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N,N,N',N'-tetrabutyl-3-oxa-pentanediamide presents excellent extraction abilities for actinides elements. The effects of hydrolysis and radiation on extraction behavior of U with TBOPDA have been investigated.

N,N,N',N'四丁基 3 氧戊二酰胺对锕系元素具有良好的萃取性能,为了考察TBOPDA稳定性,研究了温度、酸度和吸收剂量对TBOPDA萃取性能的影响。

Letφ:(Z_2)~k×M~n→M~n denote a smooth action of the group(Z_2)~k={T_1,…,T_k|T_i~2=1,T_iT_j=T_jT_i} on a closed n-dimensional manifold M~n.

设φ:(Z_2)~k×M~n→M~n是群(Z_2)~k={T_1,…,T_k|T_i~2=1,T_iT_j=T_jT_i}在n维光滑闭流形M~n上的作用,群(Z_2)~k由k个可换对合生成。

The inhibitive effect of 1, 2-benzenedicarboxylic acid on the absorption of N, P and K increased with its concentration rising. Low concentration of dibutyl phthalate increased the absorption of N, but decreased the absorption of P and K. Its high concentration restrained the absorption of N, P and K, while the low concentration of diphenylamine could stimulate the absorption of N and K, but restrain the absorption of P.

随着邻苯二甲酸浓度的增加,其对番茄幼苗根系吸收N、P、K的抑制作用增强;低浓度的邻苯二甲酸二丁酯可以促进番茄幼苗根系对N的吸收,抑制对P、K的吸收,高浓度时对N、P、K的吸收均起抑制作用;低浓度的二苯胺可以促进番茄幼苗根系对N、K的吸收,抑制对P的吸收。

The calculated results show that the most stable structures of C 5H 10NH(NH 3) n are one linear hydrogen-bonding, three-cyclic and four-cyclic structures for n=1, 2, 3, respectively. At MP2/6-31G//B3LYP/6-31G level, the MO population analysis of the most stable configurations C 5H 10NH(NH 3) n(n=1—3) has been employe...

在 MP2 /6 - 31G //B3LYP/6 - 31G水平下,对最稳定构型 C5 H10 NH( NH3) n ( n=1~ 3)的分子轨道进行布居分析,并且对相应的占据轨道进行指认。C5 H10 NH( NH3) n( n=1~ 3)垂直电离势的计算结果表明,形成氢键团簇后,分子的垂直电离势降低。

The mass loss patterns of four type litters fitted exponential model, and the decomposition rate could be well predicted by their lignin/N ratio.

结果表明:与对照相比,降水量减少条件下,蒙古栎叶凋落物的初始N、P、K浓度显著升高,初始木质素浓度显著降低,凋落物分解速率大,N、P、K矿化率高,N和P固持时间缩短;降水量增加情况下,其凋落物初始N浓度显著降低、木质素浓度显著升高,N、P、K矿化率低,N和P固持时间延长。4种类型叶片凋落物的质量损失过程均符合指数降解模型,分解速率可以由凋落物木质素/N来预测。

The effects of the different N, P and K levels and several plant growth regulators on flowering of phalaenopsis were studied, the results showed:(1) N had a great effect on the formation of leaves, and there had more leaves in plant which had high content of N; P had a major effect on the differentiation of flower buds, it could promote the differentiation of flower bud through the application of phosphate fertilizer; K and N was effect on the elongation of flower stalk, and it had important influence on the length of flower stem.

研究了不同N、P、K水平和几种植物生长调节剂对蝴蝶兰开花的影响,结果表明:(1)N对叶片的形成有较大影响,含N高的植株叶片数较多;P在花芽分化中起主要作用,增施磷肥可促进花芽分化;K和N有利于花茎伸长,它们对花茎的生长有着重要影响。

The effects of the different N, P and K levels and several plant growth regulators on flowering of phalaenopsis were studied, the results showed:(1) N had a great effect on the formation of leaves, and there had more leaves in plant which had high content of N; P had a major effect on the differentiation of flower buding, it could promote the differentiation of flower bud through the application of phosphate fertilizer; K and N was effect on the elongation of flower stalk, and it had important influence on the length of flower stem..

研究了不同N、P、K水平和几种植物生长调节剂对蝴蝶兰开花的影响,结果表明:(1)N对叶片的形成有较大影响,含N高的植株叶片数较多;P在花芽分化中起主要作用,增施磷肥可促进花芽分化;K和N有利于花茎伸长,它们对花茎的生长有着重要影响。

Understand the basic conceptions on homolysis and heterolysis of covalent bonds, and on the nucleophilic substitution and elimination; Grasp the mechanism and stereochemistry of S N 1 and S N 2 reactions; be capable of judging the stability of carbocations; know the factors that can influence the rates of S N 1 and S N 2 reactions; grasp the elimination reactions of haloalkanes, the mechanism and stereochemistry of E1 and E2 reactions.

了解共价键的均裂和异裂及亲核取代反应的基本概念;掌握 S N 1 和 S N 2 反应机理和立体化学;能够判断正碳离子的稳定性;了解影响 S N 1 和 S N 2 反应速率的因素;掌握卤代烷消除反应, E1 和 E2 反应机理和立体化学。

The results show that the calculated cell parameters are in agreement with the experimental ones. The interactions between Li—N and Al—N are strong ionic bonds in Li3AlN2. The interaction between N and H is strong covalent bond and the interaction between Li and N is strong ionic bond in LiNH2. The calculated reaction enthalpies are 23.7 and 55.3 kJ/mol, respectively, which are in agreement with the experimental ones.

结果表明:Li3AlN2的Li—N、Al—N键主要为离子键,LiNH2的N—H键主要为共价键,Li—N键主要为离子键;298 K时贮氢反应的反应焓计算值分别为23.7和55.3 kJ/mol,与实验值均符合得较好;反应中各固态、气态物质的晶胞的结构优化后的晶格常数、键长与键角等与相应的实验值均符合较好。

Treatment of pterin (2-amino-4-hydroxy-pteridine) derivatives with N,N-dimethylformamide dimethylacetal [1,(CH 3) 2NCH(OCH 3) 2] usually gave corresponding N 2-(N,N-dimethylaminomethylene)- pterin derivatives in polar solvents.

用N ,N 二甲基甲酰胺缩二甲醇 [(CH3 ) 2 NCH(OCH3 ) 2 ,1]和蝶呤(2 氨基 4 羟基蝶啶)衍生物在极性有机溶剂中反应一般得到脒化产物:N2 (N ,N 二甲基氨基亚甲基)-蝶呤衍生物。

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