查询词典 adsorption

Monte Carlo simulation technique in the grand canonical ensemble with TraPPE force field by adjusting the partial force field parameter to fitting the isotherm adsorption of pure component was employed to simulate the adsorption of methane ,ethane and the sep- aration of their mixtures in siliclite-1 respectively.

采用TraPPE力场、巨正则系综蒙特卡罗的方法，通过调节部分力场参数，拟合纯组分等温吸附的实验数据，研究了甲烷、乙烷纯组分在silicalite-1中的吸附平衡性及其共混物的分离性。

Monte Carlo simulation technique in the grand canonical ensemble with TraPPE force field by adjusting the partial force field parameter to fitting the isotherm adsorption of pure component was employed to simulate the adsorption of m ethane , ethane and the sep- aration of their mixtures in siliclite-1 respectively.

采用TraPPE力场、巨正则系综蒙特卡罗的方法，通过调节部分力场参数，拟合纯组分等温吸附的实验数据，研究了甲烷、乙烷纯组分在silicalite-1中的吸附平衡性及其共混物的分离性。

The results showed that loading Ag^＋, Ni^2＋, Cu^2＋ or Zn^2＋ ion on the activated carbon obviously improved its adsorption of benzothiophene, while loading Fe^3＋ or Co^3＋ ion on the activated carbon caused a decrease in its adsorption of benzothiophene in comparison with the original unloaded activated carbon, which was due to the variation of the nature of soft and hard acid on the surface of the activated carbon.

采用密度泛函数理论法计算结果表明，苯并噻吩的电负性χ为2.638，属软碱类物质；由于Ag^＋为软酸，活性炭负载Ag^＋离子，增加了其局部表面的软酸，从而增强了对苯并噻吩硫化物的吸附；由于Ni^2＋、Cu^2＋和Zn^2＋离子属交界酸，负载Ni^2＋、Cu^2＋、Zn^2＋离子增加了活性炭表面的交界酸，也在一定程度上提高了其表面对苯并噻吩硫化物的吸附；当活性炭表面负载了硬酸性Fe^3＋或Co^3＋离子，其局部表面硬酸增大从而降低了其对苯并噻吩的吸附。

The structural and photocatalytic properties of TiO〓 as well as surface acidity were greatly improved by sulfation. SO〓〓/TiO〓 solid superacid with Hammett constant Ho less than -12.14 was prepared by treating the TiO〓 with 1.0mol. L〓 sulfuric acid solution and then calcining at 450℃ for 3h. When compared to unmodified TiO〓, the SO〓〓/TiO〓 superacid catalyst exhibited higher anatase content, smaller crystal size, higher specific surface area, centralized pore size distribution, and the blue-shifted band edge of uv-vis adsorption spectra. Furthermore, the SO〓〓/TiO〓 superacid also showed excellent reaction activity and stability for CH〓Br photocatalytic decomposition even under the moist reaction conditions. The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.

研究结果表明：SO〓〓与TiO〓表面的结合为螯合式双配位结构；TiO〓光催化剂表面经H〓SO〓浸渍处理后，提高了表面酸性，改善了催化剂结构和光催化性能，当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时，可制得SO〓〓/TiO〓超强酸催化剂(H〓＜-12.14)，其结构和光催化活性得到明显改善，与TiO〓相比，SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移，具有优异的光催化氧化活性、稳定性及抗湿性能，光催化降解溴代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级，是一种有实际应用前景的高效光催化剂；由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型，认为在SO〓〓/TiO〓超强酸催化剂表面，由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心，其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移，具有可逆吸附水的性能，是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。

The paper deals with the experimental and theoretic study on the influence of the effect of maldistribution on adsorption process in an industrial scale fixed bed,the result shows that as the result of the effect of maldistribution the adsorption capacitate of the fixed bed is decreased.

以甲苯气体为例，研究低浓度有机污染物在活性炭固定床吸附器内受边流效应影响的吸附过程。

The isolation ability of AB-8 macroporous adsorption resin for total flavones of Ficus carica was studied by examining the characteristics of adsorption and desorption.

研究了AB-8大孔树脂对无花果总黄酮的吸附和解吸的特性，并考察了相关的工艺条件。

The adsorption characteristics of arsenic in water by cerous hydroxide were studied.The results showed that cerous hydroxide had well adsorption effect for trivalent arsenic and pentavalent arsenic.

研究了氢氧化铈对水中砷的吸附特性，结果表明：氢氧化铈对As和As均有良好的吸附效果，其吸附等温线能很好地用Langmuir方程描述。

ABSTRACT Inhibition mechanism and the relations between inhibition efficiency and molecular structure of inhibition of carbon steel in chlorhydric acid by benzene nitriles whose inhibition is caused by chemical adsorption and quaternary ammonium salts whose inhibition is caused by physical adsorption are mainly studied from microscope through quantum chemistry calculation, and the relations between inhibition efficiency and molecular structure of inhibition of carbon steel in chlorhydric acid by benzene nitriles are studied by making use of model-constructing thought of grey theory in this paper.

本文主要通过量子化学计算，从微观角度研究了化学吸附型缓蚀剂苯腈类化合物和物理吸附型缓蚀剂季铵盐在盐酸溶液中对碳钢缓蚀的缓蚀机理和缓蚀性能与分子结构的关系；并运用灰色理论建模思想，研究了苯腈类化合物在盐酸溶液中对碳钢缓蚀的缓蚀性能与分子结构的关系。其中，通过量子化学计算，从微观角度研究物理吸附型缓蚀剂在盐酸溶液中对碳钢缓蚀的缓蚀机理和缓蚀性能与分子结构的关系，是在尝试着进行；而运用灰色理论建模思想，研究缓蚀剂缓蚀性能与分子结构的关系，是一项具有尝试性和开拓性的工作。

The IR analyses proved that the polymerization effects really occurred. The BET adsorption test indicated that the adsorption amount of MIPMs to LMD was as three times as that of non-imprinted microspheres. The controlled release test indicated that the release ratio of LMD on NIPMs was linearly increased with increasing time, which suggests that the release process is completely controlled by diffusion. Meanwhile, the release ratio of LMD on MIPMs was curvedly increased with increasing time, which indicates that the release process is controlled by both diffusion and the imprinting effect.

药物扩散实验表明， LMD在非印迹微球上的释药率几乎与时间呈直线关系，说明其释药过程完全受扩散控制；而LMD在MIPMs上的释药率则呈曲线上升趋势，说明其释药过程除了受扩散控制外，还受到药物模板分子与MIPMs之间的印迹效应的协同作用的控制，从而达到了缓释药物分子的目的。

Cytophaga sp was selected for heparinase production because it was more productive. Three heparinases, named HⅠ, HⅡ and H Ⅲ were purified from the crude cell extract by means of batch DEAE-Cellulose negative adsorption, Hydroxylaptide adsorption and releasing, SP-Sepharose cation exchange chromatography, Source 30S cation exchange chromatography, Poros 20HS cation exchange perfusion chromatography and Sephacryl S200HR gel permeation chromatography.

利用超声破碎、DEAE-纤维素反吸附去杂、羟基磷灰石批处理吸附层析、SP-Sepharose离子交换层析、Source 30S离子交换层析、Porous20HS离子交换灌注层析及Sephacryl S200HR凝胶排阻层析，从噬纤维菌中纯化出三种新的肝素酶。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。