查询词典 acid reaction

Influence of alcohol-to-acid mole ratio, reaction temperature, catalyst dosage and reaction time on the esterification was investigated.

考察了醇酸物质的量比、温度、催化剂用量、反应时间等各种因素对酯化率的影响。

The method is realized by that polyether ether ketone is added into concentrated sulfuric acid to carry out sulfonation reaction, thereby obtaining sulfonated polyether ether ketone, then the sulfonated polyether ether ketone is dissolved in organic solvent, N, N (1)-Carbonyldiimidazole is added to stir for one to three hours, coupling agent is mixed for stirring the reaction for 1.5 to 4 hours, then inorganic crosslinking agent is mixed to react under the temperature of 50 to 80 DEG C. Proton conductors are mixed to continue getting the mixed solution of the sulfonated polyether ether ketone or the inorganic crosslinking agent or proton conductors under the temperature. Finally the proton exchange membrane for a direct methanol fuel cell is obtained by that the mixed solution of the sulfonated polyether ether ketone or the inorganic crosslinking agent or proton conductors is/are processed through membrane forming, drying and exuviation.

该方法首先将聚醚醚酮加入浓硫酸中进行磺化反应得到磺化聚醚醚酮；然后将磺化聚醚醚酮溶于有机溶剂中，加入N，N′-羰基二咪唑搅拌1～3小时后加入偶联剂搅拌反应1.5～4小时，再加入无机交联剂在50～80℃下反应，然后加入质子导体继续在此温度下反应得到磺化聚醚醚酮/无机交联剂/质子导体的混合溶液；最后将磺化聚醚醚酮/无机交联剂/质子导体的混合物溶液成膜，干燥，脱膜即得到所述的直接甲醇燃料电池用质子交换膜。

The reaction time, reaction temperature and catalyst influencing on esterification were investigated, and the acid value, flashing point and other properties were determined.

考察了反应时间、反应温度、催化剂等反应条件对酯化反应的影响，并对增塑剂的酸值、闪点及其他主要性能指标进行了测定，改进了酯化反应工艺条件，讨论了样品色泽、酸值及闪点的影响因素。

The invention uses benzene carbonic acid as raw material, uses hydrogen gas as reducing agent, and uses ZnO and CeO2 as main accelerating agent. In solid-bed reactor the invention carries out hydrogenation reduction reaction. The reaction temperature is 340-440Deg.C, gas hourly space velocity is 600-4800h-1, hydracid mole rate is 20:1-160:1, the selectivity ratio of benzaldehyde is 99%, and the productivity is above 95%.

该方法以苯甲酸为反应原料，以氢气为还原剂，以ZnO和CeO 2 的复合氧化物为主催化剂，在固定床反应器中，进行气相加氢还原反应，反应温度为340℃～440℃，气时空速为600h -1 ～4800h -1 ，氢酸摩尔比为20∶1～160∶1，采用本发明制备苯甲醛的选择性可达99％，收率可达95％以上。

The invention uses benzene carbonic acid as raw material, uses hydrogen gas as reducing agent, and uses ZrO2, TiO2 and Y2O3 as main accelerating agent. In solid-bed reactor the invention carries out hydrogenation reduction reaction. The reaction temperature is 340-450Deg.C, gas hourly space velocity is 600-4800h-1, hydracid mole rate is 20:1-160:1, the selectivity ratio of benzaldehyde is 96%, and the productivity is above 90%.

该方法以苯甲酸为反应原料，以氢气为还原剂，以复合氧化物ZrO 2 、TiO 2 和Y 2 O 3 为主催化剂，在固定床反应器中，进行气相加氢还原反应，反应温度为340℃～450℃，气时空速为600h -1 ～4800h -1 ，氢酸摩尔比为20∶1～160∶1，采用本发明制备苯甲醛的选择性可达96％以上，收率可达90％。

During the reaction of catalytic oxidation of mesitylene by air in the gas-liquid phase to synthesize trimesic acid as well as the correlative process, with the aim of controlling the product's quality and improving its reaction yield, it's necessary to bulid a set of reliable and integral analysis methods.

在均三甲苯气液相催化空气氧化合成均苯三甲酸的反应及相关的工艺过程中，为了更好的控制产品质量和提高反应收率，建立一套可靠完善的分析方法是很有必要的。

The better technology has been obtained: taking water-EG as solvent 2-imidazolidinone was prepared. The molar ratio of the methanal (36%) to the formic acid (85%) is 1:2.8, reaction temperature is 95~100℃, reaction time is 16 h, taking cuprous chloride and triethylamine as catalyst, the molar ratio of the cuprous chloride and triethylamin to 2-imidazolidinone is 1.0% while 1,3-DMI was prepared.

较佳工艺条件为：制备2-咪唑啉酮时，以水－乙二醇混合作溶剂；制备1，3-DMI时，甲醛(36%)：甲酸(85%)摩尔比为1：2.8，反应温度95~100℃，反应时间16 h，氯化亚铜和三乙胺作催化剂，用量分别是2-咪唑啉酮摩尔数的1.0%。

Over a solid acid catalyst, the reaction in which methanol and formaldehyde are condensed into mathylal is reversible. This reaction tends to be completion by reactive distillation and the high-purity methylal product can be obtained.

在固体酸催化剂作用下，由甲醇、甲醛缩合生成甲缩醛，该反应为可逆反应，采用催化精馏技术可使反应趋于完全，并得到高纯度甲缩醛产品。

The invention discloses a method for synthesizing acetyl tributyl citrate, which uses tributyl citrate and acetic anhydride as reaction articles, uses naphthalenesulfonic acid methylal as the catalyst during the ester synthesis process, filtering the catalyst from reacted articles after reaction, water-washing, alkaline-washing, distilling the filtrate to obatin acetyl tributyl citrate.

本发明公开了一种合成乙酰柠檬酸三丁酯的方法，它以柠檬酸三丁酯、乙酸酐为反应物，在酯合成过程中用萘磺酸甲缩醛作催化剂，反应结束后，将催化剂从反应后的物料中过滤出来，滤液经水洗、碱洗、蒸馏获得乙酰柠檬酸三丁酯。

In comparison with literature method, the microwave approach shows the salient features of rapid reaction rates and significant energy saving, clean reaction conditions, enhancement in chemical yield, and nonuse of perchloric acid(70%), which will result in cost saving and minimize safety concerns in the organic laboratory.

考察了微波辐射功率和辐射时间对目标产物收率的影响，2，4，6-三芳基吡喃盐与盐酸羟胺反应生成3，5-二芳基异噁唑衍生物的最佳微波辐射功率为600 W，辐射时间为8 min，最大收率为83%。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。