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In order to research the relations of carbon sources to structure of PHAs, six kinds of PHAs sample were synthesized by activated sludge with six different carbon sources respectively in the aerobic-anaerobic-anoxic process. Their structures were determined by 〓HNMR、〓CNMR and GC-MS. When the carbon source was acetate, the unit composition of PHAs was 93. 91mol% 3-hydroxybutanoic acid and 6. 09mol% 3-hydroxypentanoic acid ; When the carbon source was propionate, the unit composition of PHAs was 28. 66mol% HB, 63. 13mol%HV, 2. 55mol% 2-methy-3-hydroxy-butanoic acid (2MHB) and 5. 66mol% 2-methyl-3-hydroxypentanoic acid (2MHV); When the carbon source was 80% butyrate and 20% 1, 4-butanediol, the unit composition of PHAs was 65. 03mol% HB, 28. 06mol%HV, 1. 91mol%2MHB, 2. 69mol% 2MHV, 0.73mol% 4-hydroxy butanoic acid (4HB), 0.78mol% 4-methyl-3-hydroxy-pentanoic acid (4MHV), 0.80mol% 3-hydroxyhexanoic acid ; When the carbon source was 20% butyrate and 80% 1, 4-butanediol, the unit composition of PHAs was 61. 39mol% HB, 23. 01mol%HV, 4. 58mol%2MHB, 5. 97mol% 2MHV, 0.91mol% 4HB, 2. 37mol% 4MHV, 1. 77mol% HHx; When the carbon source was 60% pentanoate and 40%glucose, the unit composition of PHAs was 41. 24mol% HB, 58. 76mol%HV; When the carbon source was 60% benzoate and 40% glucose, the unit composition of PHAs was 65. 48mol% HB and 34. 52mol% HV.

为了研究不同碳源与产物PHAs结构的关系,采用好氧-厌氧-缺氧模式利用6种不同碳源培养活性污泥得到6种不同的PHAs样品,通过〓HNMR、〓CNMR和GC-MS谱图确定了这6种PHAs的单体成分和比例:以乙酸钠培养活性污泥得到的PHAs的单体组成是93.91mol%3-羟基丁酸和6.09mol%3-羟基戊酸;以丙酸钠培养活性污泥得到的PHAs的单体组成除28.66mol%HB、63.13mol%HV外,另外还有2.55mol%3-羟基2-甲基丁酸(2MHB)和5.66mol%3-羟基2-甲基戊酸(2MHV);以80%丁酸钠和20%1,4-丁二醇混合溶液培养活性污泥得到的PHAs含有七种单体组成:65.03mol%HB,28.06mol%HV,1.91mol%2MHB,2.69mol%2MHV,0.73mol%4-HB(4-羟基丁酸),0.78mol%4MHV(3-羟基-4-甲基戊酸),0.80%HHx(3-羟基己酸);以20%丁酸钠和80%1,4-丁二醇培养活性污泥所得到的PHAs含有与3#样品相同的七种单体,只是比例不同,分别是61.39mol%,23.01mol%,4.58mol%,5.97mol%,0.91mol%,2.37mol%,1.77mol%;以60%戊酸钠和40%葡萄糖培养活性污泥所得到的PHAs由HB和HV组成,比例是41.24 mol%∶58.76 mol%;以60%苯甲酸钠和40%葡萄糖培养活性污泥所得到的PHAs也由HB和HV组成,比例是65.48 mol%∶34.52 mol%。

Coconut oil is an excellent emollient, being a rich source of saturated fatty acids like oleic acid, linoleic acid, lauric acid, capric acid, caprylic acid, myristic acid and palmitic acid.

椰子油是一个很好的润肤,身为如油酸饱和脂肪酸的丰富来源,亚油酸,月桂酸,癸酸,辛酸,肉豆蔻酸,棕榈酸。

First, a lot of experiments about changing character on CaCO3 surface has been rearsched,example,fatty acid,pentaerythritol,rosin ester,cocoanut oil,rosin, pentaerythritol + rosin ester,glycerine + rosin ester ,cocoanut oil + oleic acid,titanate + fatty acid,cocoanut oil + fatty acid, and so on surface active agents. Among these surface active agents, cocoanut oil + oleic acid,and titanate+ fatty acid,and cocoanut oil + fatty acid are the best.

本文首先对纳米碳酸钙的活化改性进行了实验研究,在硬脂酸钠、季戊四醇、松香酯、椰子油、松香、季戊四醇+松香酯、甘油+松香酯、椰子油+油酸、钛酸酯+硬脂酸钠、椰子油+硬脂酸钠等表面改性剂中,以硬脂酸钠、椰子油、油酸+椰子油、椰子油+硬脂酸钠等活化剂的活化效果较为理想。

Using peptide hydrolysis combined with amino acid analysis, sugar alcohol acetylation combining with GC/MS, fattic acid methyl esterization combining with GC/MS and other technical means it was identify carbohydrate in the bioemulsifier mainly was D-mannose, and main amino acids were glutamic acid, aspartic acid, alanine, and main fattic acids that composed lipid was hexadecanoic acid, octadecenoic acid, and octadecanoic acid.

利用肽水解结合氨基酸分析、糖醇乙酰化结合GC-MS、脂肪酸甲脂化结合GC-MS等技术手段鉴定乳化剂中糖主要为D-甘露糖;主要氨基酸为谷氨酸、天冬氨酸、丙氨酸;构成脂的主要脂肪酸为十六烷酸、十八烯酸和十八烷酸。

Tea seed oil fatty acids for oleic acid, linoleic acid, palmitic acid, stearic acid, linoleic acid, myristic acid and so on, and linoleic acid, linolenic acid is the maintenance of human skin, hair growth indispensable, able to prevent arteriosclerosis.

茶籽油的脂肪酸成分为油酸、亚油酸、棕榈酸、硬脂酸、亚麻油酸、豆蔻酸等,而亚油酸、亚麻油酸是维持人体皮肤、毛发的生长所不可缺少的,能够预防动脉硬化。

M treatment materials, and also tartaric acid and no maleic acid detected in G. v treatment materials. Inoculation also increased the content of organic acid secretion (increased by 19.80~56.87 mg/kg) of trifoliate root, and the application of AlPO4 greatly increased organic acid content (increased by 20.06~21.84 mg/kg); uninoculated plant root secreted a bit of organic acid; Mycorrhizal poncirus trifoliata seedlings excreted malic acid (42.87%), citric acid (39.22%) and oxalic acid (12.06%).

接种AM真菌的根系分泌的有机酸种类与对照有所不同,未接种处理枳分泌的有机酸有草酸、苹果酸、乳酸、乙酸、顺丁烯二酸和柠檬酸等6种,而接种G.m的则检测到草酸、酒石酸、苹果酸、乳酸、乙酸、柠檬酸、丁二酸等7种,G.v处理的检测到酒石酸,接种处理均未检测到顺丁烯二酸;接种丛枝菌根真菌增加了枳根系分泌有机酸的量比未接种处理增加19.80~56.87 mg/kg,且施用AlPO4后有机酸含量显著增加(增加20.06~21.84 mg/kg;未接种植株根系仅分泌少量有机酸;接种植株根系分泌的有机酸以苹果酸(42.87%)、柠檬酸(39.22%)和草酸(12.06%)为主。

As to the high polarity, high boiling point resultant—trimesic acid, the analysis methods of infrared spetrum, gas chromatography-mass spectroscopy, vapour-phase chromatography, acid number titration and so on are seperately used to characterize its property. Infrared spetrum and gas chromatography-mass spectroscopy are used to have a qualitative analysis on the resultant and are compared with the stand diagram. Sulfuric acid-methanol esterification and rapid esterification are used to prepare the trimesic acid trimethyl-ester and have a FID quantitative analysis. So that we make sure the purity of trimesic acid in the resultant and also we have an acid alkali titration on the resultant to get its acid number, in order to verify the purity of trimesic acid in the resultant.

对于高极性、高沸点的固体产物均苯三甲酸,分别采用红外光谱、气质联用、气相色谱、酸值滴定等分析手段进行了表征:利用红外光谱、气质联用的方法进行产物的定性分析,并与在同一仪器、同一条件下做出的标准谱图进行比对;采用硫酸-甲醇酯化法和快速酯化法制备出均苯三甲酸三甲酯,对其进行气相色谱FID定量分析,进而确定固体产物中均苯三甲酸的纯度;用酸碱滴定法确定固体产物的酸值,以对固体产物中均苯三甲酸的纯度进行验证。

The mycelial growth of Rhizoctonia solani was promoted by vanillic acid and syringic acid at levels of 0.1~1 mM/L, and it was inhibited remarkably by p-counaric acid of over 1mM/L and modestly by ferulic acid. The radial extent of mycelia of Fusarium solani was increased significantly by ferulic acid of 0.1~1 mM/L and limitedly by p-coumaric acid. vanillic acid had paradoxcial effects on the growth, positively at low levels and negtively at high levels, on which Syringic acid had a slight effect.

试验结果显示:浓度为0.1~1mM/L的丁香酸对西洋参立枯丝核菌菌丝生长具有促进作用,香草酸也有一定的促进作用,但不呈浓度效应,浓度在1mM/L以上的香豆酸对其有显著的抑制作用,阿魏酸也有一定抑制作用;对于西洋参根腐菌,阿魏酸对其生长有明显促进作用,香豆酸也有一定促进作用,香草酸表现为低浓度促进,高浓度抑制作用,0.1~1mM/L丁香酸对其生长基本无影响。

The results showed that in the growth period of R. glutinosa, soil ferulic acid, vanillic acid, and vanillin contents had a persistent increase, while β-hydroxybenzoic acid content increased first but decreased then. The addition of ferulic acid (8 μg·ml-1), vanillic acid (08 μg·ml-1), vanillin (12 μg·ml-1), and β-hydroxybenzoic acid (30 μg·ml-1) in water culture had stronger inhibitory effects on R. glutinosa root length, root mass, fresh plant mass, and plant height. Treating with test phenolic acids except β-hydroxybenzoic acid increased leaf chlorophyll content significantly, compared with the control. After treated with test phenolic acids, plant SOD and POD activities decreased after an initial increase, and plant malondialdehyde content increased. In the treatment of ferulic acid, root SOD and POD activities were the lowest, and roots were rotted and dead.

结果表明:阿魏酸、香草酸和香草醛含量在地黄生长期表现为持续增加,而对羟基苯甲酸含量先升高后降低;外加阿魏酸(8 μg·ml-1)、香草酸(0.8 μg·ml-1)、香草醛(1.2 μg·ml-1)和对羟基苯甲酸(3.0 μg·ml-1)对水培地黄根长、根质量、全株鲜质量和株高有较强的抑制作用;酚酸处理使地黄叶片叶绿素含量降低,除对羟基苯甲酸外差异性极显著;经过酚酸处理的地黄幼苗SOD和POD活性为先升高后下降,丙二醛含量升高,其中阿魏酸的处理使根中酶活性降至最低,根部腐烂死亡。

Examples of metal chelating groups include hydroxides especially aryl or heteroaryl hydroxides such as phenolic hydroxides; amines which may be aliphatic aryl or heteroaryl; mercaptans which may be aliphatic aryl or heteroaryl; carboxylic acids which may be aliphatic aryl or heteroaryl; oximes and ketoximines; acetarylamides; hydroxy silanes and silicones; N-containing heterocycles such as imidazoles benzimidazoles triazoles benzotriazoles thiazoles isothiazoles acid anhydrides and more preferably acid groups (especially carboxylic acid groups phosphoric acid groups polyphosphoric acid groups phosphonic acid groups sulphuric acid groups and sulphonic acid groups).

金属螯合组的例子包括氢氧化物,特别是芳基或如酚醛氢氧化物杂氢氧化物;胺可能是脂肪族,芳基或杂;硫醇可能是脂肪族,芳基或杂,这可能是脂肪族,芳基或羧酸杂;肟和ketoximines; acetarylamides;羟基硅烷和有机硅,含N,如咪唑,苯并咪唑类,三唑类,苯并三氮唑,噻唑类,isothiazoles,酸酐杂环,多最好酸组(特别是羧酸团体,磷酸,团体,多聚酸组,膦酸组,硫酸团体和磺酸组)。

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