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They have close relationship as the former may provide new ideas and approaches for the later, while the later may be the simulation for the former and gives it helps in degradation products identification and mechanism explanation. It is necessary to choose a suitable system, which has high potential of treating EDs and close relationship to the natural environment, to combine the researches in the two aspects. Our group has been engaged in researches on the photochemical properties and application to water pollution control of different ferric species including Fe -OH complexes, Fe -polycarboxylate complexes, Ferric oxides and Fe -humic acid complexes. Fe -oxalate complexes system has higher efficiency than the other ferric species systems in photooxidation and degradation of organic compounds. This thesis is focused on the photodegradation of nine EDs estradiol (E2), estrone (E1), 17α-ethynyl estradiol (EE2), diethylstilbestrol , bisphenol-A , 4-Nonylphenol , 4-Octylphenol , di-n-butyl phthalate , and di (2-ethylhexyl) phthalate .

因此从处理效率和环境化学意义两方面考虑，结合本课题组在不同铁形态（包括Fe-OH配合物、Fe-多羧酸配合物、Fe氧化物、Fe-腐殖酸配合物等）的光化学特性及其在水污染控制中的应用方面较系统的研究工作基础，本论文选择了四类共9种典型的内分泌干扰物（雌二醇（E2）、雌酮（E1）、17α-乙炔基雌二醇（EE2）己雌酚、双酚A、壬基酚、辛基酚、酞酸二丁酯和酞酸二乙基己基酯），研究了它们在Fe-草酸盐配合物体系中的光降解效果，推测其降解机理，探索环境内分泌干扰物光氧化处理的新体系，同时为预测其在环境中的光降解行为提供了依据。

First of all, this study will be multi-walled carbon nanotubes by chemical oxidation process purified so it can be modified to deal with than the purification of purity before the modified 5 wt%, more than 1.89 times the surface area to increase the surface potential decrease of about 10 ~ 20 mV and the surface functional base (-COOH and-OH) to increase 1.45 times, and then the control technology of electroless preparation parameters include: analysis of plating time, plating analysis of temperature, metal ions in solution than the (Fe2+/ Ni2+), bath pH and the added value of dispersion Agent and other research towards Fe-Ni particles to increase the iron content and Fe-Ni particles spread in the MWCNT upper fixed targets,the results found that when the parameters for the preparation of 50 ℃, pH10, do not add dispersant, metal ions than the solution (Fe2 +/ Ni2 +) 7, the highest iron content can be Fe = 40.55 at%(flat iron content 111.17 mg / g) of nanocomposites Fe-Ni/CNT, then for a series of the nature of its analysis, the final evaluation Fe-Ni/CNT nanocomposites were processed on the effectiveness of the application of mixed pollutants, the results showed that in 120 minutes at the same time when Adsorption of heavy metal ions lead nitrate 10 ppm, selenium heavy metal ion degradation of 1 ppm and orange azo dye AO7 50 ppm standard of effluents, and after a total Fe-Ni nano-particles to SEM / EDS analysis of more than 50% still remaining.

本研究首先将多壁奈米碳管以化学氧化法做纯化改质处理能使其纯度较纯化改质前提高5 wt％、比表面积提高1.89倍、表面电位下降约10~20 mV以及表面官能基提高1.45倍，再控制无电镀技术之制备参数包括：析镀时间、析镀温度，镀液中金属离子比(Fe2+/Ni2+)、镀液pH值及是否添加分散剂等，研究朝提高Fe-Ni粒子的含铁量与Fe-Ni粒子散布固定在MWCNT上等目标进行，研究结果发现当制备参数为50 ℃、pH10、不添加分散剂、镀液金属离子比(Fe2+/Ni2+)7时，可得到最高铁含量Fe = 40.55 at％(单位铁含量111.17 mg/g)之奈米复合材料Fe-Ni/CNT，接著对其作一系列性质分析，最后评估奈米复合材料Fe-Ni/CNT对共处理混合污染物之应用效益，结果显示其在120分钟时能够同时吸附重金属硝酸铅离子10 ppm、重金属硒酸根离子1 ppm及降解偶氮橘色染料AO7 50 ppm达放流水标准，且共处理后奈米Fe-Ni粒子以SEM/EDS分析仍剩余50 %以上。

The composition of Fe-Co and Fe-Co-Mn alloy is analyzed by using Electron Probe Micro Analysis and the magnetic properties of porous alumite film in which Fe-Co and Fe-Co-Mn alloy electrodeposited are measured by a Vibrating Sample Magnetometer .

本论文通过使用多种现代测试技术，如：扫描电镜、透射电镜、电子探针X射线能谱、X射线衍射、电子衍射分析和振动样品磁强测试等，对铝阳极氧化膜的形貌、纳米级微孔内Fe—Co和Fe—Co—Mn合金的晶体结构、Fe—Co和Fe—Co—Mn合金在纳米级微孔内的电沉积工艺以及纳米级微孔内Fe—Co和Fe—Co—Mn合金的磁性进行了系统的研究。

On the antagonistical mechanism,it is suggested that the poison of Cd on tobacco could be impaired by Fe supply in Cd pollution area.

结果表明：Cd、Fe、Cd+Fe和Fe+Cd处理均不改变氨基酸的种类组成；Cd对烟草叶片氨基酸含量的影响比Fe大；Fe抑制Cd对氨基酸含量的影响，Cd也抑制Fe的作用，Cd与Fe相互拮抗，并初步探讨了拮抗机制；建议在Cd污染地区通过施加Fe来减轻Cd对烟草的毒害。

In the passivated REBAR electrode surface formed by ORCs the grain observed from AFM examination is composed of γ-Fe〓O〓 and Fe〓O〓 0 At+0.7V, the passive film on REBAR electrode formed by single-step polarization is composed of Fe (Ⅲ oxide highly doped by Fe〓. In some areas, small γ-Fe〓O〓 particals or some polymeric structure which contains dioxy and dihydroxy bridging bonds between the iron atoms may also exist in the other region.

通过AFM实验观察到的钢筋电极经循环电位扫描至+0.7V形成的钝化膜中具有的结晶颗粒主要由γ-Fe〓O〓和Fe〓O〓·yH〓O0 阶跃电位形成的钢筋钝化膜在+0.7V下主要是由掺杂了大量Fe〓的三价铁氧化物构成，在某些微小的区域可能存在γ-Fe〓O〓微晶，而在另外一些区域则具有聚合物膜的结构。

The Ni-Fe and Mg-Al-Fe-LDH show paramagnetism at normal temperature, the calcined samples of LDHs show super-paramagnetism. The magnetization increases with the higher Fe~(3+) content and is independent of the crystal structure of LDHs. Magnetization of the calcinates of Ni-Fe-LDHs is higher than the Mg-Al-Fe-LDHs.3. Two novel SFME systems were found for the first time, that is furaldehyde/DMF/water and furaldehyde/ethanol/water system.

结果表明，Ni-Fe和Mg-Al-Fe型LDHs本身及其煅烧产物在常温下均呈现顺磁性，其煅烧产物均呈现超顺磁性；同类LDH中其煅烧产物的磁性大小与Fe~(3+)含量成正比而与LDH的晶体结构无关，Ni-Fe LDHs及其煅烧产物的磁性强于Mg-Al-Fe LDHs及其煅烧产物，。3。

Two times hydrolyzation of Fe~(3+) and Cr~(3+) was firstly pointed out in the process of pillar preparation with hydrothermal method. In order to improve the thermal stability, Fe/Cr-Si-pillaring agent solution was synthesized by hydrolyzing Fe~(3+) and Cr~(3+) solution on the surface of silica sol, and Fe/Cr-Si-pillared montmorillonite (Fe/Cr-Si-PILM) was prepared with conventional method and hydrothermal method. Because the technical innovation of preparation is the best way to improve the PILM properties, two novel methods (Microwave method and Ultrasonication method) have been studied to synthesize Fe/Cr-PILM.In order to expand PILMs new application in the field of coal conversion, catalytic activity of Fe/Cr-Si-PILM catalyst in LongKou lignite and ShenHua coal residue liquefaction was discussed and characterized in the last part of this paper.

研究证明：蒙脱石的预处理是可行的，我们以预处理后的Ca-M为原料，研究并优化了PILM的水热法制备工艺，提出了金属离子的二次水解法；为了提高PILM的热稳定性，我们自制了硅溶胶，合成了Fe／Cr-Si三元复合柱化剂，并制备了Fe／Cr-Si-PILM；在PILM合成中，制备技术的革新是改进PILM性能的重要方法，为此我们探索了微波合成法和超声波合成法在制备Fe／Cr-PILM中的应用；最后，我们选择龙口褐煤和神华煤液化残渣为研究对象，探索了Fe／Cr-Si-PILM催化剂在煤炭液化中的应用，希望能开拓PILM应用的新领域。

We found that the microstructures and magnetic properties were not influenced with depositing temperature and sputtering power. The magnetic properties were only affected by Fe layer thickness. When the Fe layer thickness is thinner than 5 nm, weak exchange coupling raised between Fe cap layer and FePt recording layer. When the thickness reached 10 nm, the strongest exchange coupling formed. Film coercivity didn't distinctly vary as Fe layer thickness is thinner than 15 nm. Consequently, we measured DCD curves and had the same conclusions. Indeed, the appearance of exchange coupling is confirmed with 10 nm Fe cap layer.

我们并发现溅镀Fe之温度与瓦数，并不会对结构或是磁性质有显著的影响，Fe厚度的改变虽然也不会改变结构，但是对Cr/Pt/FePt/Fe磁性质却有明显的变化，当Fe厚度薄时(3、5 nm)，在Fe和FePt界面仅有弱的交换耦合力产生，Fe厚度是10 nm时，此时交换耦合力为最强，厚度再增加到15、20 nm时，Hc反而略为上升，同样的我们量测DCD曲线，也证实了Fe厚度10 nm的确有交换耦合力存在。

The results show that with the increase of deformation strains and thinning of Fe-Cr fibers, the saturation magnetization are about 140 A·m2/kg constantly, and the remanent magnetism and coercivity increase gradually.The magnetic properties of Fe-Cr fibers are invariant when the Fe-Cr fibers were preserved in absolute alcohol or air for more than 1 a. After Fe-Cr fibers heated in air at temperature higher than 300 ℃ for 1 h, the Fe-Cr fibers transform from ferromagnetic α-solution to paramagnetic2O3, and the saturation magnetization of samples decreases remarkably. With the increase of deformation strains, the thermal stability of thinner Fe-Cr fibers decreases.

结果表明：随着变形量的增大和Fe-Cr纤维的细化，纤维的饱和磁矩基本恒定(约140 A·m2/kg)，而剩磁和矫顽力则逐渐增加； Fe-Cr纤维在无水乙醇和空气中储存一年以上，磁性基本保持不变； Fe-Cr纤维在空气中经300 ℃以上加热1 h后，逐渐由铁磁性的α-固溶体转变为顺磁性的2O3，饱和磁化强度显著下降；且随着变形量的增大，较细Fe-Cr纤维的热稳定性较差。

The formal potentials in cyclic voltammograms of these 3+ valence complexes are followed: Co〓-TPPS (-0.08V )＞Fe〓TPPS (-0.14V)＞Mn〓-TPPS (-0.23V). The electrochemical reaction of Mn〓-TPPS is reversible, and both of Co〓-TPPS and Fe〓-TPPS are quasi-reversible. The standard heterogeneous rate constants of Co〓-TPPS and Fe〓-TPPS were determined to be 1. 4×10〓cm/s and 1.4×10〓cm/s respectively. The rates of electrode reaction are as followed: Mn〓-TPPS＞Co〓-TPPS＞Fe〓-TPPS, e.i. Mn〓-TPPS is the most easily oxidized by the dissolved oxygen, and Fe〓-TPPS is oxidized slower than Co〓-TPPS. Ni〓-TPPS can not be oxidized. It is considered that oxygen plays an important role in the valence change of central metal atom and the rate of electron transfer in some metalloporphyrins.

三价金属卟啉络合物在循环伏安图上可得到三价到二价的还原和氧化响应，电极电位从大到小排列为：Co〓-TPPS(-0.08V)＞Fe〓-TPPS(-0.14V)＞Mn〓-TPPS(-0.23V)，电极反应可逆性也不相同，Mn〓-TPPS是可逆过程，Co〓-TPPS、Fe〓-TPPS是准可逆过程，实验测得Co〓-TPPS的标准电极反应速率常数ks＝1.4×10〓cm/s，Fe〓-TPPS的ks＝1.4×10〓cm/s，电极反应的速率从大到小为：Mn〓-TPPS＞Co〓-TPPS＞Fe〓-TPPS，即Mn〓-TPPS最容易被溶解氧所氧化，Fe〓-TPPS被氧化的速度最慢，Ni〓-TMPyP不能被氧化，因此我们认为溶解氧对金属卟啉中心离子的价态和电子转移速率起着重要作用。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了