimal value of CoCl2 concentration is 0.2 mol/L and the maximum adsorbed amount is 19.674 mg/g onto this adsorbent. The adsorption capacity of phosphine onto CoCl2-modified ACF decreases with the increase of temperatures. The maximum absorbed amounts are 19.674 mg/g at 298 K, 13.537 mg/g at 313 K and 11.087 mg/g at 328 K, respectively. It is found that the Freundlich equation is more suitable for the description of phosphine adsorption process than the Langmuir equation. The isosteric heat of adsorption decreases with the increase of the surface loading on CoCl2-modified ACF, which means that CoCl2-modified ACF adsorbent has an energetically heterogeneous surface. Meanwhile, adsorptive phosphine removal performance may be a dominant of physical adsorption when the heat of adsorption is 16-24 kJ/mol, the CoCl2-modified ACF adsorbent will be one of the candidates for tail gas purification of airtight calcium-carbide furnace and recycle of phosphine.

研究结果表明：浸渍液浓度最佳值为0.2 mol/L，此改性ACF对PH3的饱和吸附量为19.674 mg/g；PH3在CoCl2改性ACF上的吸附量随温度升高而迅速降低，在298，313和328 K时PH3的饱和吸附量分别为19.674，13.537和11.087 mg/g；Freundlich吸附等温方程较好地模拟了PH3在改性ACF上的等温吸附；PH3气体在改性ACF上的等量吸附热随吸附量的增大而减小，表明改性ACF吸附剂表面能量的不均匀性；吸附热在16~24 kJ/mol范围内，过程为物理吸附，有利于密闭电石炉尾气的净化。

Their corrosion inhibition action of stainless steel in hydrofluoric acid is studied by adsorption theory and electrochemical polarization-curve method,the mechanism of corrosion inhibition action is analyzed.the result shows that the single molecule layer of these compounds is adsorbed on the surface of the stainless steel and followed Langmuir isothermal equation. the adsorption procedure of propiolic alcohol is endothermic reaction, the adsorption ability and corrosion inhibition efficiency increased when temperature rised. The adsorption procedure of other three compounds are all exothermic reaction , the adsorption ability and corrosion inhibition efficiency decreased when temperature increased.

实验结果表明：这几种物质在不锈钢表面产生单分子层吸附，并且满足Langmuir吸附规律，丙炔醇的吸附过程为吸热反应，随着温度的升高，吸附能力增强，缓蚀率升高；其它三种化合物的吸附过程均为放热反应，温度升高，吸附能力下降，缓蚀率降低。

Linear CO desorbs earlier and quicker than twin and bridged CO with the progressive heating from 25 to 300°C at 0.1MPa, and the three types of adsorption disappear at 265℃.At 205℃ the adsorption amount of linear CO and bridged CO increases with the pressure from 0.1 to 3.0MPa, but the adsorption amount of bridged CO is more than that of linear CO. At 0.1MPa and 25℃, CO2can decompose into CO and then CO adsorbs quickly, namely, CO2→CO+O, but the wave numbers of the adsorptive CO from decomposed CO2 are different from the pure CO, which demonstrates the effect of on CO adsorption. With the pressure of CO2 from 0.1 to 3.0MPa at 25℃, the total adsorption amount increases and the band at 2052cm^(-1) shifts towards higher frequency.

压力保持0.1MPa，温度由25℃升至300℃时，线式比桥式先脱附，至265℃时，3种吸附基本脱附完全；当温度维持205℃不变而压力逐步由。0.1升至3.0MPa时，线式吸附增量较少，桥式吸附增量较多，CO2在0.1MPa，25℃时就能发生快速的解离吸附，即CO2→CO+O，其吸附行为表现为CO的线式吸附，但吸附峰与纯CO吸附时不同；当温度稳定在25℃而压力逐步升至2.5MPa时，不仅CO2吸附量增大，而且其2052cm^(-1)吸附峰有向高波数移动的趋势。

The results indicated that a dependable kinetic model could be obtained by modifying the Temkin equation by considering the H2 and NH3 adsorption factors. Activation energy for the ammonia synthesis reaction was obtained as 90.2 kJmol^(-1) after linear fitting the kinetic and thermodynamic parameters k, K(subscript H2) and K(subscript NH3) with the Arrhenius and Van't Hoff equation, which was much lower than that over iron-based catalyst, which indicated that the activation energy barrier of N2 dissociative adsorption on Ru was far lower than that on either the conventional magnetite-based catalyst or wustite-based catalyst; the hydrogen adsorption heat was 76.2 kJ mol^(-1), indicating that the adsorption of hydrogen on the Ba-Ru-K/AC catalyst was so strong that it inhibitied the dissociative adsorption of nitrogen.

结果表明，在Temkin方程中加入H2和NH3的吸附项能够获得可靠的动力学模型，用Arrhenius和Van't Hoff方程对动力学和热力学参数k、K(下标 H2)和K(下标 NH3)进行线性拟合，得到氨合成反应的活化能为90.2 kJmol^(-1)，远低于铁基催化剂，说明Ru上N2的解离吸附活化能垒远低于传统磁铁矿基催化剂和维氏体基催化剂。H2的吸附热为76.2 kJmol^(-1)，证明Ba-Ru-K/AC催化剂上H2的吸附较强烈，对N2的吸附有强烈的抑制作用。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。