查询词典 H2O

Three new fulvene polymeric compounds, namely 1[Ag (L3]CH2C12 , 2[Ag2(L25(H2O)(S03CF3)2]0.5C6H6 and 3 Mn(L42(C2H5OH)2 , were synthesized, respectively. Compounds 1 and 2 reported herein represent the organometallic polymers based on both Ag-N and Ag-C coordination interactions. In the solid state, compound 3 are bound together by strong intermolecular N H-O hydrogen bonding system into a supramolecular one-dimensional H-bonded chain.B.

一、富烯有机配体的合成及与金属离子的反应化学利用富烯负离子的芳酰化反应和Heck-偶联反应合成了富烯配体L1-L18，并合成了三个基于富烯配体的金属有机配位聚合物1[Ag(L3]·CH_2Cl_2、2[Ag_2(L25(H_2O)(SO_3CF_3)_2]·0.5C_6H_6和氢键驱动的超分子聚集体3Mn(L4_2(C_2H_5OH)_2。

Ti-MWW exhibited a conversion of 97% for allyl aolcohol and a selectivety of above 99% for glycidol when the allyl aolcohol epoxidation was carried out at 333K for 30 min with Ti-MWW of 0.05g, allyl aolcohol of 10mmol and H2O of 20ml.

当Ti-MWW 用量0.05g，水加入量20ml，烯丙醇加入量10mmol，在333K 下反应30min，烯丙醇的转化率达到97%，对缩水甘油选择性达到99%以上。

Using 60% high concentrated Sb2O5/H2O colloid as a raw material, a method for preparation of flame retardant Sb2O5 hexamethylene ketone colloid was studied.

胶态Sb2O5是锑深加工产品，具有优良的阻燃性能，是锑系阻燃剂中最好的一个品种，也是近年来日、美系阻燃剂中发展较快的一个品种[1～2]。

The molecules involving azo and imino functional groups can coordinate with Hg2＋ to result in a large blue shift from 453 to 363 nm corresponding to a notable color change from orange to pale yellow in aqueous methanol solution (H2O/CH3OH＝1/4, V/V), which can be applied to naked eye detection of Hg2＋.

这些传感器分子包含偶氮和亚胺功能基团，在水/甲醇溶液（体积比1/4）中，可以与汞离子配位，使紫外-可见光谱中吸收峰发生由453到363 nm的蓝移，引起一个明显的溶液由橙色到淡黄的颜色变化。因而，这些传感器有肉眼检测汞离子的潜在应用。

We have developed a simple and easy-handling procedure for copper-catalyzed cyanation of aryl halides using K4[Fe_6] as the cyanide source. The present procedure has ligand- and base-free advantages, and was accomplished under the conditions of exposure to the air without degassing of the solvent.4. We carried out the selective control of preparation for phenyl ether and phenol from iodobenzene with 10 mol% of Cu_2·H_2O as the catalyst under the condition of exposure to air.

这个程序有无配体无碱的好处，并能够在暴露于空气的条件下进行，溶剂也不用脱气。4、空气气氛下，用10 mol%的Cu_2·H_2O催化碘苯偶联，实现了制备二苯醚和苯酚的选择性控制：即在有(来源：Aa955BC55论文网www.abclunwen.com)机溶剂NMP中实现了碘苯直接制备二苯醚的Ullmann反应，在H2O中实现了碘苯直接制备苯酚。

The results showed that under 200 W power, in the present of various alkalis, e.g. Na2CO3, NaF, KF, NaHCO3, and DMF-H2O (V∶V=5∶3) used as solvent, PVC-TETA-Pd could catalyze sodium tetraphenylborate to react quantificationally with iodobenzene in 20 min without inert gas protection, and all the phenyl g...

实验发现：在微波功率为200W时，在Na2CO3，NaF，KF，NaHCO3等多种碱的存在下，以DMF的水溶液(V∶V=5∶3)为溶剂，在无惰性气体保护下，PVC-TETA-Pd催化四苯硼钠与碘代苯在20min内即可定量反应，与常规加热方式相比，节省了大量时间；同时也证明了四苯硼钠的四个苯基均可参与Suzuki偶联反应；该催化剂回收再利用3次后，仍具有较高的催化活性。

The first part is to synthesize 5-formyl -8- quinolinol from 8-uinolinol and chloroform , using ethanol as a solvent. Then analysizing the 5-formyl-8-quinolinol by IR. The second part is , according to ideas of molecule designing, to synthesize the new self-assembly Inorganic-Organic coordination polymers Co(u2-bpyV2O6,(C4H4N2)Ni2(H2O)2-V4Ol2,(Cl2Hl2N2)Co-V2O6 using Cu, Ni, and Co as templating, 4-cyano-pyridine(4-CNPy), 4,4-bipyridine,pyrazine, l,2-bis(4-pyridyl)ethane, 5-formyl -8- quinolinol as building blocks and Ammonium Metavanadate (NH4VO3) as subordinate building blocks by Hydrothermal , analysizing their content of element determining their structures by X-Ray diffraction.

本课题实验分为两部分：一是配体的合成，以8-羟基喹啉、三氯甲烷为原料，以乙醇为溶剂，合成了5—甲醛基—8羟基喹啉并且对其进行了IR的分析测定；二是配位聚合物的合成，通过分子设计，采用溶剂热法以Cu、Ni、Co为中心离子，以5—甲醛基—8羟基喹啉、4，4-联吡啶、吡嗪、1，2-二吡啶基乙烷为配体，以偏钒酸根(VO_3~-)为辅助配体，通过水热法自组装合成了新的3-D网状结构配位聚合物Co(μ_2-bpy)V_2O_6，(C_4H_4N_2)Ni_2(H_2O)_2·V_4O_(12)，C_(12H_(12)N_2Co·V_2O_6，并对其进行了元素分析和晶体结构的测定。

The experimental conditions were as follows: C18 chromatographic column, mobile phase of MeOH-H2O (both include 0.1% methanoic acid), flow rate at 1.0 mL/min, gradient elution, detection wavelength at 290 nm and room temperature.

采用C18色谱柱，甲醇－水（含0.1％的甲酸）梯度洗脱；流速为1.0mL/min，检测波长290nm；柱温为室温。

When the NAIs combined with H2O molecules, the control efficiency of E.

coli气胶控制效率会高於吸湿性较差的B。

The alterations of protein secondary structure before and after interaction with NAR were determined both in H2O and D2O buffer solutions.

在缓冲水溶液和重水溶液中分别测定了与药物作用前后蛋白质二级结构的变化。

The absorption and distribution of chromium were studied in ryeusing nutrient culture technique and pot experiment.

采用不同浓度K2CrO4(0，0.4，0.8和1.2 mmol/L)的Hoagland营养液处理黑麦幼苗，测定铬在黑麦体内的亚细胞分布、铬化学形态及不同部位的积累。

By analyzing theory foundation of mathematical morphology in the digital image processing, researching morphology arithmetic of the binary Image, discussing two basic forms for the least structure element: dilation and erosion.

通过分析数学形态学在图像中的理论基础，研究二值图像的形态分析算法，探讨最小结构元素的两种基本形态：膨胀和腐蚀；分析了数学形态学复杂算法的基本原理，把数学形态学的部分并行处理理念引入到家实际应用中。