查询词典 acid reaction

For the saturated aromatic aldehydes with malononitrile and barbituric acidit, the reaction was found to proceed very efficiently at room temperature giving excellent yields under ultrasonic irradiation, while for α,β-unsaturated aldehydes as well as p-phthalaldehyde with malononitrile and barbituric acid the reaction also proceeded smoothly at room temperature with good yields.

在超声波辐射下，不仅饱和芳香醛与丙二腈、巴比妥酸的一锅反应在室温下能高收率地进行，而对于α，β-不饱和醛以及二元醛与丙二腈、巴比妥酸的一锅反应也能在室温下顺利进行，获得较高的收率。

One of the reaction products in the solid state reaction between silver behenate and phthalic acid — di-silver phthalate (Ag2PA) was prepared by liquid deposition method, and was characterized with elemental analysis, ICP-AES and FT-IR.

采用液相沉淀法合成了山嵛酸银与邻苯二甲酸的固相反应产物邻苯二甲酸二银，并通过元素分析、ICP-AES、FT-IR等方法对其进行了表征分析。

Under the catalysis of rare earth composite solid superacid SO42-/ZrO2-La2O3,reaction of a-pinene and anhydrous oxalic acid afforded bornyl oxalate smoothly. Followed by saponification reaction, borneol was obtained selectively.

在稀土复合固体超强酸SO42-/ZrO2-La2O3的催化下， a -蒎烯与无水草酸的反应能顺利生成草酸龙脑酯，经皂化反应后，能选择性地合成正龙脑。

A series of liquid crystals containing naphthalene 1~13 was synthesized by the reaction of carbonyl compound with Grignard reagent and coupling reaction between phenyl boronic acid and halogen naphthalene .

经羰基化合物与格氏试剂反应及芳基硼酸与萘基卤化物偶联反应合成了系列含萘环骨架液晶化合物1~13；产率在73%~759%。

According to the result, we believed that the reason resulted in the low sensitivity was that the marker residue compound MQCA structure has changed after conjugated with protein and the antibody induced by the conjugation could not recognize the free MQCA in the ci-ELISA. Therefore we designed some hapten which could reserve the marker residue structural speciality mostly. After synthesis route selection and optimum, the hapten 7-Hydroxymethyl-3-methyl-quinoxaline-2-carboxylic acid was synthesized, used 4-methyl-2-nitroaniline as the start material via six steps, such as oxidation cyclization, bromize reaction, hydrolysis, Beirut reaction, reduction, hydrolysis. This work established basis for producing the high affinity antibody and developing the sensitive ELISA residue detection method.

本论文认为导致ELISA检测灵敏度较低的原因，是残留标示物和蛋白偶联后的特征结构发生改变，诱导产生的抗体不能够对游离MQCA很好的识别，因此，本论文设计了能够最大化保留MQCA结构特征的系列半抗原结构，并对其合成路线进行了筛选和优化，最终以对甲基邻硝基苯胺为起始原料，经氧化环化、溴代、水解、Beirut缩合、还原、水解六步反应制备含羟甲基结构的MQCA衍生物7-羟基甲基-3-甲基-喹噁啉-2-羧酸，为制备对游离残留标示物高亲和力的抗体，高灵敏度的ELISA残留检测方法的建立奠定基础。

The higher the degree of external hydrogen-donation is, the easier the reaction is.③Thiophenes can be alkylated by the carbonium ion born in the reaction, and they can be polymerized on the strong acid sites.

噻吩类化合物可与反应过程中产生的正碳离子发生烷基化反应；在含有强酸性中心的催化剂上，噻吩类化合物之间还会发生一定程度的缩合反应。

The influence of reaction condition on the yield of isopropyl chloroacetate as investigated such as catalyst loading, molar ratio of chloracetic acid to isopropanol, reaction time and repeated use of the catalyst.

考察了催化剂的用量、反应物物质的量比、反应时间和催化剂的重复使用等因素对收率的影响。

The silver nanoparticles modified by oleic acid were successfully synthesized by the replacement reaction of silver nitrate with metal sodium in decalin, and the reaction was achieved via ultrasonic irradiation.

在有机介质十氢化萘中，以金属钠、硝酸银和油酸钠为起始原料，通过超声辐射使金属钠和硝酸银发生置换反应，成功制备了油酸表面修饰的Ag纳米微粒。

This work, concentrated on the asymmetric allylation of aldehydes controlled by different chiral auxiliaries prepared from rotational pure tartaric acid, can be divided into three parts.The first part aims to review the developments of chiral drugs and asymmetric synthesis, from which derived the present research topic backgrounds and works.Synthesis and applications of allylation from aldehydes are the second part of the thesis. By optimizing the reaction conditions, such as solvents, temperature, time and chiral auxiliaries like N,N\'-dibenzyl tartamide, N,N\'-p-dimethylphenyl tartamide, N,N\'-o-dimethylphenyl tartamide, N,N\'-o-dichlorophenyl tartamide, N,N\'-a-dinaphyl tartamide, N,N\'-dicyclohexyl tartamide and N,N\'-diphenyl tartamide, ideal experimenttal conditions are obtained according to HPLC monitoring, as well as the auxiliaries\' recoveries experiments. Starting from benzaldehyde and 3-bromopropaldehyde, N,N\'-dibenzyl tartamide is considered the best auxiliary in this reaction.

本文介绍了醛的不对称烯丙基化反应，以光学纯酒石酸为原料，研究了不同构型手性配体在醛的烯丙基化反应中的立体选择性，全文共分三部分十个章节：第一部分对当前手性药物和手性技术进行了概述，并由此展开了本文的研究背景和任务；第二部分为有机合成部分，对醛的不对称烯丙基化反应进行了深入探讨，以苯甲醛为原料对反应条件进行优化，在优化的反应条件下对制备的七种可回收手性酰胺配体(N-苄基酒石酸二酰胺、N-对甲苯基酒石酸二酰胺、N-邻甲苯基酒石酸二酰胺、N-邻氯苯基酒石酸二酰胺、N-a-萘基酒石酸二酰胺、N-环己基酒石酸二酰胺和N-苯基酒石酸二酰胺)进行筛选，优化配体回收实验条件，最终确定出N-苄基酒石酸二酰胺在苯甲醛的不对称烯丙基化反应中具有较大优越性，结晶回收的手性配体光学纯度保持不变。

It showed that the ammonium ferric sulfate dodecahydrate was an excellent catalyst,the yield of the n-butyl lactate could reach over 95.0% under molar ratio of n-butyl alcohol and lactic acid 2.25∶1,the reaction temperature of 110～125℃,reaction time of 1.5 h and amount of the ammonium ferric sulfate dodecahydrate catalyst of 2.5%.

实验表明：NH4Fe(SO4)212H2O是合成乳酸正丁酯的良好催化剂。最佳反应条件为：醇酸物质的量比2.25∶1，催化剂的用量为反应物料总量的2.5％，酯化反应时间为1.5 h，反应温度110～125℃，酯化率可达95.0％。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。