查询词典 acid reaction

Six derivatives of 4-phenyl-3-phenoloxymethyl-5-mercapto-1,2,4-triazlyole were synthesized from phenoloxyacetyl hydrazide by two-steps reaction under microwave irradiation, then reacted with 2-chloroacetic acid to give six novel derivatives of 2-(3-phenoxymethyl-4-phenyl-[1,2,4]triazole-5-thio)-acetic acid.

在微波辐射条件下，芳氧乙酰肼经两步反应制得4-苯基－3-芳氧甲基－1，2，4-三唑－5-硫酮衍生物，再与氯乙酸反应得到6种尚未见文献报道的2-（3-芳氧甲基－4-苯基－1，2，4-三唑－5-硫基）乙酸衍生物。

Theoretical investigation of the solvent effects on the mechanism of the reaction of pentafulvenone with hydrocyanic acid to produce the main product of acid of type b was carried out at B3LYP/6-311+G** level via the conductor-like polarizable continuum model.

在B3LYP/6-311+G**计算水平上，采用导体极化连续模型研究了溶剂化效应对6-亚甲基环戊二烯酮与HCN反应生成主要产物b类酸的反应机理的影响。

Theoretical investigation of the solvent effects on the mechanism of the reaction of pentafulvenone with hydrocyanic acid to produce the main product of acid of type b was carried out at B3LYP/6-311+G(superscript **) level via the conductor-like polarizable continuum model.

在B3LYP/6-311+G计算水平上，采用导体极化连续模型研究了溶剂化效应对6-亚甲基环戊二烯酮与HCN反应生成主要产物b类酸的反应机理的影响。

In this paper, initiator is dissolved in 1-bromopropane which is solvent. Then the propene and hydrogen bromide that can be dissolved in 1-bromopropane are inlet in l-bromopropane when initiator is decomposing. The reaction occurs in fluid phase and high-purity 1-bromopropane is synthesized by one step method. In this paper, the material HBr is synthesized with NaBr and sulfuric acid at the presence of hydrobromic acid.

本论文以1-溴丙烷为溶剂，将引发剂溶于其中，加热到引发剂开始分解时再通入丙烯和HBr，使二者溶解于1-溴丙烷中，在液相中进行反应，实现丙烯"一步法"合成高纯1-溴丙烷利用NaBr与硫酸在氢溴酸存在下反应制备HBr气体，以作为合成1-溴丙烷的原料。

Difluorodiphenylsulfone and 4, 4"-difluorodiphenylketone are sulfonated by 50 % sulfuric acid. A new biphenol monomer containing six-membered ring imide is synthesized by reaction of 1, 4, 5, 8-naphthelenetetracarboxylic acid dianhydride with 3-aminophenol or 4-aminophenol sodium.

以50%发烟硫酸为磺化试剂，以4，4′-二氟二苯砜和4，4′-二氟二苯酮为原料反应得到双磺化的4，4′-二氟-3，3′-二磺酸钠-1，1′-二苯砜和4，4′-二氟-3，3′-二磺酸钠-1，1′-二苯酮。

The results show that, foamed acid possesses some characters such as low density, flowback easily, water plugging, selectively blocking up, corrosion control, reaction control, esc. Then foamed acid was especially fit for gas wells, reacidizing wells, wells of prominent interlamination antinomy between layers, wells containing water and oil in a same layer, esc.

研究结果表明，泡沫酸具有密度低、易返排、堵水不堵油、堵大不堵小、缓蚀、缓速等重要性质，特别适用于气井、重复酸化的老井、层间渗透率差异井、油水混层井等的酸化施工作业。

The results showed that when the catalyst amount was 4 g/L,the molar ratio of L-ascorbic acid to malic acid was 1:3,and the reaction temperature was 55 ℃,the highest L-ascorbyl malate yield of 69.30% could be obtained.

结果表明：添加固定化酶量4g/L，底物配位物质的量比1：3，温度55℃，L-抗坏血酸苹果酸酯的得率最高为69.30%。

The effect of various conditions on the reaction, such as solvent, temperature, the amount of catalysts,the concentration of hydrochloric acid, the amount of hydrochloric acid, oxygen/air and so on, was studied.

在此基础上，系统地考察了溶剂、温度、催化剂各组分的用量、盐酸的浓度、盐酸的用量、氧气/空气等因素对芳香化合物氧化氯化反应的影响。

During the manufacturing of the critical intermediate cephalosporin nucleus --7-amino-3-chloro-cephalosporanic acid diphenylmethyl ester hydrochloride salt, first the feasibility of the one-pot synthetic route of open loop, closed loop and ozonization when chlorine is passed over is qualified by experiments. Then the critical factors that will influence this reaction are studied as follows: the mol ratio of triphenyl phosphite and Diphenylmethyl 3-hydroxy-7-phenylacetaminoceph-3-em-4-carboxylate-l-oxide is four to one; the quantity of the stablizer should be at least more than two to one. The temperature of the system must be 25℃ when chlorine is passed over so that the hydrochloride can be precipitated to obtain cephalosporin nucleus of cefaclor--7-amino-3-chloro-cephalosporanic acid diphenylmethyl ester hydrochloride salt.

在制备关键中间体头孢母核7-氨基-3-氯头孢烷酸二苯甲酯盐酸盐时，先通过实验验证把开环、闭环、臭氧化三步在通入氯气时并为一锅煮的合成路线的可行性之外，又研究了影响该反应的几个重要因素：亚磷酸三苯酯与3-羟基-7-头孢烷-5-亚砜-2-甲酸二苯甲酯的摩尔比为4：1；稳定剂2-甲基-2-丁烯的用量至少大于2：1，通入氯化氢气体时体系温度在25℃时盐酸盐则能够顺利析出，获得头孢克洛的头孢母核—7-氨基-3-氯头孢烷酸二苯甲酯盐酸盐。

As the second part of a series of studies on the synthesis of 2-phenoxyisobutyric acid ethyl ester by tri-liquid-phase catalysis, this work examines the factors affecting the reaction between 2-bromoisobutyric acid ethyl ester and sodium phenolate with tetra-n-butylammonium bromide as a phasetransfer catalyst.

本文为以三液相催化技术合成2-苯气基异丁酸乙酯之研究系列的第二部份，主要在探讨各变因对以溴化正四丁基铵为相间转移触媒，催化2-溴异丁酸乙酯与酚化钠（NaOPh，水相亲核试剂）反应的影响。

The labia have now been sutured together almost completely.The drains and the Foley catheter come out at the top.

此刻阴唇已经几乎完全的缝在一起了，排除多余淤血体液的管子和Foley导管从顶端冒出来。

To get the business done, I suggest we split the difference in price.

为了做成这笔生意，我建议我们在价格上大家各让一半。