查询词典 acid reaction

Cyclic voltammetry indicated that there were Cr→Cr, Cr →Cr oxidation reaction on anode, while there were Cr→Cr, Cr→Cr, Cr →Cr deoxidization reaction on cathode. The graphite electrodes treated by acid and heating could enhance the reversibility and kinetic of the electrode reaction. The nature graphite electrodes had been eroded during charge/discharge process, while the graphite electrodes by activation could avoide corroding by hexad chromium ion. The reversibility and kinetic of the electrode reaction of chromium ion on activation electrode had been increased, so which indicated that graphite surface augment oxygenous function corps which could increase electrode hydrophile capability.

循环伏安实验表明：铬液流电池的电极反应非常复杂，在阳极存在Cr→Cr，Cr→Cr的氧化反应，在阴极存在Cr→Cr，Cr→Cr，Cr→Cr的还原反应；热处理的石墨电极和重铬酸钾处理的石墨电极能提高电极反应的活性和可逆性；在充放电实验中未处理的石墨电极发生严重腐蚀；分别用这两种方法处理过的石墨电极具有防止六价铬侵蚀的功能；铬离子在活化处理过的石墨电极上的反应活性和可逆性增加，可以认为：重铬酸钾溶液活化处理和加热处理后的石墨表面的含氧官能团增加，电极亲水性增强。

Finally, pentyl acetate and benteine could be respectively synthesized by esterification reaction in the presence of nanometer rare earth composite solid superacids (SO_4)~(2-)/ZrO_2-Gd_2O_3 and (SO_4)~(2-)/ZrO_2-Nd_2O_3. The effects of reaction time, reaction temperature, the mol ratio of acid to alcohol and the use level of catalyst on esterification yield were discussed. In the end, we obtained their optimal reaction conditions.

采用纳米稀土复合固体超强酸SO_4~(2-)/ZrO_2-Gd_2O_3，SO_4~(2-)，~/ZrO_2-Nd_2O_3分别合成了乙酸戊酯和乙酸苄酯两种香料，实验考察了反应时间、反应温度、醇酸比及催化剂的用量对酯化率的影响，并由此得出反应的最佳条件。

This complex reaction was phenolic electronic substitution reaction, so reaction rate was related with the positive electricity of pro-electronic reagent, as well as the form of aromatic hydrocarbons. Rates of chlorination of phenol and 2-monochlorophenol were faster in alkaline water than that in weak acid water, so 2,4-dichlorophenol and 2,4,6-trichlorophenol formation concentrations increased with the reaction time.

该复合反应属于酚类电子取代反应，反应速率与亲电子试剂的阳电性以及芳香烃的形式有关，碱性水环境中氯取代苯酚和2-一氯酚的速率要快于在弱酸性水环境；随着pH的升高，2，4-DCP和2，4，6-TCP的生成浓度也不断增加。

Therefore esterification crosslinked reactionbetween polyearboxylic acid and wood can be quantitatively determined.According toexperiment results of stereoscopic configuration choices by crosslinking agents,crosslinkingreaction between model of reaction intermediate and wood,and the intermediate characteristic incrosslinking reaction,crosslinking reaction intermediate was proofed.We can infercrosslinking reactions between polycarboxylicacid and wood want through a mechanism of twosteps reaction process,the first cyclic anhydrides were formed as intermediates by dehydratingbetween hydroxyls in polycarboxylic acids,second esters were occurred by substitution reactionbetween wood hydroxyls and cyclic anhydrides.

从而可全面定量表征木材与多元羧酸类化合物的酯化交联反应；依据交联剂立体构型选择性、反应中间体模型物与木材的交联反应和交联反应中间体的波谱特征实验结果，证实了交联反应中间体，因此可以推测：多元羧酸类化合物与木材化学组分的交联反应是经历两步反应的机理，首先多元羧酸中相邻羧基的羟基之间脱水形成五元环酸酐中间体，然后木材的羟基与酸酐发生亲核取代反应形成酯。

Under the optimal reaction conditions like 140°C of reaction temperature, 2.5 MPa of reaction pressure, 1.5 mg catalyst and 8 h of reaction time, the highest yield of adipic acid and TON were 21.4% and 24 582, respectively.

优选的反应条件是：反应温度为140℃，氧气压力为2.5 MPa，反应时间为8 h，催化剂用量为1.5 mg。在此条件下，己二酸的质量收率可达21.4%，活性转化数可达24 582。

The latest applications of boronic acids as catalyst to organic synthesis are reviewed, focusing on the catalytic activities and reaction mechanism of different catalysts discovered in condensation reaction, carboxylic acid reduction reaction, and Diels-Alder reaction.

吴记勇 ；方浩*；徐文方摘要：综述了有机硼酸类作为催化剂应用于有机合成反应中的最新研究进展，重点介绍了所发现的各种有机硼酸催化剂在缩合反应、羧酸还原反应、Diels-Alder反应中的催化活性以及反应机理。

We studied the effect of water on the palladium acetate-catalyzed coupling reaction of aryl boronic acid with aryl bromide or acyl chloride in ionic liquid or PEG, and found that water had a remarkable rate accelerating effect on the Suzuki reaction and Suzuki-Type reaction when other reaction conditions were uniform.

研究了水对离子液体或聚乙二醇中Pd2催化的卤代苯或苯甲酰氯与苯硼酸的Suzuki和Suzuki-Type偶联反应收率的影响。

The factors affect on the degree of substitution of product, yield and apparent viscosity, such as the mol rates of EPTAC with -NH2, reaction temperature, reaction time and the content of water in system have been discussed in detail. FTIR spectrometer and UV spectrometer are used to characterize the structure of the derivative and it is proved that substitution reaction mainly occurs on the -N element .The particle size and morphology of chitosan and quantemary ammonium salt of chitosan are analysised by comparing photos of their scanning electron microscope. The degree of substitution of HACC is determined by acid -base conductometric titration. An error in current formula of DS has pointed out and a correct formula has presented.On the base of experience of above experiment, the reaction conditions of HACC were systematically investigated through orthogonal design, and then the best conditions are found. Water-solubility and dependence of pH are studied.

壳聚糖和环氧丙基三甲基氯化铵在异相条件下发生反应，通过单因素实验，制备了一系列不同性能的壳聚糖季铵盐，本文首次详细讨论了反应条件(反应摩尔比、反应时间、反应温度、水含量)对产率及产物性能的影响；用红外光谱和核磁共振对结构进行表征分析时，发现季铵盐阳离子基以N位上取代为主；通过电镜图片对壳聚糖和季铵盐衍生物外观形貌进行对比，采用酸碱电导滴定法测定产物的取代度，并对常用取代度公式做了修正。

Ethyloxymethylnaphththyridinecarboxylic acid ; condensation reaction ; cyclization reaction ; ethylation reaction ; hydrolysis reaction ; spectrum characteristic

乙基氧甲基萘啶羧酸；缩合反应；成环反应；乙基化反应；水解反应；光谱特征

The Effect of different reaction conditions (solvent, reaction temperature, molar ratio of iodobenzene and acrylic acid, kind and amount of base, amount of catalyst, reaction time) on the yield was investigated. The suitable condition of the reaction was obtained.

考察了不同反应因素（溶剂、温度、原料比、缚酸剂及其用量、催化剂用量、反应时间）对反应的影响，确定了该催化剂对碘代苯与丙烯酸交叉偶联生成反式－肉桂酸的适宜反应条件。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。