查询词典 C.H.

The empty p orbital and the occupied σorbital by a lone electron pair of carbene point towards H atom and C atom of the C—H bond respectively.

卡宾空的p轨道和占有一对孤电子的σ轨道分别指向C—H键的H原子和C原子。

Under a lower pressure, the relationship between C/H and CO adsorption quantity was a beeline and the CO adsorption quantity increases with the of C/H ratio. The relationship between C/H and CO adsorption is a concave curve with the pressure increasing, and the higher the pressure, the higher the discrete degree.

当压力较低时，C/H与吸附量呈直线关系，随着C/H的增加而增加；随着压力的升高，C/H与煤对CO吸附量之间呈凹形曲线关系，压力越高离散度越大。

Let C be a nonempty closed convex subset of a Hilbert space H, P:H→C be a nearest point projection, and T:C→H be a nonexpansive mapping satisfying the weakly inwardness condition, and :C→C be a fixed contractive mapping. Let the implicit iterative sequences {x},{y} and the explicit iterative sequences {x},{y}.

设C为实Hilbert空间H的非空闭凸子集，P：H→C为最近点投影映射，T：C→H为非扩张映象，且T满足弱内向条件，：C→C为压缩映象。t∈(0，l)，定义了2种隐式粘性迭代序列{x}，{y}和2种显式粘性迭代序列{x}，{y}，证明了T有不动点当且仅当序列{x}，{y}，{x}，{y}有界。

By use of the Fischer-Tropsch reaction in a C-H-O system, we discussed the relationships between inorganic CO〓 and some physical chemistry conditions, such as Oxygen flee degree , temperature, pressure, other objects consistency and catalyzer. a when T=200K～2000K, if f〓＞0, the reaction of generating CO〓 will be dominant, CH〓 hardily exists; b when T＞1000K, CH〓 is not propitious to exist, carbon in system almost exists in form of CO〓; c the more pressure, the more CO〓 is propitious to exist; d the more consistency of CO, O〓 and H〓O, the more CO〓 is propitious to exist, the more consistency of H〓, the more CH〓 is propitious to exist.

依据C-H-O体系费托反应的简化模型，讨论了氧逸度、温度、压强、其它物质浓度、催化剂等物理化学条件对无机成因CO〓生成的影响，从理论上讨论了在地质环境中，无机成因CO〓存在的物理化学条件：1在T＝200K～2000K的温度范围内，体系中一旦氧逸度＞0，生成CO〓的反应将占绝对优势，CH〓几乎不可能存在；2T＞1000K时，不利于CH〓形成，使体系中的碳主要以CO〓的形式存在；3体系压强越大，越有利于CO〓的形成；4反应物CO、O〓、H〓O的浓度越高，越有利与CO〓的存在，H〓的浓度高有利于CH〓的形成。5地质成藏作用可以经历很长的地质年代，这足以补偿矿物岩石中的Ni、Mo、Fe、Co、Ru等催化性能的降低及其它动力学条件的不足，使得费托反应可能发生，从而生成无机成因的CO〓和烃类。

The results showed that the decomposition of 4-nitroimidazole began with the split of the C—NO2 bond in the temperature range of 185—210℃. The strongly oxidative product NO2 destroyed the instable annulus of 4-nitroimidazole instantly, all the other C＝N, C＝C, C—H and N—H bonds of the five membered ring were broken simultaneously, and the detected gas products of 4-nitroimidazole decomposition were NO2, CO2 and CO.

结果表明，4-硝基咪唑的催化热分解起始于其分子中C-NO2化学键的断裂，温度范围是185~210℃。C-NO2键的强氧化性的裂解产物NO2瞬间作用于4-硝基咪唑分子中不稳定的五员环，使化学键C=N、C=C、C-H和N-H同时被打破。4-硝基咪唑的气体分解产物包括NO2、CO2和CO。

In addition, the changes of molecular geometry, atomic natural charge and IR spectra of the reaction system during the crucial step of O to attack H showed that the rupture of C—H bond and the formation of O—H bond were concerted stepwise. Obvious changes of atomic natural charge happened to atoms C(1), H(11), O(28), O(29) and N(27). The bond lengths and bond angles related to these atoms were also varied greatly.

NO2中O进攻1-H决速反应过程中，分子几何、原子自然电荷及IR光谱变化表明， C—H键的断裂和N—H键的形成是一个协同过程；参与新键形成和旧键断裂原子C(1)， H(11)， O(28)， O(29)和N(27)的原子自然电荷及与其相关的键长、键角有明显的变化。

A computational result of RHF/LANL2DZ optimized structure and total energy shows that the isomers with C H���π structure have lower total energy, and that stability and isomeric preference of isomer are related to the C H���π interaction in the isomer.

用 RHF/LANL2DZ对该体系可能的异构体进行结构、能量优化，可能形成C—H…π相互作用的异构体具有较好的稳定性。C—H…π相互作用对含吡啶环的[CoN5Cl]^2+系配合物的异构体的选择性形成及其稳定性具有重要作用。

Direct competitions of intramolecular C - H insertions into benzylic C - H and 4-nitroor 4-methoxy substituted benzylic C - H of methyl 2-diazo-3-oxo-6-(4-substituted phenyl)-4-(2-phenylethyl)hexanoate 44a and 44b catalyzed by Rh-mediated carbenoid were alsoinvestigated, and the relative reactivities obtained by compound 44a or 44b were comparableto those obtained by indirect method.

此外，还研究了Rh催化分解下，对位硝基取代或甲氧基取代的4-(2-苯基乙基)-6-(4-取代苯基)-2-重氮基-3-氧代己酸甲酯44a、44b苯甲位C-H插入反应的相对速率，与化合物47a和47f得到的结果比较，数据平行。

Therefore, the previous data of heats of formation of polynitrocubanes estimated from groupadditivity method are corrected.3. Calculations indicate that, for polynitrocubanes, there are parallel relationships between their experimental kinetic acidities pKa, the average s characters in the exocyclic carbon orbital used for the C-H bonds within each molecule, and the average C-H stretching frequencies within each molecule.

计算结果表明，多硝基立方烷的实验动力学酸性pK_a、分子内用于形成C-H键的环外碳轨道平均s成分和分子内的平均C-H伸缩频率之间，存在平行的递变关系，这对基于s_a或v_a的数值预估动力学酸性pK_a、进而指导多硝基立方烷和其它相关化合物的合成有助。

The stretching vibrational frequencies of C-H and N-H bonds of the tetrazole rings are higher than those of substituents'.

环C-H或N-H键伸缩振动频率均较取代基相应的C-H和N-H伸缩振动频率高。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。