查询词典 acetic anhydride

For the synthesis of NHC precursors, there are also several routes: condensation of glyoxal, amines and paraformaldehyde; alkylation of imidazole or monosubstituted imidazole with alkyl halide; annulation of ortho esters and 1,2-diamines; ring closure of hydrazines or amides with acetic anhydride; reduction of thiones with Na/K in THF.

关于N-杂环卡宾前体的合成途径主要有：乙二醛、伯胺和多聚甲醛的缩合反应；卤代烷与咪唑及其取代咪唑的烷基化反应；原甲酸酯与1，2-二胺的成环反应；肼或酰胺与酸酐的环化反应；用Na/K对环硫脲化合物的还原反应。

For the first time acetic anhydride was used as solvent to disperse HAp particles, which avoided adding acid solution into the suspension and the gas formed by the electroanalysis of water.

石02具有介于钦和HAp之间的热膨胀系数，起到过渡层的作用，从而可降低烧结后涂层和基底之间的残余应力，减少 HAp涂层裂纹的发生，进一步改善了涂层的结合性能。

Aim To prepare lower degree of substituted starch acetate with cassava starch as material, acetic anhydride as acetylation reagent, sodium hydroxide as catalyst and sodium sulfate as gelatinization inhibiter.

目的 以木薯淀粉为原料，醋酸酐为乙酰化试剂，NaOH为催化剂，Na2SO4为膨胀抑制剂，制备了低取代度木薯淀粉醋酸酯。

The invention discloses a method for synthesizing acetyl tributyl citrate, which uses tributyl citrate and acetic anhydride as reaction articles, uses naphthalenesulfonic acid methylal as the catalyst during the ester synthesis process, filtering the catalyst from reacted articles after reaction, water-washing, alkaline-washing, distilling the filtrate to obatin acetyl tributyl citrate.

本发明公开了一种合成乙酰柠檬酸三丁酯的方法，它以柠檬酸三丁酯、乙酸酐为反应物，在酯合成过程中用萘磺酸甲缩醛作催化剂，反应结束后，将催化剂从反应后的物料中过滤出来，滤液经水洗、碱洗、蒸馏获得乙酰柠檬酸三丁酯。

Naphthyl aceate was synthesized with acetic anhydride and naphthol using aminosulfonic acid as catalyst.

以氨基磺酸为催化剂，用乙酸酐和β-萘酚合成了乙酸β萘酯。

The ammonia was evaporated under decreasing pressure, and the precipitate was filtered off and the liquid was poured into hot saturated picric acid solution to get picrate with a yield of 85.0%. The optimum process starting from imidazole-4,5-dicarboxylic acid was: imidazole-4,5-dicarboxylic acid in acetic anhydride was refluxed to get imidazole-4-carboxylic acid, and the product was esterification in ethanol with a catalyzer of concentrated sulfuric acid to get ethyl imidazole-4-carboxylate, at last the compound above was reduced by LiAlH4 in ether at room temperature to get the target compound, the total yield of this route was 49.6%.

以4，5-二羧酸咪唑为原料的较佳工艺：1 脱羧反应：4，5-二羧酸咪唑40g，醋酐1200ml，回流10h，过滤并将滤液浓缩至干，所得固体加至50%的乙醇溶液回流，过滤并将滤液自然冷却过夜，过滤得固体；2 酯化反应：4(5)-羧酸咪唑50g，乙醇1000ml和浓硫酸60ml，加热回流2h，5%浓度NaOH溶液调节至pH＝8，减压浓缩至干，加入少量水回流，自然冷却过夜并过滤得固体；3 还原反应：LiAlH410g，乙醚300ml和4(5)-羧酸咪唑乙酯28g，常温反应1.5h，小心滴加25ml水后过滤，滤渣溶于300ml甲醇中并过滤，收集所得乙醚和甲醇滤液浓缩至干，将所得固体溶于300ml乙醇中加热回流，后将溶液浓缩至约30ml，冷却并过滤得固体，该路线总收率为49.6%。

The other for: safrole, sassafras oil, safrole different 82 yuan / kg; 1 - phenyl -2 - propanone 2,500 yuan / kg; 3.4 dioxane methylene diphenyl -2 - propanone 7200 yuan / ton; Piperonal 1,000 yuan / kg; N-acetyl-o-amino benzoic acid 11500 yuan / ton; anthranilic acid 15,500 yuan / ton; Phenylacetate 15,000 yuan / ton; acetic anhydride 9900 yuan / ton; trichloromethane 4100 yuan / ton ; anhydrous ether 8500 yuan / ton; piperidine 58000 yuan / ton; methyl ethyl ketone 10,000 won / ton; sulfate 1,200 yuan / ton; hydrochloride 400 yuan / ton; ethanol 4200 yuan / ton.

另供：黄樟素、黄樟油、异黄樟素82元/公斤；1-苯基-2-丙酮2500元/公斤；3.4 亚甲基二氧苯基-2-丙酮7200元/吨；胡椒醛1000元/公斤；N-乙酰邻氨基苯酸11500元/吨；邻氨基苯甲酸15500元/吨；苯乙酸15000元/吨；醋酸酐9900元/吨；三氯甲烷4100元/吨；无水乙醚8500元/吨；哌啶58000元/吨；甲基乙基酮10000元/吨；硫酸1200元/吨；盐酸400元/吨；无水乙醇4200元/吨。

The other for: safrole, sassafras oil, safrole different 82 yuan / kg; 1 - phenyl -2 - propanone 2,500 yuan / kg; 3.4 dioxane methylene diphenyl -2 - propanone 7200 yuan / ton; Piperonal 1,000 yuan / kg; N-acetyl-o-amino benzoic acid 11500 yuan / ton; anthranilic acid 15,500 yuan / ton; Phenylacetate 15,000 yuan / ton; acetic anhydride 9900 yuan / ton; trichloromethane 4100 yuan / ton ; anhydrous ether 8500 yuan / ton; piperidine 58000 yuan / ton; toluene 5200 yuan / ton; methyl ethyl ketone 10,000 won / ton; sulfate 1,200 yuan / ton; hydrochloride 400 yuan / ton; anhydrous Ethanol 4200 yuan / ton.

另供：黄樟素、黄樟油、异黄樟素82元/公斤；1-苯基-2-丙酮2500元/公斤；3.4 亚甲基二氧苯基-2-丙酮7200元/吨；胡椒醛1000元/公斤；N-乙酰邻氨基苯酸11500元/吨；邻氨基苯甲酸15500元/吨；苯乙酸15000元/吨；醋酸酐9900元/吨；三氯甲烷4100元/吨；无水乙醚8500元/吨；哌啶58000元/吨；甲苯5200元/吨；甲基乙基酮10000元/吨；硫酸1200元/吨；盐酸400元/吨；无水乙醇4200元/吨。

Then esterification of 3, 7-dimethyl-2-pentadecanol with acetic anhydride, the active component of sex pheromone of pine sawfly, 3, 7-dimethyl2-pentadecanyl acetate was obtained in 83. 4％ yield.

最后，用乙酸酐对3，7-二甲基-2-十五碳醇进行酯化，得到松叶蜂性信息素的活性组分--3，7-二甲基-2-十五碳醇乙酸酯，收率为83.4％。

Synthesis of terpinyl acetate from terpineol and acetic anhydride with solid superacid SO42-/TiO2 Ce4+as catalyst had been studied for the first time.

并以该固体超强酸SO42-/TiO2-Ce4+为催化剂，松油醇和乙酸酐为原料合成乙酸松油酯。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了