查询词典 Palladium

Palladium-catalyzed homo-coupling of Boronic Acids with Supported Reagents in Supercritical Carbon Dioxide Lei Zhou;Qiu-Xiang Xu;Huan-Feng Jiang

蚕茧保鲜剂在双孢蘑菇保鲜中的应用研究章伯元；包立军

We studied the effect of water on the palladium acetate-catalyzed coupling reaction of aryl boronic acid with aryl bromide or acyl chloride in ionic liquid or PEG, and found that water had a remarkable rate accelerating effect on the Suzuki reaction and Suzuki-Type reaction when other reaction conditions were uniform.

研究了水对离子液体或聚乙二醇中Pd2催化的卤代苯或苯甲酰氯与苯硼酸的Suzuki和Suzuki-Type偶联反应收率的影响。

Iodobenzene, bromobenzene and their derivatives reacted smoothly with n-butyl acrylate or styrene under phosphine-free reaction conditions in the presence of palladium acetate and fluoroquinolones.

碘苯、溴苯和其它芳基卤衍生物与丙烯酸丁酯、苯乙烯等取代乙烯类化合物在钯和氟喹诺酮的催化下发生Heck反应。

Cyclopentene ; oxidation ; cyclopentanone ; palladium acetate ; iron phthalocyanine

环戊烯；氧化；环戊酮；醋酸钯；酞菁铁

The effect of cyclopentene concentration palladium salts, FePc, acid and reaction mechanism were discussed.

在乙腈的酸性水溶液中，考察了 Pd Ac2 /Fe Pc催化氧化环戊烯合成环戊酮的催化活性，讨论了影响该反应活性的因素及其反应机理。

In the experimental processes, the degenerately p-doped silicon wafers with 100 nm silicon oxide were used as the back gate; palladium metal electrodes were formed by photolithography combined with lift-off technique, and finally deposited and aligned CNTs on the predefined electrode pairs to complete devices fabrication by using alternating current dielectrophoresis.

在实验制作方面，我们以退化型之重掺杂矽基材作为背闸极，基材上方长出100nm之氧化矽绝缘层，配合微影制程定义钯电极於介电层上，再利用介电泳力将奈米碳管接合至电极上方，完成奈米碳管电子元件之制作。

For the smelting slags of exhausted automobile catalyst, a method for determination of trace amounts of platinum and palladium by plus-dual-wavelength overlapping spectrophotometry in dibenzyl dithiooxamide-SnCl2 system was developed.

针对失效汽车催化剂火法熔炼渣，研究了采用正峰双波长叠加，二苄基二硫代乙二酰胺-SnCl2体系萃取光度法测定渣中痕量铂钯的方法。

This dissertation is mainly focused on the reactivity of methylenecyclopropanes and comprises six parts. 1 The reactions of methylenecyclopropanes with phenylsulfenyl chloride, phenylselenyl chloride and diphenyl diselenide; 2 The coupling reactions of the ring-opening products derivated from methylenecyclopropanes; 3 The palladium-catalyzed ring-enlargement of mono-aryl group substituted methylenecyclopropanes to cyclobutenes. 4 The gold-catalyzed domino ring-opening and ring-closing hydroamination of methylenecyclopropanes with sulfonamides; 5 The Lewis acid-catalyzed reactions of mono-aryl group substituted methylenecyclopropanes with diethyl ketomalonate in the presence of water; 6 The iodobenzene diacetate mediated novel 1,3-dipolar cycloaddition of methylenecyclopropanes, vinylidenecyclopropanes, and methylenecyclobutane with phthalhydrazine.

本论文主要研究了亚甲基环丙烷类化合物的一些化学反应性能，共由以下六部分组成：1、亚甲基环丙烷类化合物与苯硫氯、苯硒氯及二苯基二硒的反应；2、亚甲基环丙烷类化合物开环产物的偶联反应；3、单芳基取代的亚甲基环丙烷类化合物在钯催化剂作用下的扩环反应；4、金化合物催化磺酰胺对亚甲基环丙烷类化合物的串联开环关环氨氢化反应；5、路易斯酸催化亚甲基环丙烷类化合物与丙酮二羧酸二乙酯在有水存在下的反应；6、醋酸碘苯促进的亚甲基环丙烷类化合物、亚乙烯基环丙烷类化合物及亚甲基环丁烷类化合物与邻苯二甲酰肼的新型1，3-偶极环加成反应。

Keywords ion plantation;palladium;electroreduction;nitrobenzene;glass carbon electrode

离子注入；钯；电化学还原；硝基苯；玻璃碳电极

Employing acetyl chloride as the electrophile afforded the β-acetoxyvinyl-γ-butyrolactone 3 as the product, which provided an experimental evidence to the mechanism involving the palladium enolate intermediate.

使用乙酰氮作为亲电试剂得到了β－乙酰氧基烯基－γ－丁丙酯3，这一结果为烯醇钯中间体的机理提供了一个实验证据。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。