查询词典 Ionic

The main content of this paper as follows: The acidic strength, reaction temperature, reaction time of Chlorine-aluminate Ionic Liquids with different structure of cation on the activity of transalkylation of MN with TeMB and the selectivity of 2,6-DMN were studied. The optimum reaction condition was obtained: the molar fraction of AlCl_3 is 0.71, molar ratio of 2-MN and TeMB is 1, the amount of ionic liquid is 32wt%, reaction temperature is 20℃and reaction time is 8h using X-xAlCl_3 and X-xAlCl_3 as catalysts; the optimum reaction time is shortened 6h using Et_3NHCl-xAlCl_3 as catalyst.

本文主要研究了以下内容：分别考察了不同阳离子结构的氯铝酸盐类离子液体的酸强度、反应温度、反应时间等因素对MN和TeMB转移烷基化的催化反应活性和2，6-DMN选择性的影响，优化得到适宜的反应条件为：以X-xAlCl_3和X-xAlCl_3为催化剂时，AlCl_3的摩尔分数x=0.71，2-MN和TeMB摩尔比为1∶1，离子液体用量为32wt％，反应温度为20℃，反应时间为8h；以Et_3NHCl-xAlCl_3为催化剂时，反应时间缩短到6h。

FT-IR spectrum showed that the new bands at 3000cm-1~2700cm-1 and 1600cm-1~1400cm-1 were assigned to the C-H telescopic vibration and the framework vibration feature of imidazole ring, besides the characteristic bands of BMMs appeared in all samples, however, all of characteristic bands for imidazolium ionic liquid disappeared in the samples when calcined at 550oC, which implied that the structure of imidazolium ionic liquid has been destroyed during calcinations.

FT-IR分析测试中3000cm-1~2700cm-1及1600cm-1~1400cm-1波数范围内的谱带被认为是饱和的C-H伸缩振动和芳环骨架振动，说明离子液体的存在，这些峰只在萃取样品中出现，可见键连的离子液体的结构在焙烧过程中被破坏。

In this paper, after a brief introduction for the composition and structure of lignin, cellulose, hemicellulose and room-temperature ionic liquids, the recent progress in dissolution and separation of lignocellulose with ionic liquids is reviewed.

本文在介绍木质素、纤维素、半纤维素和相关室温离子液体的组成与结构的基础上，综述了室温离子液体在溶解、分离木质纤维素方面的研究进展。

It was found that moisture in the system of reaction is main reason that lead to deactivation of ionic liquids. The reaction mechanism of transalkylation reaction of methylnaphthalene and 1,2,4,5-tetramethylbenzene catalyzed by chlorine-aluminate ionic liquids has been proposed.

考察了离子液体的循环使用情况，分析确定了离子液体的失活原因，认为反应体系中的微量水使离子液体水解是造成离子液体失活的主要原因。

Seven acidic ionic liquids were synthesized and used as catalyst in the synthesis of N-formyl morpholine ,among which a reusable ionic liquid [HSO3-pmim]HSO4 was selected and characterized.

合成了7种酸性离子液体，并将其应用于催化合成N-甲酰吗啉的反应中，筛选出了一种可以重复使用的离子液体[HSO3-pmim]HSO4，并对其进行了表征。

We studied the effects of protein content, pH and ionic strength on viscosity of silver carp myofibril protein by orthogonal rotational regression design, and established the regression equation of silver carp myofibrillar protein solution viscosity with protein content, pH and ionic strengt

利用二次回归正交旋转试验设计，研究了蛋白质浓度、pH、离子强度对鲢鱼肌原纤维蛋白粘度的影响，建立相应的回归方程，分析比较了它们间的相互作用关系，确定了取得最优粘度时，各因素的组

Because of the nondirectional property of ionic bond and the fully delocalized property of pi electrons on carbon layers, translation will not change the electronic structure of carbon layers, resulting in that A-GIC and AE-GIC hare quite good lubrication as well. The electrons come from metals mainly transfer to the delocalized pi orbitals of carbon layers, and the increase of delocalized electrons will make metal graphite intercalation compound more electro-conductive than graphite itself. Because ionic bond between metals and carbon layers is weaker and its lattice energy is much less than that of typical NaCl crystal, so metals could be left from interlayers. The Mulliken populations of C-C in intercalation compounds are smaller than that of graphite, and the HOMO energy level of GIC is higher than that of graphite too. These Lead to that GIC will easier be oxidized.

由于离子键没有方向性，又由于碳层中的π电子是充分离域的，所以碳层不会由于平移而改变其电子结构，金属石墨层间化合物仍具有很好的润滑性；金属失去的电子主要转移到碳层的离域π轨道中，碳层离域电子增多使金属石墨层间化合物的导电性比石墨增强；金属与碳层间的离子键强度比较弱，其晶格能远小于典型的离子晶体，因而金属易从石墨层中脱出；金属石墨层间化合物中的C-C间Mulliken布居值小于石墨中C-C间的值，且金属石墨层间化合物的HOMO能级也高于石墨的HOMO能级，所以石墨层间化合物中的碳原子较石墨更易被氧化。

The effects of molar ratio of linoleic acid and ethanol, temperature , and amount of ionic liquid on esterification reaction were studied and the optimal reaction conditions were obtained, that is, n :n = 4:1 , at refluence temperature, with the amount of ionic liquid equaling 42wt.

研究了环境友好的BF4离子液体催化亚油酸等高碳脂肪酸与无水乙醇酯化反应，考察了亚油酸与乙醇的摩尔比、反应温度、离子液体用量等条件对亚油酸酯化反应结果的影响，优化了反应的工艺条件。

The solubilization power of non-ionic surfactant is higher than that of ionic surfactants.

比较发现，非离子型表面活性剂的增溶能力高于离子型表面活性剂。

Ionic liquids were synthesized under various molar ratios of Et3NHCl to AlCl3. The effects of ionic liquids and extraction conditions on the thiophen removal and recovery were investigated using thiophen containing n-Octane as model gasoline.

用盐酸三乙胺(Et3NHCl)和无水AlCl3按不同的摩尔比合成了离子液体，并评价了其对模型汽油中噻吩硫的脱除与回收效果。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。