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The mean conˉcentrationsof the total bile acid in the gallbladders were respectively77.53±11.93,51.81±8.12and53.27±7.04in group DM,CH and DMCH,but it was79.28±18.28in group N.Combined bile acids(both glycocholic acid and taurocholic acid)were apparently lessened and the ratio of cholic acid and chenodeoxycholic acid was rised in group DM,CH and DMCH,the concentrationsof cholesterol were respectively5.31±0.81,5.69±2.20and5.12±1.47,but0.86±0.20,in the group N;those of phospholipd were respectively0.35±0.16,0.52±0.18and1.38±0.34,but0.59±0.28,group N.

胆囊胆汁成分分析中,DM组、CH组和DMCH组总胆汁酸分别为77.53±11.93、51.81±8.12和53.27±7.04,N组为79.28±18.28;与N组比较结合胆汁酸减少,其中甘氨胆汁酸盐与牛磺胆汁酸盐均减少;鹅去氧胆酸减少,胆酸/鹅去氧胆酸比值升高;胆汁胆固醇分别为5.31±0.81、5.69.20和5.12±1.47,N组为0.86±0.20;磷脂分别为0.35±0.16、0.52±0.18和1.38±0.34。

Stones were seen in the gallbladder of12/12cases in either group DM and CH,and11/12in the group DMCH.The mean conˉcentrationsof the total bile acid in the gallbladders were respectively77.53±11.93,51.81±8.12and53.27±7.04in group DM,CH and DMCH,but it was79.28±18.28in group N.Combined bile acids(both glycocholic acid and taurocholic acid)were apparently lessened and the ratio of cholic acid and chenodeoxycholic acid was rised in group DM,CH and DMCH,the concentrationsof cholesterol were respectively5.31±0.81,5.69±2.20and5.12±1.47,but0.86±0.20,in the group N;those of phospholipd were respectively0.35±0.16,0.52±0.18and1.38±0.34,but0.59±0.28,group N.

胆囊胆汁成分分析中,DM组、CH组和DMCH组总胆汁酸分别为77.53±11.93、51.81±8.12和53.27±7.04,N组为79.28±18.28;与N组比较结合胆汁酸减少,其中甘氨胆汁酸盐与牛磺胆汁酸盐均减少;鹅去氧胆酸减少,胆酸/鹅去氧胆酸比值升高;胆汁胆固醇分别为5.31±0.81、5.69.20和5.12±1.47,N组为0.86±0.20;磷脂分别为0.35±0.16、0.52±0.18和1.38±0.34。

The diluent solution of glyoxylic acid and oxalic acid was used as the separation object.TOA (in n-octanol) was used as the solvent. The extraction characteristics of single acid and two-acid solution were studied,and the influence of pH and the concentration of complexing agent on the distribution coefficients were measured. The suitable mathematic models were proposed to describe the relationship between TOA and carboxylic acid based on assumed extraction reaction in organic phase.

摘 要:以草酸和乙醛酸的稀溶液为分离对象,采用三辛胺为萃取反应剂、正辛醇为稀释剂,研究了单溶质、双溶质有机酸的萃取分离特性,测定了溶液pH值、萃取反应剂的浓度等因素对双溶质有机酸萃取的影响,提出了萃取的化学反应发生在有机相中的假定,建立了TOA萃取草酸的数学模型。

The diluent solution of glyoxylic acid and oxalic acid was used as the separation object. TOA (in n-octanol) was used as the solvent. The extraction characteristics of single acid and two-acid solution were studied, and the influence of pH arid the concentration of complexing agent on the distribution coefficients were measured. The suitable mathematic models were proposed to describe the relationship between TOA and carboxylic acid based on assumed extraction reaction in organic phase.

以草酸和乙醛酸的稀溶液为分离对象,采用三辛胺为萃取反应剂、正辛醇为稀释剂,研究了单溶质、双溶质有机酸的萃取分离特性,测定了溶液pH值、萃取反应剂的浓度等因素对双溶质有机酸萃取的影响,提出了萃取的化学反应发生在有机相中的假定,建立了TOA萃取草酸的数学模型。

Organic: dihydroxybenzene, oxalic acid, hydroquinone, fumaric acid, gulonic acid, o-dihydroxybenzne; m-dihydroxybenzene; coke powder, tartaric acid, cyanuric acid, G salt, R salt.

有机物:苯二酚、草酸、对苯二酚、富马酸、古龙酸、邻苯二酚、间苯二酚、焦炭粉、酒石酸、氰尿酸、 G 盐、 R 盐。

The investigation of variation of fatty acids composition during fermentation indicated that the molar percent of unsaturated octadecyl acids increased and unsaturated eicosyl acids decreased when n-propyl alcohol was presented, the molar percent of saturated pentacosyl acid, hexadecyl acid, heptadecyl acid, eicosyl acid and docosyl acid were not sensitive to the addition of n-propyl alcohol.

饱和的十五、十六、二十二、十七和二十酸组分含量不受正丙醇添加的影响。

The fatty acid in soybean oil had been determined with a main composition of hexadecanoic acid C(subscript 16:0, 8.6%, octadecenoic acid C(subscript 18.2, 52.1%, octadecenoic acid C(subscript 18:1, 33.1% and octadecanoic acid C

而加氢产物中检测到正构烷烃同系物,以正构十七烷烃和正构十八烷烃的含量最高,分别约为16.5%和18.5%,同时检测到少量烷基苯同系物等芳烃化合物。

ConclusionThe main components of essential oils are 2,4-bis(1,1-dimethylethyl) phenol (4.4%), tetradecanoic acid (6.96%), n-hexadecanoic acid (7.69%), 9,12-cctadecadienoic acid (6.37%), hexadecanoic acid-2-hydroxy-1- ethyl ester (4.79%) and octadecanoic acid-2-hydroxy-1- ethyl ester (4.77%), respectively.

结论阿给炭挥发油的主要成分为2,4-二树丁基苯酚(4.4%)、十四酸(6.96%)、n-十六酸(7.69%)、-9,12-十八碳二烯酸(6.37%)、软脂酸-2-羟基-1-羟甲基乙酯(4.79%)、硬脂酸-2-羟基-1-羟甲基乙酯(4.77%)。

Hexadecanoic acid,stearic acid,oleic acid,linoleic acid and linolenic acid from soybean salad oil have been quantitatively analyzed by using gas chromatograph combined with,Heated-filament pyrolyzer and Curie-Point pyrolyzer.

方法采用气相色谱仪,FID检测器,FFAP毛细柱,热丝型裂解器及居里点裂解器,对大豆色拉油的五种主要组分:软脂酸,硬脂酸,油酸,亚油酸,亚麻酸进行了定量分析。

Tetrachloroterephthalic acid was prepared by chlorinating terephthalic acid, oleumsolvent and iodine catalyst. Tetrachloroterephthalic acid was acylated by sulphurous oxychloride in the presence of DMF to form tetrachloroterephthaloyl chloride. The acyl chloride product was fluorinated by potassium fluoride and esterified by methanol to synthesize dimethyl tetrafluoroterephthalate. The ester was reduced with potassium borohydride and lithium chloride to give tetrafluoroterephthalyl alcohol. The above product was bromated in the hydrobromic acid to obtain 4-bromomethyl-2,3,5,6-tetrafluoro-benzene methanol. 4-Methyl-2,3,5,-6-tetrafluorobenzene ethanol was obtained by reducing the bromide with magnesium. In the exist of DCC and DMAP, tefluthrin was got by the condensation reaction between 4-methyl-2,3,5,6-tetrafluoro-benzene methanol and-(1RS,3RS)- 3-(2- chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethyl cycolpropanecar-boxylate acid.

对苯二甲酸与氯气在碘存在下以发烟硫酸为溶剂进行氯化制备四氯对苯二甲酸;再以DMF为催化剂与二氯亚砜反应生成四氯对苯二甲酰氯;以氟化钾为氟化剂,环丁砜为溶剂置换氟化,再与甲醇酯化得到四氟对苯二甲酸甲酯;以KBH4-LiCl为还原剂二甲醚为溶剂反应制得四氟对苯二甲基苄醇;以氯苯为溶剂在溴化氢溶液中溴化得到溴化产物;在乙醇溶液中经镁粉还原得到4-甲基-2,3,5,6-四氟苄醇;甲基苄醇与功夫酸在催化剂二环己基碳二亚胺和4-二甲氨基吡啶作用下缩合得到七氟菊酯,总收率达43.6%。

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