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The result shows that the purification efficiencies of ammonia-nitrogen and ortho-phosphate by immobilized algae in a stationary phase are higher than that in an exponential phase; the starvation treatment increases the removing rates of ammonia-nitrogen and ortho-phosphate, cells of Scenedesmus starved for 48 hours can obtain higher NF4(superscript +)-N and PO(superscript 3- subscript 4)-P removal efficiencies than starved for 48, 72, 24 and 0 hours respectively.

结果表明:静止初期藻细胞对NH4-N和PO(上标 3-下标 4)-P去除率比指数末期高,处理5d后,静止初期细胞对NH4-N和PO(上标 3-下标 4)-P的去除率分别为76.7%及91.7%,指数末期细胞氮、磷的去除率分别为75.4%和88.7%;饥饿处理可明显提高藻细胞对NH4-N和PO(上标 3-下标 4)-P的去除效率,藻细胞饥饿时间对NH4-N和PO(上标 3-下标 4)-P去除率的影响大小依次为48h,72h,24h,0h。

The facts indicate that apart from the asymmetric induction of chiral diamine backbone,sterically hindered substitute groups on the aromatic rings,and the presence of sp~3-hydridized amino donors and its N,N\'-disubstituted groups in chiral SalanCrX complexes all play important roles in controlling polymer stereochemistry and enantioselectivity.

研究发现除了手性二胺骨架的不对称诱导作用,苯环上的大位阻取代基、N,N\'-二取代基的位阻作用以及N原子上sp~3杂化的供电子效应都对调控聚合物的区域和对映体选择性有很大作用。

As for the ester exchange reaction on phosphorus, it was found that N-phosphoryl histidine the fastest one among all of the N-phosphoryl aminoacids. The results studied by MNDO method indicate that due to theparticipation of imidazole group, the formation of hexa-coordinatephosphorus intermediate made the iso-propoxyl which is opposite toimidazole group more active than the other ones and much easier to leave.When iso-propoxyl left, a new penta-coordinate phosphorus intermediate wasformed, and it is sterically favorable to be attacked by an alcohol from theopposite direction of imidazole.

对于磷上酯交换反应,实验中发现N-磷酰组氨酸反应速度明显高于其它N-磷酰氨基酸,理论研究表明,侧键咪唑基参与下六配位磷中间体形成后,位于咪唑基对面的异丙氧基反应活性大大提高,即从咪唑基的对面位置发生异丙氧基的离去和另一分子醇的进攻,在能量上和空间上都是有利的。N-磷酰丝氨酸的磷上酯交换反应有着类似的特点。

The process of DC discharge in O2/N2 mixtures with the different N2 concentration has been simulated. The dependences of number of collisions with the E/N and the energy of electron are given. It is analyzed stressfully that the process of electron-molecule collision with the E/N and the energy of electron in air at atmospheric pressure.

对于O_2/N_2混合气体,模拟了不同配比条件下直流放电过程,得出了发生碰撞的粒子数随E/N、电子能量的变化;着重分析了空气中激发、电离、分解及分解电离碰撞的粒子数随E/N的变化,给出了电子漂移速度和平均电子能量随E/N的变化。

N-substituded thioacridones with five different structures were synthesized via a route involving Ull-man reaction, cyclization, N-alkylation and sulfurization. The structures of each thioacridone were identified with IR and MS. The results from UV-spectrophotometry show that the five N-alkythioacridones all have stronger absorption in the visible light region.

采用乌尔曼反应、酸催化环化、N-烷基化和硫代化四步反应路线合成了5种不同结构的N-取代硫代吖啶酮,利用IR和MS分析手段表征了其结构,UV分光光度计的测定结果表明5种硫代吖啶酮在可见光区都有较强的吸收。

Huapai products:pchlorophenol,ochlorophenol,2,4dichlorophenol,2,6dichlorophenol,2,4,5trichlorophenol,2,4,6trichlorophenol,4chloro2benzyl phenol,pbromophenol,2,4,6tribromophenol,1chloro4(1,1dimethyl ethyl) benzene ether,3bromoanisole,mbromofluorobenzene,2tetra hydrofuran,αbromo4chloro acetophenone,αbromo4methoxy acetophenone,4chloro benzophenone,4chloro2methylaniline,n(2hydroxyethyl)ethane diamine; n(2aminoethyl)ethanolamine,2,3dibromopropionyl chloride,4bromo benzene sulphonyl chloride,terephthaloyl chloride,isophthaloyl chloride,nchlorosuccinimide,nbromosuccinimide,pchloranil;tetrachloro1,4benzoquinone,5chloroisatin.

华派公司产品:对氯苯酚,邻氯苯酚,2,4二氯苯酚,2,6二氯苯酚,2,4,5三氯苯酚,2,4,6三氯苯酚,4氯2苄基苯酚,对溴苯酚,2,4,6三溴苯酚,对氯苯基叔丁基醚,间溴苯甲醚,间溴氟苯,α溴甲基四氢呋喃,α溴代4氯苯乙酮,α溴4甲氧基苯乙酮,4氯二苯甲酮,4氯2甲基苯胺,N(2羟乙基)乙二胺, 2,3二溴丙酰氯,对溴苯磺酰氯,对苯二甲酰氯,间苯二甲酰氯,N氯代丁二酰亚胺,N溴代丁二酰亚胺,四氯苯醌,5氯靛红。

But the electrochemical results show that complexes exhibitcompletely irreversible redox behaviour which is different from thatfound in diiron proteins. 1.3 To obtain the diiron species which are stable to elec-trochemical reduction, a series of new tetranuclear cage ironspecies containing two 〓 cores, with using hexadentatepolybenzimidazole ligands, were synthesized and characterized by vari-ous spectroscopic methods. Their physical properties have been investi-gated. The crystal structures of 〓〓tetrakis (benzimidazol-2-ylmethyl)-1, 4-diaminobutane and 〓,〓-tetrakis ( N-ethylbenzimidazol-2-ylmethyl )-1, 4-diaminobutane were determined. They contain two 〓 cores which arelinked to each other by -〓-chain in the ligands.

1.3为了获得电化学还原稳定双核氧桥联Fe化合物,使用六齿配体合成了一系列含有两个〓单元四核笼状化合物,并用各种谱学手段表征了它们,还研究了它们的物理化学性质确定了〓L=N,N,N',N'-四(苯骈咪唑基-1,4-丁二胺和〓,〓四-1,4-丁二胺化合物的晶体结构,它们含有两个〓单元,其中两个〓单元是通过配体的〓链桥联成四核笼状结构。

Author was menstruated content of boron and researched the status of lack of Boron and researched relativity of its Influencing facto, the results showed that the average content of available boron in the yellow soil was 0.39±0.27 mg/kg, 80 percent of its was under 0.5mg/kg which was lack for boron and 17.44 percent of its was under 0.2mg/kg which was especially lack for boron; The distribute frequencies of available boron contents of yellow soils in Chongqing was dispersedly, its range of 0.07mg/kg to 1.99mg/kg. The diversity of different zoology area was distinct. The result of pertinence analyses showed that available boron contents had correlativity with the pH(r=0.181** n=281) and CEC(r=0.124** n=281 and It had correlativity with Organic matte When the content of organic matte is high; in addition, soil granule、clime was the Influencing factor of availability of boron in Yellow Soils in Chongqing.

笔者通过调查取样对重庆市黄壤硼的含量进行测定并分析了缺硼的程度,对其影响因素进行了相关性分析,研究结果表明:重庆市黄壤有效硼的平均含量为0.39±0.27mg/kg,其中近80%的土壤样品有效硼含量低于0.5mg/kg,属于低硼或缺硼土壤,还有17.44%的土壤样品有效硼含量低于0.2mg/kg,属于极度缺硼的土壤;而有效硼含量的分布频率比较分散,变幅较大,从0.07mg/kg~1.99mg/kg,变异系数达到69.41%,不同生态类型区土壤有效硼含量的差异十分明显;而相关性分析结果表明:土壤有效硼与土壤pH值(r=0.181** n=281)和CEC(r=0.124** n=281呈正相关,在有机质含量较高的条件下与其相关性也较为显著(r=0.347** n=90,而土壤质地以及气候也对重庆市黄壤硼的有效性有很大的影响

In this paper analyzing stationary structures of NH~+_(4)H_(2O_(n=1~6) clusters,it is found that the first stationary structure is linear hydrogen bonding NH~+_(4) with H_(2)O in clusters,the second is bifurcated structure ,the third is trifurcated structure.

利用密度泛函理论中B3LYP方法,6-31G基组对NH4+(H2O)n(n=1~6)簇合物进行几何优化,得到了稳定结构。本论文分析了NH4+(H2O)n(n=1~6)簇合物的稳定结构,发现NH4+与H2O以线性氢键结合成的簇合物结构最稳定,其次是二叉结构,再次是三叉结构

Based on the experimental results, it could be consequentially concluded that N-methoxycarbonylation of aromatic amines was followed by the exclusive N-methylation of methyl N-aryl carbamates during the reaction process.

苯环上有钝化基团的一级芳胺反应活性比较好,获得N-甲基-N-芳基氨基甲酸甲酯的产率较高,反应时间也较短;而苯环上活化基团的存在,则会降低一级芳胺的反应活性。

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Shop assistant: Please check at the door.

店员:请您到门口柜台交费。

In the end, transportation of PAHs in the environmental matrix was preliminarily investigated and discussed according to PAHs data of soils and sediments from a certain region in Shanghai. The result indicated that there are two or more pathways on PAHs transportation in the environmental matrix.

最后,对上海特定地区内PAHs在环境介质中的迁移径途进行了分析讨论,结果表明上海市土壤和沉积物等环境介质中PAHs的迁移存在多种途径。

Quick stop! AIDS doctors while the side and say hello and colleagues mention a blood sample box, the Red Cross had sent blankets and so on, with patients有说有笑to go home.

快停车!防艾医生们一边招呼一边和和同事们提着血液采样箱,抱着红十字会送来的被子等,有说有笑地同患者往家走。