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The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.
研究结果表明:SO〓〓与TiO〓表面的结合为螯合式双配位结构;TiO〓光催化剂表面经H〓SO〓浸渍处理后,提高了表面酸性,改善了催化剂结构和光催化性能,当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时,可制得SO〓〓/TiO〓超强酸催化剂(H〓<-12.14),其结构和光催化活性得到明显改善,与TiO〓相比,SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移,具有优异的光催化氧化活性、稳定性及抗湿性能,光催化降解溴代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级,是一种有实际应用前景的高效光催化剂;由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型,认为在SO〓〓/TiO〓超强酸催化剂表面,由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心,其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移,具有可逆吸附水的性能,是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。
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The technical characteristics of the invention is that: the rotor end face tooth profile contains four, five or six sections of tooth curves with the circular nature; when it has five sections, addendum circular arcs and dedendum circles are added to the addendum or the dedendum of the rotor; when it has six sections, both the addendum circular arcs and the dedendum circles are added to the addendum and the dedendum of the rotor at the same time, to form four different combination schemes; there are common tangents at the connection points of the two adjacent teeth forming curves, which has a smooth tooth-profile without cusp, a high-wearing feature, a long life of the rotor, a small leakage triangle, and a good sealing property.
本发明的技术特征是:转子端面齿型是包含四段、五段或六段圆弧性质的齿曲线;当为五段时,在转子的齿顶或齿根加上齿顶圆弧或齿根圆弧,当为六段时,在转子的齿顶和齿根同时加上齿顶圆弧和齿根圆弧,形成四种不同的齿型组合方案;相邻的两组成齿曲线的连接点处具有公切线,齿型光滑,没有尖点,耐磨性好,转子的使用寿命长,泄漏三角形小,密封性好。
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The results show that:(1) When N-methylethylenediamine and N, N'-methylethylenediamine equatorially coordinated to Cd〓, arenedisulfonates such as 1, 5-naphthalenedisulfonate, 2, 6-naphthalenedisulfonate and 4, 4'-bipenyldisulfonate act as a bridging ligands coordinated to adjacent Cd〓 centers, leading to a one dimensional chain structure.
研究结果表明:(1)N-甲基乙二胺和N,N'-二甲基乙二胺与Cd〓在赤道平面配位后,芳烃二磺酸根离子作为桥联配体与相邻的Cd〓在轴向配位形成了一维链状结构。
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Objective:To provide practical anatomy data about the lumbar isthmus and to quantitatively evaluate structural features of the lumbar isthmus and its relationship to adjacent anatomic structure,and to understand the vulnerability of the pars interarticular of the fifth lumbar vertebra.
目的 :提供腰椎峡部的应用解剖学资料,定量评价腰椎峡部的结构特点及其与毗邻结构的解剖关系,探讨腰 5椎弓峡部易患病性的解剖基础。
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Then on the basis of study results about regional geology, ophiolite,structure,and seismic depth-sounding in the Qinghai-Tibet plateau and its adjacent areas, this paper promotes a new model to interpret tectonics.This new model thinks that in this large area there was not simple B-type subduction which is accompanied with ocean-floor spreading at mid-ocean ridges to form ocean basins appearing as new oceans and new ocean plates,but intercontinental seas due to ocean-floor spreading,obduction of ophiolite tectonic slice as oceanic crust slabs and complex A-type subduction of continental lithosphere slabs.
而后又以青藏高原及邻区为例,根据区域地质、蛇绿岩和地质构造研究的成果,特别是地震测深研究的成果,详细地论证了本区不存在有大洋中脊扩张成为大洋盆地的新大洋和大洋板块简单的B型俯冲模式,但存在有海底扩张的陆间海和海洋地壳板片的仰冲以及大陆岩石圈板片复杂的A型俯冲新模式。
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The first step in the degradation is most probably the classical ester scission reaction to give a carboxylic acid and olefinic end groups. Further ester scission on the adjacent ester groups of carboxylic acid and olefinic molecular chains can then lead to the formation of lower weight pyrolytic products, such as: CH〓=CHOCOPhCOOCH=CH〓、CH〓=CHOCOPhCOOH and HOOCPhCOOH, and they can pyrolyze continually to produce substrate pyrolytic compounds, such as: HOOCPhCOCH〓、PhCOOH、PhH、PhCOCH〓 and CO、CO〓. At the same time, a corsslinking cyclization reaction occurred of the formation of the gas products during the degradation of PET.
断裂大分子链端邻近羰基和乙烯基的酯键持续断裂,不断地形成小分子裂解产物,如:CH〓=CHOCOPhCOOCH=CH〓、CH〓=CHOCOPhCOOH以及HOOCPhCOOH,这些产物还会进一步裂解成分子量更低的小分子裂解产物,如:HOOCPhCOCH〓、PhCOOH、PhH、PhCOCH〓以及CO、CO〓等,与此同时,一部分乙烯基酯端基的大分子链碎片会发生支化而相互连接,再经&链脱离&和环化反应形成难燃的交联产物。
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At the end of Oligocene to Miocene, due to lateral extrusion of material in the collisional belt, west Yunnan and adjacent region between the Red River-Ailao Shan and the Saging faults escaped to SSE.
渐新世末—中新世,高原地区的物质侧向挤出,红河—哀牢山断裂和实皆断裂之间的滇西及邻区向南南东脱逸。
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One of many factors contributory to development of periodontitis is an unerupted or abnormally erupted third molar and it may cause deep pocket formation and bony resorption at the distal side of adjacent second molar. It is also prone to result in periodontitis due to interdental food impaction and uneasy cleaning between the third molar and second molar.
在形成牙周炎的众多贡献因子中,其中因第三大臼齿萌发方向异常或萌发不全,可能造成第二大臼齿远心侧形成牙周囊袋和周围牙周骨头吸收;或第二及第三大臼齿间因缝隙口腔清洁不良而好犯牙周病。
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It is usually better to allow the gas to burn itself out in a confined area and keep adjacent objects cool with water, rather than to risk a potential explosion.
通常最好让气体在狭窄空间内自己烧完,同时用水一直冷却着临近的物体,而不是冒可能爆炸的危险。
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The gene launches a biochemical process in which a molecule called plasmin perforates the membranes of tissues, causing the membranes to break down and allowing the cancer cells to escape into the bloodstream and to adjacent tissues.
这种基因启动了一种生化过程,在这个过程中,一种叫做血浆酶的分子能够在组织膜上打孔,并导致膜降解,从而使癌细胞能够流窜到血管和临近组织。
- 推荐网络例句
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Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).
呼气,收缩臀部肌肉;拱起身体,尽量抬起头来,右腿伸直朝向天花板(膝微屈,以避免肌肉紧张)。
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The cost of moving grain food products was unchanged from May, but year over year are up 8%.
粮食产品的运输费用与5月份相比没有变化,但却比去年同期高8%。
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However, to get a true quote, you will need to provide detailed personal and financial information.
然而,要让一个真正的引用,你需要提供详细的个人和财务信息。