查询词典 acid reaction

The effects of water,free fatty acid,and acetic acid in the reaction system on the reaction were systematically studied.

系统研究了反应体系中的水、游离脂肪酸和乙酸对反应的影响。

The effect of different calcium chloride concentration, reaction time and neutralized acid on yield of tagatose was investigated by single factor tests. Results showed that the condition, such as calcium chloride (0.01～0.03 mol/L), reaction time(20～40 min), acetum, carbon dioxide, phosphate acid to synthesize tagatose was suitable.

通过单因素实验，确定了以D-半乳糖为原料进行化学法合成D-塔格糖的工艺条件为：CaCl2的添加量在0.01～0.03 mol/L，反应时间在20～40 min，并用醋酸、CO2、磷酸中和时D-塔格糖产率较高。

The effect of different reaction conditions,such as catalyst concentration,molar ratio of reactants,reaction temperature,reaction time,on the coupling reaction of trioxane and methyl formate synthesizing methyl glycolate and methyl methoxy acetate using sulfuric acid as catalyst has been studied.Through the analysis for the yield of products and system pressure,and comparison with other different acidity catalysts,we considered that the activation of formaldehyde was the control step of reaction rate to the...

以硫酸为催化剂，研究了三聚甲醛与甲酸甲酯偶联合成乙醇酸甲酯和甲氧基乙酸甲酯的反应中，催化剂浓度、原料配比、反应温度、反应时间等条件对反应过程的影响，通过对产物收率和系统压力变化的分析，并结合与其它不同酸强度催化剂的对比，得到甲醛的活化是偶联反应的速率控制步骤，催化剂的酸强度决定其对甲醛的活化能力，是影响偶联反应的主要因素。

Through lots of tests, the new technology of preparing the polymeric ferric aluminum silicate sulfate by using the waste-acid of Ti02-industriy and the coal fly ash has been designed. The highest Al-acid stripping rate can be achieved by the waste sulfate acid under boiling degree for 1. 5h when the mass ratio between NaCl and Coal Fly ash is 0. 05:1, as well as that between Coal Fly ash and Waste Acid ratio is 1:10. By means of the oxidation-polymerized reaction under 40-50*C and normal pressure, using NaNCkas catalyst and air as oxidation, the polymeric ferric aluminum sulfate can be obtained. The poly-silicic acid is polymerized with soluble glass in the optimum conditions of pH=5-6 and the concentration of Si02 is about 3%. The inorganic high molecule coagulant of PFASS is synthesized with the poly-silicic acid into the solution of polymeric ferric aluminum sulfate.

本论文通过大量的试验，研究开发出了用粉煤灰及钛白废酸制取聚合硫酸硅酸铁铝的新工艺，其最佳工艺条件为：于沸点温度，以NaCl为助溶剂(NaCl与粉煤灰质量比为0.05：1)，以钛白废酸浸取粉煤灰(固液比为1：10)中的铝1.5小时，最大浸取率可达40％；经过滤洗涤后，调节滤液pH至2.0左右，以NANO_2为催化剂(NaNO_2用量为滤液中FeSO_4·7H_2O量的3％)，空气为氧化剂，于40-50℃进行常压催化氧化反应，制取聚合硫酸铁铝，催化氧化时间为2小时；将工业水玻璃稀释至3％左右，调节其pH于5-6，室温下制备活性聚硅酸；将活性聚硅酸与聚合硫酸铁铝按照一定比例复合，经熟化，即制得新型无机高分子混凝剂PFASS。

The Suzuki reaction, the coupling of organoborate compounds with organic electrophiles catalyzed by Palladium complexes, is a valuable Csp2-Csp bond forming reaction. The reaction has been drawing increased attention in that the reaction permit the use of organoboron compounds that are thermally stable and inert to water and oxygen.In this section microwave promoted Suzuki reaction of phenylboronic acid with benzyl halides catalyzed by Pd(PPh3)2Cl2 DMF/H2O(v/v=10 : 2) was first reported.

第四章：微波辐射下Pd配合物催化端烯与芳卤偶联反应研究本章中我们在微波辐射条件下，研究了PdclZ(P Ph3)：催化端烯与芳卤的偶联反应，合成出了七种乙烯基化合物；并分别考察了微波辐射功率、辐射时间、原料配比、和PTc等因素对反应的影响，优选出了较佳的反应条件，并根据文献及实验结果，讨论了可能的反应机理。

The lumped kinetic model of monoterpene, abietic type resin acid, pimaric acid type resin acid, p-cymene, hydro-monoterpene, dehydro-abietic acid, hydro-abietic type resin acid, and hydro-pimaric acid type resin acid was established based on the structural groups and approximate reaction kinetic theory according to the fundamental principles of the lumped method.

在消除内、外扩散影响的条件下，在线跟踪反应产物并用气相色谱法测定反应体系组成随时间的变化，构造了Pd／C催化剂上松脂分子间氢转移集总反应网络，建立了包含单萜烯、枞酸型树脂酸、海松酸型树脂酸、对伞花烃、氢化单萜烯、脱氢枞酸、氢化枞酸型树脂酸和氢化海松酸型树脂酸等复杂反应体系的集总动力学模型，并估算了模型参数。

The phase equilibrium data of SBO-FAME-Methanol, SBO-FAEE-Ethanol and Glycerol-FAEE-Ethanol systems were measured. The results indicated that it involved two different stages: liquid-liquid-solid reaction stage and liquid-solid reaction stage. When the molar ratio of methanol to oil is 12:1 at 65℃, the turning point is at a 55% biodiesel yield. The liquid-liquid-solid reaction model was proposed based on the double-membranes theory. It indicated that the process is reaction and mass transfer controlled together at the first stage, and the second stage is reaction controlled. The predictions of the model are matched with the experimental results.In the end, the acid was extracted using methanol and ethanol from jatropha curcas l oil.

测定了生物柴油制备过程中的SBO-FAME-Methanol、SBO-FAEE-Ethanol、Glycerol-FAEE-Ethanol三组分相平衡数据，表明固体碱催化过程分为液-液-固和液-固两个反应阶段，在醇油摩尔比为12：1、65℃的初始反应条件下，转化率达到55%时，为第一阶段向第二阶段的转折点；基于双膜理论建立了固体碱催化制备生物柴油的非均相液-液-固反应模型，表明两个反应阶段分别为传质、反应共同控制和反应控制，模型计算值与实验值吻合较好。

Thirdly, the acrylic rosin was synthesized by the addition reaction from gum rosin andacrylic acid. The levo-pimaric acid was converted into acrylic pimarie acid throughDiels-Alder addition with acrylic acid. The abietic-type acids in the gum rosin were inisomerization balance under high temperature, and the abietic acid and palstric acid would beconverted into levo-pimaric acid and reacted in the later type.

第三，通过脂松香与丙烯酸加成合成了丙烯酸松香，该反应是左旋海松酸与丙烯酸发生Diels-Alder加成反应生成丙烯海松酸，由于脂松香中的枞酸型树脂酸在高温下处于异构化平衡状态，因此随着反应的进行枞酸、长叶松酸等会异构化为左旋海松酸参与反应。

The active zinc borate, hydrophobic and oleophilic, is prepared, using borax, zinc sulfate, boric acid and fatty acid or its salt as the material and water as the solvent, by controlling the proper reaction temperature, solid-to-liquid ratio, material ratio, reaction time and the addition quantity and time of the fatty acid or its salt and by filtering, drying and pulverizing.

本发明以硼砂、硫酸锌、硼酸和脂肪酸或其盐为原料，以水做溶剂，通过控制适当的反应温度、固液比、物料比、反应时间及脂肪酸或其盐的加入量及加入时间，通过过滤、干燥和粉碎制备出疏水亲油的活性硼酸锌。

Reaction of citric acid with paraformaldehyde gave anhydromethylene citric acid with a yield of 63%;the reaction of compound with acetic anhydride gave the corresponding anhydride with a yield of 87%;the esterification of compound with lauryl alcohol gave anhydrocitric acid monoester with a yield of 76%.

将等浓度的柠檬酸和多聚甲醛加热，反应生成柠檬酸缩醛环酯，产率为63%；与乙酸酐反应得到相应的柠檬酸酐，产率为87%；与月桂醇酯化，生成产物，产率为76%；用二氧六环做溶剂，将与等浓度的碱进行开环反应，生成柠檬酸月桂醇单酯，产率为83%。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。