查询词典 activation energy

Factors affecting the activity of urease in PPy film were studied and activation energy of the ferment was determined.

研究了聚合条件对酶活性的影响，并测定了掺杂于聚吡咯中的脲酶的活化能等动力学参数。

For vortex-liquid phase,the E-J relation could be described according to the Kim-Anderson model:U=U0(1-J/JC).While for vortex-glass phase,the electric field decays verydramatically with decreasing current density,so it is difficult to be observed with theinstrument has limited precision.In the intermediate current region,the E-Jrelations of the both phases could be fitted in terms of a phenomenological model:U=(U0/μ)[μ-1],it was concluded that the sign of μ-value changes fromnegative to positive when the temperature decreases lower than the glass-transitiontemperature Tg,meanwhile,the activation energy U enhances dramatically.Whilein the large current region,Zeldov's logarithmic model was suitable for fitthing theE-J curves of the both phase.Moreover,there was no abrupt change of U or thecharacteristic current density IC.However,the effective radius of vortex line variesremarkably around Tg.

对于涡旋液体相，小电流区的E-J关系可以用计及反跳的Kim-Anderson模型U＝U0(1-J/JC)来描述，而对于涡旋玻璃相，小电流区的电场随电流密度减小而迅速衰减，以致很快脱离了实验测量精度的范围；在中等电流区，两相的E-J关系可以用共同的唯象过渡模型U＝(U0/μ)[μ-1]来拟合，得到在玻璃转变温度Tg两侧μ值由正到负的变化，同时激活能U在Tg以下迅速升高；在较高电流区，两相的E-J关系可以很好的用Zeldov对数模型来描述，拟合结果表明U在Tg两侧的趋势没有明显变化，但是涡旋线的有效半径发生了显著变化。

Under the optimum conditions, the linear range of the method was 0-80 μg/L. The detection limit was 4.58×10^(-7) g /L.The catalytic reaction was the zeroth order one. The apparent activation energy and the reaction rate constant was found to be 96.04 kJ/mol and 3.61×10^(-3)/s, respectively. The sensitivity was increased by 3 times in the presence of surfactant.

在最佳实验条件下，方法线性范围为0~80μg/L，检出限为4.58×10^(-7)g/L；催化反应为动力学零级反应，表观活化能为96.04kJ/mol，反应速率常数为3.61×10^(-3)/s；反应在表面活性剂存在下，灵敏度提高3倍。

When the reaction temperatures were 303.15, 308.15, 313.15, 318.15, 323.15 and 328.15 K, respectively, the apparent reaction rate constants of abietic acid were 0.0036, 0.0041, 0.0062, 0.0087, 0.011 and 0.0157 min^(-1), respectively. Its reaction activation energy was 50.29 kJ/mol.

枞酸的氧化反应温度为30，35，40，45，50和55℃时，表观速率常数分别为0.0036，0.0041，0.0062，0.0087，0.011和0.0157min^(-1)，表观反应活化能E为50.29kJ/mol。

The non-isothermal kinetic data were analyzed with the Achar equation, Coats-Redfern equation, Kissinger equation, Flynn-Wall-Ozawa equation and Starink equation.The mechanism function and kinetic parameters of the thermal decomposition in the third step were obtained.The chemical reaction mechanism (F3) controlled the third thermal decomposition process.The apparent activation energy and the pre-exponential factor were 351 kJ·mol-1 and 2.57×10 30s-1 respectively.

采用Achar方程、Coats-Redfern方程、Kissinger方程、Flynn-Wall-Ozawa方程和Starink方程对非等温动力学数据进行了分析，得到了第3步热分解反应的机理函数、动力学参数和热分解反应动力学方程，其热分解反应过程受F3机理控制，表观活化能为351 kJ·mol-1，指前因子为2.57×

The activation energy and rate constant of the allylation reaction was calculated in virtue of kinetic study.

进行了动力学研究，获得了反应活化能和各反应温度下的反应速率常数，同时研究结果表明烯丙基化反应级数为2，反应机理为S(来源：A16BC论文网www.abclunwen.com)N2 亲核取代反应。

The presence of solvent disfavors the reaction, whereas the participation of water in the aminolysis reaction plays a positive role and reduces the activation energy greatly.

没有水分子参与的情况下，路径a的反应能垒最低，而在有水分子参与反应时，按协同机理反应生成P2的反应路径略占优势。

Under certain experimental conditions,the Terbiumbasic Calbonate can be dissolved in aqueous solution of nicotinic acid to yield an Orange Tb Complex, which has a broad characteristic absorption band between, 370—410 nm The autoreduction of the Tb—Complex was studied by means of spectrophotometric method, It was determined by experiments that the reaction order is equal to two and the apparent activation energy of the auto—reduction is equal to 68.4±0,8KJ/mol.

在一定条件下，Tb的碱式碳酸盐可以溶解在烟酸的水溶液中形成橙黄色的络合物，该络合物在390nm波长附近有一宽带特征吸收峰。消光值在0。～1.0范围內与Tb的浓度具有直线关系。分光光度法对Tb自还原反应研究确定：于15℃及烟酸浓度为0.35M时，当pH值小于6.0条件下，随pH值的增加，其自还原速度常数减小，该自还原反应级数为二，反应活化能为68.4±0.8KJ/mo1。

The optimal measuring conditions were investigated. The results indicated that the catalytic reaction to Pt and bromocresol purple was the first-order reaction. The apparent activation energy was 217.4kJ/mol and the maximum absorption wavelength of fading reaction was at 434 nm. The linear range of Pt was 0.16-4.0μg/L and the detection limit was 2.5×10^(-11)g/mL. Most of common ions had no interference with the determination, while ten multiples of Ru, Rh and Os had interference with the determination of Pt. Therefore.

选择了最佳测定条件，实验结果表明，催化反应对铂和溴甲酚紫为一级反应，反应的表观活化能为217.4kJ/mol，褪色反应的最大吸收波长为434nm，方法测定R哪的线性范围为0.16~4.0μg／L，检出限为2.5×10^(-11)g/mL，大多数常见离子不干扰测定，10倍以上的Ru，Rh和Os对测定有干扰，可在测定前分离除去。

The results demonstrated that the fractional conversion and reaction rate were rapidly increased in the initial curing reaction. The higher the curing temperature, the higher the fractional conversion and reaction rate was. With increasing of the curing temperature and time, the fractional conversion and reaction rate decreased and became constantly. The initial curing reaction was a first order reaction. The apparent activation energy and frequency factor of curing reaction used G- capryl ester was bigger than that of used G-oligomer.

结果表明：固化体系在研究的固化温度下，转化率和反应速率在固化反应初期增加快速，温度越高增加越快，随着固化时间的延长，这种变化逐渐变慢，并最终趋于恒定；初期固化反应为一级反应，反应初期的表观活化能和指前因子大小顺序为G-预聚体＞G-辛酯。

The absorption and distribution of chromium were studied in ryeusing nutrient culture technique and pot experiment.

采用不同浓度K2CrO4(0，0.4，0.8和1.2 mmol/L)的Hoagland营养液处理黑麦幼苗，测定铬在黑麦体内的亚细胞分布、铬化学形态及不同部位的积累。

By analyzing theory foundation of mathematical morphology in the digital image processing, researching morphology arithmetic of the binary Image, discussing two basic forms for the least structure element: dilation and erosion.

通过分析数学形态学在图像中的理论基础，研究二值图像的形态分析算法，探讨最小结构元素的两种基本形态：膨胀和腐蚀；分析了数学形态学复杂算法的基本原理，把数学形态学的部分并行处理理念引入到家实际应用中。